Chemical Reactions and Equations
Chemical Reactions and Equations
Chemical reaction:
The process of
combination of different atoms to form different products is known as
chemical reaction. Chemical reaction involves a change in the physical and
chemical properties like:
- Change in
the colour of the substance
- Change in
the state of the substance
- Change
in heat energy - Absorption of energy or release of energy
- Release of
gas
- Evolution of
light and sound
Example:
Burning of coal:
During the burning coal, the solid state coal burns with release of heat and
gas.
Chemical equation:
A chemical equation is a symbolic representation of the reactants and the
products using their chemical formulae.
A chemical equation contains:
• Reactants
• Products
• An arrow separates the
reactants and products
Reactants are the substances which take parts in the chemical reaction.
Products are the substances which produced during chemical reaction.
C + O2 → CO2
Reactants
Product
Representation of physical states of reactants and products:
• For solids it is
"(s)".
• For liquids it is
"(l)".
• For gases it
is "(g)".
• For aqueous solutions it is
"(aq)".
• For gas produced in the
reaction it is "(↑)".
• For precipitate formed in the
reaction it is "(↓)".
• Direction of reaction is
indicated by "(→)".
Example:
Zn (s) + dil.H2SO4 (aq) → ZnSO4
(aq) + H2 (g) (↑)
(Reactants)
(Products)
A chemical equation is helpful to understand a chemical reaction in a easy way.
In a chemical equation the masses of reactants and products may or may not be
equal. But according to law of conservation of mass "the total
mass of the reactants and the products should be equal".
So in order maintain the law true it is necessary to balance a chemical
equation.
Steps involved in balancing of chemical equation:
• Determining the reactants and
products in a reaction.
• Counting the number of atoms
of each element on both sides of the equation.
• Selecting the elements that
occur for the least number of times in the equation.
• Balance atoms of each element
on both sides of the reaction.
• Always leave hydrogen and
oxygen for last to balance.
• Balance the hydrogen atoms
lastly followed by balancing of oxygen atoms.
Example:
Formation of Ammonia:
N2 + H2 →
NH3 (Un-balanced equation)
Step 1: 2-Nitrogen atoms, 2-Hydrogen atoms → 1 –Nitrogen atom, 3-Hydrogen atoms
Step 2: In the above equation number of Nitrogen atoms on both sides are
not equal, multiply with suitable integer to balance the Nitrogen atoms on both
sides.
So, multiply with "2" on the product side.
N2 + H2 →
2NH3
In the above equation the number of Nitrogen atoms were balanced.
Step 3: Hydrogen atoms on both sides were not balanced. So, multiply with
suitable integer.
Multiply with "3" to Hydrogen on reactant side.
N2 + 3H2 →
2NH3
Now the above equation is balanced.
Reaction of potassium hydroxide with sulphuric acid:
Write down the equation
KOH + H2SO4 → K2SO4 + H2O
(This is not balanced equation)
Check the number of atoms of each element on both sides
Potassium (K) Atoms on both sides are not equal, balance the Potassium atoms by
multiplying with suitable integer.
2KOH + H2SO4 → K2SO4 + H2O
Now Potassium atoms on both sides are balanced.
Number of Hydrogen atoms on both sides is not equal, balance hydrogen atoms by
multiplying with suitable integer.
2KOH + H2SO4 → K2SO4 + 2H2O
Now Hydrogen atoms on both sides are balanced. And Oxygen atoms on both sides
get balanced.
This is balanced equation as atoms of all elements on both sides are balanced
2KOH + H2SO4 → K2SO4 + 2H2O
Types of Chemical Reactions
In general
chemical reactions are classified into:
-
Combination reactions
-
Decomposition reactions
-
Single displacement reactions
-
Double displacement reactions
Combination reactions:
A combination reaction is one in which two or more reactants combine to
form a single product. Combination reactions are again of three types.
They are:
Combination reactions between elements.
Combination reactions between compounds.
Combination reactions between elements and compounds.
Combination reactions between elements:
In these reactions elements were combined to form a product.
Examples :
Formation of calcium oxide by the combination elements calcium and oxygen.
2Ca + O2 → 2CaO
Formation of ammonia by the combination of elements nitrogen and hydrogen.
N2 + 3H2 → 2NH3
Combination reactions between compounds:
In these reactions compounds were combined to form product.
Example:
Reaction of calcium oxide in water to form calcium hydroxide
CaO + H2O → Ca(OH)2
Combination reactions between elements and compounds:
In these reactions elements and compounds combined to form product.
Example:
Formation of sulphur trioxide by the combination of sulphur dioxide and oxygen.
2SO2 + O2 → 2SO3
Decomposition reaction:
Decomposition reactions are those in which a substance splits into two or
more simpler substances. Decomposition reactions are the opposite of
combination reactions. Decomposition reactions are of three types:
-
Thermal decomposition
-
Electrolysis
-
Photolysis
Decomposition by the application of heat on a substance is called thermal
decomposition.
Example:
Thermal decomposition of calcium carbonate.
CaCO3 + Δ (Heating) → CaO + CO2
Decomposition of any substance by passing current through it is
called electrolysis.
Example:
Electrolysis of water
2H2O →
2H2 + O2
The decomposition reaction resulting from action of light energy is called
photolysis.
Example:
Photolysis of silver chloride
2AgCl → 2Ag + Cl2
Single displacement reaction:
Single displacement reaction is the one in which one element substitutes or
displaces another element in a compound to give new
compound. Generally in a single displacement reaction, less
active metal is displaced by a more active metal.
It is important
to note that in a single displacement reaction, one of the reactants is always
an element.
Example:
The reaction of magnesium with copper chloride
Mg + CuCl2 → MgCl2 + Cu
Double displacement reaction:
The reactions which involves exchange of ions (cations and anions) between
the reactants are called double displacement reactions.
AB + CD → AC + BD
Example:
Double displacement reactions classified into different types. They
are:
- Neutralization
reactions
- Precipitation
reactions
- Gas forming
reactions
Neutralization reaction:
Reaction in which
hydrogen ions of an acid react with hydroxide ions of a base to form water is
an neutralization reaction.
Example : The reaction of hydrochloric acid
with sodium hydroxide.
H+Cl– + Na+OH– → Na+Cl– +
H2O
Precipitation reaction:
Reactions which proceeds through the formation of precipitation are called
precipitation reactions.
Example:
In the reaction of barium chloride with sodium sulphate produces precipitate of
barium sulphate along with formation of sodium chloride.
BaCl2 (aq) + Na2SO4 (aq) →
BaSO4 (s) + NaCl (aq)
Gas forming reaction:
In these reactions gas is produces as one of the product during reaction.
Example:
Na2CO3 (s) + 2HCl (aq) →
2NaCl (aq) + H2O (l) + CO2 (g)
Based on energy differeneces between reactants and products the chemical
reactions are classified into two types. They are exothermic reaction and
endothermic reaction.
Exothermic reaction:
Chemical reactions in which heat energy released are known as exothermic
reactions.
Burning of methane gas in air produces heat energy.
CH4 (g) + 2O2 (g) → CO2 (g) +
2H2O (l)+ heat
All combustion reactions are exothermic
reactions.
Endothermic reaction:
Reactions which involves absorption of energy are known as endothermic
reactions.
Example:
Formation of nitric oxide from nitrogen and oxygen.
N2 (g)+ O2 (g) +
Heat → 2NO
Combustion reaction:
Burning of a substance in the presence of oxygen which resulting
release of energy is called combustion.
Example:
Combustion of ethylene gas.
C2H4 + 3O2 → 2CO2 +
2H2O
Oxidation reaction:
Oxidation reaction involves the addition of oxygen or the removal of
hydrogen from a substance.
Example:
Rusting of iron
Rusting of iron:
Iron when reacted with both water and oxygen are present (moist air),
corrodes. Its silvery colour changes to a reddish-brown, because hydrated
oxides are formed which is commonly called as rust.
Reaction showing the formation of rust when reacted with water in presence of
oxygen
(atmosphere).
4Fe + 3O₂+ XH₂O → 2Fe₂O₃.XH₂O
Reduction reaction:
The reaction which involves addition of hydrogen or removal of oxygen from
a substance is called reduction reaction.
Example:
Photosynthesis is a reduction reaction.
Redox reaction:
The reactions in which both oxidation and reduction occurring together
are known as redox reactions.
Example:
CuO + H2 → Cu + H2O
The above is a redox reaction as copper is reduced and hydrogen is
oxidised.
Acids Base and Salt
Acids
The
word "acid" comes from the Latin word "acidus" which
means sour.
According to Arrhenius theory an acid is a substance which ionizes and gives hydrogen
ions when dissolved in water
Example: Hydrochloric acid in water releases H+ ions.
HCl + H2O → H+ (aq) +
Cl–(aq)
A hydrogen ion cannot exist on its own, so it combines with a water molecule to
form a hydronium ion.
Example: Hydrochloric acid when dissolved in water liberates a hydrogen
ion and a chloride ion. The hydrogen ion combines with water to form a
hydronium ion.
HCl + H2O → H3O+ (aq) +
Cl–(aq)
Classification of acids:
Classification of acids based on source:
Based on the source the acids were classified into two types. They are organic
acids and in-organic acids.
Organic acids:
Acids obtained
from food like curd, lemons, grapes, raw mango, citrus
fruits and gooseberry are called organic acids.
In-organic acids:
Acids which are synthesised in the laboratory are called as in-organic
acids or mineral acids
Following table is the list of some acids which are used in the laboratory.
|
Name of the
acid
|
Chemical
formula
|
|
Sulphuric acid
|
H2SO4
|
|
Nitric acid
|
HNO3
|
|
Hydrochloric
acid
|
HCl
|
|
Acetic acid
|
CH3COOH
|
Classification of acids based on
concentration:
The word concentration indicates the quantity of acid in relative to the
quinatity of water in the aqueous solution of that acid.
Highly concentrated acid contains high percentage of acid in comparision with
water in that solution.
Low concentrated acid contains low percentage of acid in comparision with water
in that solution.
Dilution of acid:
Mixing an acid with water reduces the concentration of hydronium ions of
the acid per unit volume. This is called dilution of acid. The action of acids
with water is exothermic as heat is generated on dilution.
Classification of acids based on strength:
Based on ionisation, the acids were classified into strong acids and weak
acids.
Strong acids: Acids which ionises complely into its ions are called strong
acids.
Example: HCl, H2SO4, HNO3...etc
Weak acids: Acids which ionises partially into its ions are called weak acids.
Example: CH3COOH, H2CO3...etc
Classification of acids based on basicity of acids:
Based on basicity acids were classified into different types. They are
Mono-basic acids
Di-basic acids
Tri-basic acids
Mono-basic acids:
Acids which on ionisation produces on hydronium ion in water are termed as
mono-basic acids.
Example: HCl
Di-basic acids:
Acids which on ionisation produces two hydronium ions are called as
di-basic acids.
Example: H2SO4, H2CO3..etc
Tri-basic acids:
Acids which on ionisation produces three hydronium ions are called
astri-basic acids.
Example: H3PO4, H3PO3..etc
Properties of acids:
Acids have corrosive action on skin.
Acids are good conductors of electricity.
Acids neutralizes bases to form salt and water.
Chemical properties of acids:
Reaction of acids with active metals:
Acids reacts with metals to form metal salts. In this
reaction, hydrogen gas is liberated.
Example: In the reaction of hydrochloric acid reacts with zinc produces
hydrogen gas and zinc chloride.
2HCl + Zn → ZnCl2 + H2
Reaction of acids with metal
carbonates:
Acids reacts with metal carbonates to form corresponding
salts, carbon dioxide and water.
Example: Hydrochloric acid on reaction with sodium carbonate forms sodium
chloride, carbon dioxide and water.
2HCl + Na2CO3 → 2NaCl + CO2 + H2O
Reaction of acids with metal hydrogen
carbonates:
Acids reacts with metal hydrogen carbonates and form
corresponding salts, carbon dioxide and water.
Example: Hydrochloric acid on reaction with sodium bicarbonate forms
sodium chloride, carbon dioxide and water.
HCl + NaHCO3 → NaCl + CO2 + H2O
Reaction of acids with metal
oxides:
Acids reacts with metal oxide to form salt and water.
Example:
Sulphuric acid on reaction with cupric oxide forms copper sulphate and water.
CuO + H2SO4 → CuSO4 + H2O
Indicators:
An acid base indicator is a substance which exhibits
different colour in acids and bases.
Red cabbage is a visual indicator used to detect acids.
Onions are called olfactory indicators. They change their odour with
change in the nature of solution.
Litmus is a natural indicator and is extracted
from lichens.
Apart from natural indicators there are a few synthetic indicators, such
as methyl orange and phenolphthalein.
Following table gives colours of the indicators in presence of acids and bases.
|
Indicator
|
Acid
|
Base
|
|
Methyl
orange
|
Red
|
Yellow
|
|
Phenolphthalein
|
Colourless
|
Pink
|
|
Blue
litmus paper
|
Red
colour
|
No Change
|
|
Red
litmus paper
|
No change
|
Blue
colour
|
Universal
indicator is a mixture of different number of indicators which shows different
colours in different solutions.
Uses of acids:
- Sulphuric acid is used in the manufacture of fertilisers, paints, dyes, chemicals , plastics
and synthetic fibres.
- Sulphuric
acid is also used in car batteries.
- Nitric
acid is used in the manufacture of
fertilizers, explosives like TNT, dyes and drugs.
- Hydrochloric
acid is used before galvanizing, to remove oxide
film from steel and also as a descaling
agent for boilers. It is also used in
the textile, leather and food industry.
- Hydrochloric
acid used in the manufacture of glucose from corn starch.
- Ethanoic
acid (CH3COOH) is used for coagulating latex to prepare rubber
from it. It is also used in the preparation of perfumes.
- Boric acid
(H3BO3) is useful as an antiseptic and insecticide.
- Boric
acid is useful as a flame retardent.
- Carbonic
acid (H2CO3) is useful in the form of
carbonated drinks
Bases
According
Arrhenius theory any substance that can produce hydroxide ions when
dissolved in water is called as a base.
Substance + Water → Metal ion +
OH–
Example:
NaOH (aq) → Na+ (aq) +
OH– (aq)
A base is said to be an alkali if it is soluble in water. In general hydroxides
of alkali metals and alkaline earthmetals are considered as alkalies.
Example:
KOH (aq) → K+(aq)
+ OH– (aq)
Ca(OH)2(aq) →
Ca+2 (aq) + OH– (aq)
It is not a necessary that a base should contain hydroxide ion.
There are some bases even they does not contain hydroxide ion, can be
considered as bases.
Example: Ammonia (NH3)
Ammonia when dissoled in water forms ammonium hydroxide which is a weak base.
NH3 + H2O → NH4OH (aq)
Oxides of alkali metals and alkaline earthmetals are also considered as basic
in nature.
Example: CaO, MgO, Na2O, K2O...etc
Classification of bases:
Classification based on the strength:
Based on the extent of ionisation bases are classified into strong bases and
weak bases.
Strong bases:
The bases which undergoes complete ionisation in aquesous solution are
called as strong bases.
Example: NaOH, KOH...etc
Weak bases:
The bases which undergoes partial ionisation in aqueous solution are
called weak bases.
Example: NH4OH, NH3...etc
Classification of based on acidity:
Based on acidity bases can be classified into different types. They are:
Mono acidic base
Di acidic base
Tri acidic base
Mono acidic bases:
Bases which produces only one hydroxide (OH-) ion in aqueous
solutions are called mono acidic bases.
Example: NaOH, KOH...etc
Di acidic bases:
Bases which produces two hydroxide ions in aqueous solutions are called di
acidic bases.
Example: Ca(OH)2, Mg(OH)2...etc
Tri acidic bases:
Bases which produces three hydroxide ions in aqueous solutions are
called tri acidic bases.
Example: Al(OH)3, Fe(OH)3...etc
Physical properties of bases:
• Bases are bitter to taste,
soapy to touch.
• Bases are good conductors of
electricity in aqueous solution. In aqueous solution, they release ions, which
conduct electricity.
• Bases liberates heat
on dilution.
Indicators in pressence of bases:
Bases turns red litmus to blue.
Phenolphthalein turns pink in pressence of bases.
Methyl orange turns to yellow in pressence of bases.
Chemical properties:
Reaction with active metals:
Bases react with metals to liberate hydrogen gas
Example: Sodium hydroxide react with zinc and liberate hydrogen and
sodium zincate.
NaOH + Zn → Na2ZnO2 + H2
Reaction with
non-metal oxides:
Bases react with non-metallic oxides to form salt and
water. This is similar to a neutralization reaction between an acid
and a base.
Example: Calcium hydroxide reacts with carbon dioxide to form calcium carbonate
and water
Ca(OH)2 + CO2 → CaCO3 + H2O
From this reaction, it can be concluded that non-metallic oxides
are acidic in nature.
Reaction with acids:
Bases reacts with acids to form salts and water.
Example:
Potassium hydroxide reacts with hydrochloric acid to form potassium chloride
and water.
KOH + HCl → KCl + H2O
Uses of Bases:
• Mild
bases neutralise the acidity in the stomach.
• Sodium hydroxide is used in
the manufacture of soaps, paper and synthetic
fibres like rayon.
• Calcium hydroxide is used in
the manufacture of bleaching powder. Bleaching powder is used as
a disinfectant.
• Magnesium hydroxide is used
as an antacid to neutralize the acid in the stomach.
• Ammonium hydroxide is used in
the preparation of fertilizers like ammonium
phosphate and ammonium sulphate.
Strength of Acids and Bases
Neutralization is
a chemical reaction in which an acid reacts with
a base to form salt and water. In this process,
a hydrogen ion of the acid combines with a hydroxide ion of
the base to form a water molecule. The anion of the acid combines
with the cation of the base to form a salt.
For example when hydrochloric acid reacts with sodium hydroxide the chlorine of
hydrochloric acid combines with sodium of sodium hydroxide to form sodium
chloride. The hydrogen of hydrochloric acid combines with the hydroxyl part of
the sodium hydroxide and forms water.
HCl + NaOH → NaCl + H2O
Strength of acids or bases:
Based on extent of ionization acids and bases are classified into strong
acids, weak acids and strong bases, weak bases.
Strong acids or strong bases ionizes completly (100%) to form
ions in the aqueous solution.
Example:
Hydrochloric acid ionizes completly to form ions.
HCl (aq) → H+(aq) + Cl–(aq)
Sodium hydroxide ionizes completly to form ions.
NaOH (aq) → Na+ (aq) + OH– (aq)
Weak acids or weak bases ionizes partially
(<100%) to form ions in the aqueous solution.
Example:
Acetic acid ionizes partially in aqueous solution to form ions.
CH3COOH (aq) ⇔ H+(aq) + CH3COO– (aq)
Ammonium hydroxide ionizes partially in aqueous solution to form ions.
NH4OH ⇔ NH4+ + OH– (aq)
An acid or base is considered as strong or weak depending on the concentration of hydrogen and hydroxide ions within
it.
This concentration or the power of hydrogen differs from
substance to substance and can be measured using a scale, called the pH
scale.
A solution that has a pH value of less than 7 is acidic and a
solution with a pH value of more than
7 is basic. A neutral solution is indicated by
a pH value of 7 on the scale.
Strong acids will posses pH values between
0-2 and weak acids posses pH values more than 3.
Strong bases will posses pH values between
12-14 and weak bases posses pH values less than 12.
pH of some of the acids and bases:
|
|
pH
|
|
Hydrochloric
acid
|
0.1 - 1.0
|
|
Sulphuric acid
|
1.0 - 1.2
|
|
Phosphoric acid
|
1.3 -1.5
|
|
Acetic acid
(Vineger)
|
2.9 - 3.0
|
|
Carbonic acid
|
3.8 - 4.0
|
|
water
|
6.9 - 7.0
|
|
Ammonia
|
10.8 -
11.2
|
|
Sodium
hydroxide
|
13 - 14
|
- Antacids like Milk
of Magnesia are mild bases that neutralize the acids in
the stomach and aid digestion.
- If the pH
lowers, the acidity in the mouth increases and leads
to tooth decay. Toothpastes are basic in
nature and they counteract the acid in the mouth.
- Hydrangea produces pink
flowers when the soil has a pH value of 6.8 or higher
and blue flowers when the pH value is 6.0 or less.
- If
the soil is acidic, then the
applied pesticides, herbicides and fungicides will
not be absorbed by the soil. In order to neutralize the
soil, suitable bases are used. Generally, salts of calcium
or magnesium, which are basic are used to neutralize soil
acidity.
- When
a bee stings, formic acid is released. That is what makes
the skin burn. Baking soda, which is a
base, neutralizes the formic acid and provides relief from the
pain.
Salts and their Properties
The compounds
formed by the reaction between an acids and a bases
are known as a salts.
Acid + Base → Salt +
Water
Salts are ionic compounds which contain positively
charged cations and negatively charged anions. During salt
formation cation is coming from base and anion is coming from acid.
Example: In Sodium chloride (NaCl) formation cation sodium is coming
from sodium hydroxide and anion chlorine is coming from hydrochloric acid.
Classification of salts:
Based on nature the salts have been classified into different types. They
are:
Normal salts
Acidic salts
Basic salts
Double salts
Complex salts
Normal salts:
These salts are formed by the complete replacement of hydrogen in acids by
other metal cations from the bases.
NaCl is normal salt formed by the reaction of HCl with NaOH.
HCl + NaOH → NaCl + H2O
Acidic salts:
Salts which are formed by the partial replacement of hydrogens atoms of
acids are called acidic salts.
Example:
NaHSO4 is formed when partial replacement of hydrogen atoms by the sodium atoms
of base.
H2SO4 + NaOH → NaHSO4 + H2O
In general these salts formed when the reacted base is not sufficient for the
neutralisation of acid.
Basic salts:
Salts which are formed by the partial replacement of hydroxyl group are
called basic salts.
Example:
Ca(OH)Cl is formed by the partial replacement of hydroxide group from Ca(OH)2
by chloride ions of acid.
Ca(OH)2 + HCl → Ca(OH)Cl + H2O
In general these salts formed when the reacted acid is not sufficient for the
neutralisation of base.
Table below giving neutral, acidic and basic salts.
|
Type
of Salt
|
Type
of Acid
|
Type
of Base
|
Example
|
|
Neutral
pH = 7
|
Strong
Acids
Examples:
HCl
H2SO4
|
Strong
Bases
Examples:
NaOH
KOH
|
NaCl
K2SO4
|
|
Acidic
pH < 7
|
Strong
Acids
Examples:
HCl
HNO3
|
Strong
Bases
Examples:
NH4OH
Mg(OH)2
|
NH4Cl
Mg(NO3)2
|
|
Basic
pH > 7
|
Weak
Acids
Examples:
H2CO3
CH3COOH
|
Strong
Bases
Examples:
NaOH
KOH
|
Na2CO3
CH3COOK
|
Double salts:
Salts that are formed by mixing of two simple salts which are obtained
crystallisation.
Example:
Potash alum - K2SO4 Al2 (SO4)3 .24H2O
Dolomite - CaCO3.MgCO3
Complex salts:
The salts which contains different types of metal atoms which on
hydrolysis produces complex ions along with simple ions are called complex
salts.
Example:
[Ag(NH3)2]Cl ⇄ [Ag ( NH3 )2 ]+ +
Cl-
Salts in our daily life:
Baking soda
Chemical name: Sodium hydrogen carbonate
Molecular formula: NaHCO3
Sodium hydrogen carbonate is commenly called as baking soda.
Sodium hydrogen carbonate is used in the baking industry.
It is used in preparation of soda acid.
It is also used in foam type fire extinguishers.
Washing soda:
Molecular formula: Na2CO3.10H2O
Chemical formula: Sodium carbonate.decahydrate
Adding water to sodium carbonate and this allowing this mixture to cool to
forms decahydrated sodium carbonate. This is commenly called as washing soda.
Na2CO3 + 10H2O → Na2CO3.10H2O
In general sodium carbonate is prepared by passing CO2 gas
through concentrated NaOH.
2NaOH + CO2 → Na2CO3 + H2O
Properties:
It is a white crystalline solid. It exists as decahydrate of sodium
carbonate.
When exposed to dry air and heating it loses water molecules to change into
anhydrous form.
Na2CO3.10H2O + Exposure to open dry air →
Na2CO3.H2O + 9H2O
Na2CO3.H2O + Heating → Na2CO3
It is soluble in water and during dilution heat will releases out.
On reaction with acids sodium carbonate releases carbon dioxide along with the
formation of sodium salts and water.
Na2CO3 + HCl → 2NaCl + H2O + CO2
Sodium carbonate is used to manufacture of glass, cleansing agents, soap, glass and paper.
Bleaching powder (CaOCl2):
Bleaching powder chemically known as calcium oxy chloride.
It is prepared by the reaction between chlorine and slaked lime at about
40 0C.
Ca(OH)2 + Cl2 → Ca(OCl)Cl + H2O + Cl2
Ca(OH)2 + H2SO4 → CaSO4 +
H2O + Cl2
It acts a strong oxidising agent to bleach substances.
CaOCl2 + KNO2 → CaCl2 + KNO3
CaOCl2 + H2S → CaCl2 + H2O
+ S
It is used to bleach cotton, linen textiles and wood
pulp.
Coloured matter + Bleaching powder → Colourless product
It is also used to disinfect drinking water.
Hydrated salts:
The molecules of salts which contain fixed number of water
molecules in them are called hydrated salts.
In general they exists as dry in pure form.
These salts on heating loses water molecules in them and forms anhydrous salts.
Example:
Ferrous sulphate heptahydrate (FeSO4.7H2O) on heating
loses water molecules in it.
FeSO4.7H2O
(on heating) → FeSO4 + 7H2O
Some of the hydrated salts along with their chemical formula.
|
Name of the salt
|
Chemical formula
|
|
Sodium
carbonate decahydrate
|
Na2CO3.10
H2O
|
|
Zinc
Sulphate heptahydrate or White vitriol
|
ZnSO4.7H2O
|
|
Magnesium
sulphate heptahydrate or Epsom salt
|
MgSO4.7H2O
|
|
Potash
alum
|
K2SO4 Al2 (SO4)3 .24H2O
|
|
Copper
(II) sulphate pentahydrate or Blue vitriol
|
CuSO4.5H2O
|
|
Calcium
sulphate dihydrate or Gypsum
|
CaSO4.2H2O
|
Plaster of paris (CaSO4. 1 2 H2O):
Plaster of paris which is chemically called calcium sulphate
hemihydrate.
Since it is brought to use from paris, called as "plaster of paris".
It is prepared by heating of gypsum at 373K.
CaSO4.2H2O 373 K →
CaSO4 1 2 H2O
+ 1 1 2 H2O
Gypsum
Plaster of Paris
Water
Uses:
It is used as a bandage, proofing material, sealing
agent.
It is used for making statues, toys and decorative
articles.
It is also used for smoothening wall surfaces.
Metals and Non-metals
Metals and Non-metals
Metals:
In general metals can be defined as the elements which have a
tendency to lose electrons and form positively charged ions or cations.
Example: sodium has an electronic configuration of 2,8,1. During a
chemical reaction, sodium can lose an electron to a non-metal like chlorine to
form a sodium ion that has an electronic configuration of 2,8.
Physical
properties of metals:
Physical state:
All metals are solids at room temperature.
Example: Iron and copper.
The one exception is mercury, which is a liquid.
Lustrous nature:
All metals are lustrous. Metal surfaces shine when they are freshly
cut.
Example: Gold and silver are popularly used for making jewellery because
of their lustrous nature.
Density:
Metals have high densities and, therefore, tend to sink in water.
Example: Tin and lead sink in water.
Exceptions to this rule are lithium, sodium and potassium. The density of these
elements is lower than that of water and hence they do not sink.
Malleability:
Metals are highly malleable, and can be beaten into thin sheets.
Example: Aluminium and zinc can be rolled into thin sheets. This property
makes them suitable for use in various industries like construction and
manufacturing.
Ductility:
Metals are highly ductile and can be drawn into wires.
Example: Copper and silver can be drawn into thin wires.
Conductivity:
Metals are good conductors of heat and electricity. Copper wires are
commonly used in electric cables because of this property.
Melting point:
Metals have high melting points.
Example: Tungsten has a high melting point, due to which it is used in
bulb filaments.
Mercury is an exception to this property, since it has a low melting point.
Chemical
properties of Metals:
Metals react with non-metals to form ionic compounds.
Example: Sodium reacts with chlorine to form sodium chloride.
2Na + Cl2 →
2NaCl
Reaction
of metals with oxygen:
Most of the metals combine with Oxygen to form basic metal oxides.
Example: When magnesium burns in oxygen it forms magnesium oxide.
2Mg + O2 → 2MgO
Metal oxides of alkali metals soluble in water to form hydroxide solutions,
called alkalies.
Example: Sodiumoxide soluble in water to form sodium hydroxide.
2Na2O + H2O
→2 NaOH
Reaction
of metals with water:
Sodium, potassium reacts vigorously even with cold water.
2Na +
2H2O → 2NaOH + H2
2K +
2H2O → 2KOH + H2
Calcium reacts slowly with cold water. And can react vigorously with hot water.
Ca +
2H2O → Ca(OH)2 + H2
Magnesium does not reacts with cold water. It reacts very slowly with hot water
but reacts vigorously with steam.
Mg +
2H2O → Mg(OH)2 +
H2
Iron and zinc do not react either with cold or hot water but react with steam.
Zn + H2O → ZnO + H2
Fe + H2O → FeO + Fe2O3 + H2
Aluminum do not reacts either with cold water, hot water and even steam because
of its protective oxide layer.
Metals like Lead, Copper, Gold and Silver do not show any reaction with water.
Non-metals:
Non-metals are elements that have a tendency to accept electrons to form
negatively charged ions or anions.
Example: Chlorine has an electronic configuration of 2,8,7. During a
chemical reaction, chlorine can accept an electron from a metal like sodium to
form a chloride ion. A chloride ion has an electronic configuration of 2,8,8.
Physical
properties of non-metals:
Physical state:
Non-metals exist as solids, liquids and gases.
Example: Silicon and carbon are solids; bromine is a liquid; chlorine, fluorine
and oxygen are gases.
Lustrous nature:
Non-metals are non-lustrous and have a dull appearance in nature.
Density:
Most of the non-metals have very low density.
Example: Oxygen and nitrogen are lighter than air.
Exception is diamond, a form of carbon. Diamond is one of the strongest known
substances.
Non-metals are not malleable.
Non-metals are bad conductors of heat and electricity.
Exception is graphite, a form of carbon which
is a good conductor of electricity.
Non-metals have low melting and boiling points.
Example: Sulphur and Phosphorus have low melting and boiling points.
Chemical
properties of non-metals:
Formation
of covalent compounds:
Reaction between non-metals produces covalent compounds.
Example: Hydrogen and chlorine reacts with each other form hydrogen chloride
H2 + Cl2 → 2HCl
Reaction
of non-metals with oxygen:
Non-metals reacts with oxygen to form oxides which are either acidic or neutral
in nature.
Example:
Sulphur reacts with oxygen to form sulphur dioxide which is acidic in nature
S + O2 →
SO2
Nitrogen reacts with limited supply oxygen to form nitric oxide which is a
neutral oxide in nature.
N2 + O2 → 2NO
Non-metal oxides dissolves in water to form acidic solutions.
Example:
Sulphur dioxide dissolves in water to form sulphurous acid.
SO2 +
H2O → H2SO3
Non-metals are good oxidizing agents.
Example: Sulphur in hydrogen sulphide undergoes oxidation when hydrogen
sulphide reacts with chlorine.
H2S + Cl2 → 2HCl + S
Metals and non-metals are separated through electrolysis
Activity Series
The arrangement
of metals in the decreasing order of
their reactivity is known as activity series. In the
activity series highly reactive metals placed at the top and least reactive
metals placed at the bottom.
Gold placed at bottom of the series is the least reactive among the metals and
potassium placed at the top is the highly reactive metal. Hydrogen is the
non-metal included iin order to compare the reactivity of metals.
The metal placed higher in the series can displace the other
metal from its salt solution. Thus potassium can displace all other
metals from their salt solutions.
Example: Potassium can displace hydrogen from the acids.
2K + 2HCl →2KCl + H2
Metals of low reactivity cannot displace high reactive metals from their salts.
For this reason oxides of highly reactive
metals like magnesium and aluminium are
not reduced easily either
by hydrogen, carbon or carbon monoxide.
Metals that are placed below copper do not rust easily because
of their low reactivity.
Reactivity towards oxygen:
On moving down in the reactivity series the reactivity with oxygen
decreases.
Metals like potassium, sodium, calcium, magnesium and aluminium can react with
oxygen at room temperatures.
Potassium can react with oxygen to form its super oxide in addition to
oxide.
K + O2 → KO2
4K + O2 → 2K2O
Sodium on reaction with oxygen forms metal oxide as well as metal peroxide.
4Na + O2 → 2Na2O
2Na + O2 → Na2O2
Calcium, magnesium and aluminum on reaction with oxygen forms their metal
oxides.
2Ca + O2 → 2CaO
2Mg + O2 → 2MgO
4Al + 3O2 → 2Al2O3
Reactivity towards water:
While moving down in the activity series the reactivity towards water
decreases.
Potassium, sodium and calcium can reacts vigorously even with cold water with
the liberation of hydrogen gas.
K + H2O → KOH + H2
Na + H2O → NaOH + H2
Ca + H2O → Ca(OH)2 + H2
Magnesium reacts very slowly with cold water but can reacts vigorously
with hot water to produce hydrogen gas
Mg + H2O → MgO + H2
Metals like aluminium, zinc and iron does not reacts with cold water or warm
water but can reacts with hot steam.
2Al + H2O → Al2O3 + H2
Zn + H2O → ZnO + H2
3Fe + H2O → Fe3O4 + H2
Reactivity towards mineral acids:
The metals which are present above hydrogen in the reactivity series can
reduce hydrogen ions from the acids like HCl and H2SO4.
Reactivity decreases on moving down the group in the series.
Potassium, sodium reacts vigorously with dilute acids to liberate hydrogen gas.
K + 2HCl → 2KCl + H2
Na + 2HCl → 2NaCl + H2
Calcium, magnesium also reacts vigorously but slowly with acids libearating
hydrogen gas.
Ca + 2HCl → CaCl2 + H2
Mg + 2HCl → MgCl2 + H2
Metals below to hydrogen in the series does not liberate hydrogen on reaction
with concentrated or diluted acids.
Ore:
Metals are available in the form of their ores.
Ore is a mineral which contains high percentage of metal from which a metal can
be extracted most economically.
Methods of extraction of metals from ore are based on the reactivity
of metals.
Methods of extraction:
• Reduction
• Electrolysis
Reduction is the process of removal of
oxygen for extraction of metals from their oxide
ores. The common reducing agents used for reduction of
metal oxides are:
• Carbon monoxide
• Carbon
• Hydrogen
Examples:
During the extraction of iron from its oxide:
Iron oxide is reduced to iron by carbon monoxide.
FeO + CO → Fe + CO2
Iron oxide is reduced to iron using carbon as the reducing agent.
FeO + C → Fe + CO
During the extraction of copper from its oxide:
Copper oxide is reduced to copper using carbon as the reducing agent.
CuO + C → Cu + CO
Copper oxide is reduced to copper using hydrogen as the reducing agent.
CuO + H2 → Cu + H2O
But oxides of potassium, sodium, lithium, barium,calcium, magnesium and
aluminum cannot be reduced by using carbon, carbon monoxide and hydrogen
because of their high affinity for oxygen.
Important ores of Aluminium:
• Bauxite:
Chemial formula is: Al2O3.2H20
• Bauxite is the
principal ore of aluminium.
• Corundum: Chemial formula is: Al2O3
•
Cryolite: Chemial formula is: Na3AlF6.
The extraction of aluminium from bauxite involves three steps:
• The purification of
bauxite using Bayer’s process.
• The electrolytic
reduction of anhydrous Al2O3 by Hall
and Herault’s process.
• The last step is
the purification of impure aluminium by Hoope’s
process
Aluminium is used in:
•
Manufacture of automobile components
• Construction process
• Manufacture of
electric wires
• Packing
medicines and pharmaceutical products
• Manufacture of soft drink
cans and espresso coffee makers
• Manufacture of utensils
Alloy:
An alloy is a homogeneous mixture of solid
solution of two or more metals or metals with non-metals.
Duralumin is a light and tensile alloy of
aluminium. Duralumin is used in the making of air craft
frames, pressure cookers.
Magnalium is an alloy of aluminium and
magnesium. Magnalium is used in the making of balances because
of its high structural strength and resistance to
corrosion. It is also used in the making of optical
instruments like cameras and microscopes due to
its light weight and resistant to corrosion.
Some important
alloys:
|
Name of
the Alloy
|
Composition
|
Properties
|
Uses
|
|
Brass
|
Cu: 80%
Zn: 20%
|
It is generally
strong resistant to corrosion and easily moulded into different shapes.
|
In making of
utensils, pipes and radiator statues etc
|
|
Bronze
|
Cu: 90%
Sn: 10%
|
It is very
strong in nature and also posses good resistance property.
|
In making of
coins, ornaments, utensils and statues
|
|
Stainless steel
|
Fe: 82%
(Ni + Cr): 18
|
Resistant to
water, air and alkalies.
|
In making of
surgical instruments, watches and utensils etc
|
|
Magnalium
|
Al: 95%
Mg: 5%
|
Very light in
weight and very hard in nature.
|
In making light
articles and physical balance etc
|
|
Duralumin
|
Al: 95%
Cu: 4%
Mn: 0.5%
|
It is very
strong in nature and very light in weight. And is resistant to corrrosion.
|
In making parts
of aeroplane and ship etc
|
Forms of Carbon
Forms of Carbon
Allotropy:
Allotropy is the property of an element to exist in more than one physical
forms having similar chemical properties but different physical
properties.
Carbon exists both in crystalline and amorphous allotropic
forms.
Crystalline allotropes of carbon:
Diamond
Graphite
Fullerene
Amorphous allotropes of carbon:
Coal
Coke
Charcoal
Lampblack
Gas carbon
Coke
Diamond:
Diamond is a rigid, compact, three dimensional structure.
Diamond is very hard to break.
Diamond is bad conductor of heat and electricity. Because in diamond each
carbon is bonded to four other carbon atoms. There are no free electrons
present in it.
Diamond are not attacked by acids, bases and other reagents but it can
reacts with fluorine to form carbon tetrafluoride at about 1023 K temperature.
C + 2F2 → CF4
Diamond burns in air at about 1173 K to produce carbon dioxide gas.
In diamond carbon atoms are in tetrahedral arrangement.
Uses:
Diamonds are used in glass cuttings and in making drills.
Diamond is widely valued in jewellary is used as an abrasive in sharpening
tools.
Diamond is also useful in die-making and in the manufacture of tungsten
filaments for light bulbs.
Because of reflection property it is used as gem in jewellery.
Graphite:
Graphite contains carbon atoms in hexagonal rings, which are joined to form
layers.
The layers of carbon can slide over each other.Graphite is a good conductor of
heat and electricity. Since graphite contains free electrons, it is
a good conductor of heat and electricity.
Graphite burns in air at about 973 K to produce carbon dioxide gas.
Uses:
Since graphite is a good conductor of electricity it is used as electrode.
Graphite is used as moderator in nuclear reactors.
It is also used as solid lubricant in machines.
Fullerenes :
Fullerene was discovered in the year 1985.
C60 is the very popular and stable form of the known
fullerenes. This consists of 60 carbon atoms arranged
in pentagons and hexagons, like in a standard football.
Fullerenes are also called Buckminsterfullerenes as they are shaped
like the geodesic dome designed and built by the US
architect Buckminster fuller.
Fullerenes are prepared from graphite at higher temperatures.
There exists other members of fullerenes like C70, C84...etc
Bonding in Carbon
In general carbon involves in covalent
bonding.
Covalent
bond:
A bond formed by the sharing of valence electrons between atoms of similar
electronegativity is called covalent bond.
Properties
of covalent compounds:
Covalent compounds have low melting and boiling points.
Covalent compounds are non conductors of electricity this is due to
the absence of free ions.
Classification
of covalent bonds:
Based on the number electrons shared between the atoms, the covalent bond is
classified into three types. They are:
• Single covalent bond
• Double covalent bond
• Triple covalent bond
Single
Covalent Bond:
Single covalent bond is formed by sharing a single pair of electrons.
Example: H2 (H - H)
Hydrogen has one electron and it requires one more electron to attain the
nearest inert gas configuration. To achieve this each hydrogen atom
contributes an electron to form a single bond. Thus, a single covalent bond is
formed between the two atoms of the hydrogen molecule.
Double
Covalent Bond:
Double bond is formed by the sharing of two pairs of electrons of the
valence shell.
Example: Oxygen molecule (O = O)
The atomic number of oxygen is 8. It requires two electrons to achieve the
nearest stable inert gas configuration, which is neon. To achieve this, two
oxygen atoms contribute two unpaired electrons to produce two bond pairs. Thus,
they share these two electron pairs to form a double bond
Triple
Covalent Bond:
Triple bond is formed by sharing of three pairs of electrons of the
valence shell.
Example : Nitrogen molecule (N ≡ N).
The atomic number of nitrogen is 7. It requires 3 more electrons for attaining
the nearest inert gas (neon) configuration. Thus, 2 nitrogen atoms combine
together and produce 3 bond pairs and share the three bond pairs between them.
Representation
of a Bond:
Bond formation can be represented using Lewis structures. The Lewis dot
structures provide a picture of the bonding in molecules in terms of the shared
pairs of electrons and the octet rule.
Example: Lewis dot structures of CCl4 and CH4.
Bond
Formation in Carbon:
From the electronic configuration of carbon, it is clear that it has to either
gain or lose four electrons, to attain noble gas configuration.
If carbon gains four electrons it would form a c-4 ion. It is unable to hold four
extra electrons. It would be difficult for the six protons to hold the ten
electrons.
Formation of C+4 is difficult as it requires high amount
of energy which leaves six protons in the nucleus and holding only two
electrons.
Thus formation of both C-4 and
C+4 forms is difficult.
Carbon overcomes this difficulty by sharing its electrons with other atoms of
carbon or with atoms of other elements. sharing of electrons results in a
covalent bond and the shared electrons belong to either of the atoms, this
sharing helps in achieving noble gas configuration.
Covalent
Bond Formation in Methane:
During the formation of a methane molecule carbon atom share its four
valence electrons with four hydrogen atoms. Thus in methane molecule there
exists four single bonds between carbon and four hydrogen atoms.
Double
bond formation of Carbon:
Carbon can involve in double bonding either with it self or with other atoms
like Oxygen.
Example:
Formation of CO2: Carbon shares its four valence electrons with
two oxygen atoms. Thus carbon forms two double bonds with two oxygen atoms.
Triple
bond formation of Carbon:
Carbon can involve in triple bonding either with it self or with other atoms
like Nitrogen.
Example:
Formation of HCN: Carbon shares three of its valence electrons with one
nitrogen atom to form triple bond with it. And shares one electron with one
hydrogen to form single bond with it.
Hydrocarbons
he existence of
such a large number of organic compounds is due to the unique properties of
carbon.
The unique properties of carbon are:
→ Tetra valency
→ Catenation
→ Formation of multiple bonds
Tetravalency:
Carbon shares its four valence electrons with other atoms and forms four single
covalent bonds to get nearest noble gas formation. This is known as
tetravalency.
Catenation:
The property of self linkage among identical atoms to form long
chain compounds is known as catenation.
Carbon exhibits maximum catenation, when compared to elements like sulphur and
silicon, due to strong carbon-carbon bonds and tetra valency. Due to this
catenation, carbon atoms can form various types of straight chains, branched
chains and ring structures.
Formation of multiple bonds:
Carbon atoms are capable of forming multiple bonds with other carbon atoms.
Hydrocarbons:
All the carbon compounds which contain just carbon and hydrogen are called
hydrocarbons.
Classification of hydrocarbons:
Hydrocarbons are broadly divided into two groups.
• Open chain hydrocarbons
• Cyclic or closed chain
hydrocarbons
Open chain hydrocarbons:
Open chain hydrocarbons contain carbon-carbon straight chains. They are further
classified into two types.
• Saturated hydrocarbons
• Unsaturated hydrocarbons.
Saturated hydrocarbons or Alkanes:
Saturated hydrocarbons are straight chain compounds containing only single
covalent bonds. These are also known as alkanes.
General formula of alkanes is CnH2n+2.
Example: Methane, ethane, propane, butane... etc.
Unsaturated hydrocarbons:
Unsaturated hydrocarbons are the straight chain compounds containing double or
triple covalent bonds.
Unsaturated hydrocarbons are classified into two types. They are alkenes and
alkynes.
Alkenes:
Hydrocarbons with a double bond between carbon atoms are known as alkenes.
General formula of alkenes is CnH2n.
Example: Ethene, propene, butene...etc
Alkynes:
Hydrocarbons with triple bonds between carbon atoms are known as alkynes.
General formula of alkynes is CnH2n-2.
Example: Ethyne, propyne...etc
Cyclic or closed chain hydrocarbons:
The compounds of carbon which contain a closed ring of carbon atoms are called
as cyclic hydrocarbons. They are of two types.
•
Alicyclic hydrocarbons
•
Aromatic hydrocarbons
Alicyclic Hydrocarbons:
Alicyclic hydrocarbons are in the form of a carbon cycle. They contain
three or more carbon atoms.
Example: Cyclopropane, Cyclo butane.
Alicyclic compounds does not follow Huckel's rule.
Aromatic Hydrocarbons:
The cyclic compounds which contain a single and a double bond at alternate
positions and exhibit special properties are known as aromatic compounds.
Huckel's rule (4n+2 rule): According to Huckel’s rule the hydrocarbons which
contains 4n+2 (where n = 0,1,2,3,…etc) number of delocalized pi electrons which
are present in a ring structure are called aromatic compounds.
Example:
Benzene: Benzene (C6H6) containing a six
membered carbon ring with alternate single and double bonds is an aromatic
compound.
Homologous Series:
A series of organic compounds with the same general formula but differ from
adjacent members by "-CH2-" group are referred to as
homologous series of compounds.
And successive members of homologous series differ from one another in
their mass by 14 units.
Example:
Homologous series of alkanes:
General formula of homologous series of alkanes is CnH2n+2.
|
Number of
carbon atoms
|
Molecular
formula
|
Structure of
the molecule
|
Name of the
alkane
|
Molecular mass
|
|
n =1
|
CH4
|
CH3-H
|
Methane
|
16
|
|
n =2
|
C2H6
|
CH3-CH2-H
|
Ethane
|
30 (16+14)
|
|
n =3
|
C3H8
|
CH3-CH2-CH2-H
|
Propane
|
44 (30+14)
|
|
n=4
|
C4H10
|
CH3-CH2-CH2-CH2-H
|
Butane
|
58 (44+14)
|
|
n=5
|
C5H12
|
CH3-CH2-CH2-CH2-CH2-H
|
Pentane
|
72 (58+14)
|
|
n =6
|
C6H14
|
CH3-CH2-CH2-CH2-CH2-CH2-H
|
Hexane
|
86 (72+14)
|
|
n = 7
|
C7H16
|
CH3-CH2-CH2-CH2-CH2-CH2-CH2-H
|
Heptane
|
100 (86+14)
|
Homologous series of alcohols:
CH3 - OH : Methanol
CH3-CH2-OH : Ethanol
CH3-CH2-CH2-OH : Propanol
CH3-CH2-CH2-CH2-OH : Butanol
The difference between methanol and ethanol, the difference between ethanol and
propanol is by a 'CH2'group.
Similarly the homologous series of alkanes:
CH4, C2H6, C3H8, C4H10......
Nomenclature of Hydrocarbons
The system of assigning a name to a
compound is known as nomenclature. There are two systems for naming
organic compounds
·
Common
or trivial system
·
IUPAC
system
The trivial names are given on the basis of the source and certain properties
of organic compounds.
Ex: Citric acid is named, as it is found in citrus fruits.
In the year 1947 the IUPAC that is the International Union of Pure and Applied
Chemistry system of naming compounds was first developed.
The IUPAC system is a systematic nomenclature in which the name of a compound
correlates to its molecular structure.
The IUPAC
nomenclature system is a set of logical rules devised and used to write a
unique name for every distinct compound. According to the IUPAC system of
nomenclature, the name of an organic compound consists of a root word,
a suffix and a prefix.
Root Word:
The root word indicates the number of carbon atoms in the basic skeleton.
|
Number
of carbon atoms
|
Root
word
|
|
C
|
Meth
|
|
C-C
|
Eth
|
|
C-C-C
|
Prop
|
|
C-C-C-C
|
But
|
|
C-C-C-C-C
|
Pent
|
|
C-C-C-C-C-C
|
Hex
|
|
C-C-C-C-C-C-C
|
Hept
|
|
C-C-C-C-C-C-C-C
|
Oct
|
|
C-C-C-C-C-C-C-C-C
|
Non
|
|
C-C-C-C-C-C-C-C-C-C
|
Dec
|
Example: C-C-C-C-C
Root word in the above system is ‘Pent’ (as it contains five carbon atoms).
Suffix:
A suffix designate the functional groups that may be present in the
compound. The suffix is again divided into primary and secondary.
Primary suffix:
Primary suffix indicates the degree of saturation or unsaturation in the
basic skeleton and is added immediately after the root word.
Primary suffix + Root word → Saturated or unsaturated carbon chain
Nomenclature of Alkanes:
For saturated hydrocarbons, the primary suffix “ane” should be added.
Example: The IUPAC name of a molecule which contains single bond between
carbon atoms.
CH3-CH3 : Eth + ane : Ethane
CH3-CH2-CH3 : Prop + ane : Propane
Nomenclature of Alkenes:
Hydrocarbons containing double bonds are known as alkenes.
For such hydrocarbons, the primary suffix “ene” should be added to
the root word.
Example: The IUPAC name of a molecule which contains double bond between
carbon atoms.
CH2=CH2: Eth + ene: Ethene
CH3-CH=CH2: Prop + ene: Propene
In writting nomeclature of alkenes according to IUPAC, it is important to
mention the position of double for the molecules which contain more than
three carbon atoms.
Example:
CH2=CH-CH2-CH3:
Root word: But
Prefix: 1-ene
Root word + prefix: 1-Butene
CH3-CH=CH-CH3:
Root word: But
Prefix: 2-ene
Root word + prefix: 2-Butene
Nomenclature of Alkynes:
Hydrocarbons that contain a triple bond between carbon atoms are
known as alkynes and for naming such hydrocarbons the primary
suffix “yne “should be added.
Example: The IUPAC name of a molecule which contains triple bond between
carbon atoms.
CH≡CH: Eth + yne: Ethyne
CH3-C≡CH: Prop + yne: Propyne
In writting nomeclature of alkynes according to IUPAC, it is important to
mention the position of triple bond for the molecules which contain more than
three carbon atoms.
Example:
CH≡C-CH2-CH2-CH3:
Root word: Pent
Prefix: 1-yne
Root word + prefix: 1-Pentyne
CH3-C≡C-CH2-CH3:
Root word: Pent
Prefix: 2-yne
Root word + prefix: 2-Pentyne
Secondary Suffix:
A secondary suffix indicates the functional group present
in the carbon compound. Functional groups are defined as specific
atoms, group of atoms or ions which are part of a larger hydrocarbon chain and
impart characteristic properties to the compounds.
Nomenclature of a molecules with functinal group:
|
Organic
Compound
|
Functional
Group
|
Secondary
Suffix to be used
|
|
Alcohols
|
-OH
|
-ol
|
|
Aldehydes
|
-CHO
|
-al
|
|
Ketones
|
>CO
|
-one
|
|
Carboxylic acid
|
-COOH
|
-oic aid
|
|
Acid
amides
|
-CONH2
|
-amide
|
|
Acid
chlorides
|
-COCl
|
-oyl
chloride
|
|
Esters
|
-COOR
|
-alkyl...oate
|
|
Cyanides
|
-CN
|
-nitrile
|
|
Thioalcohols
|
-SH
|
-thiol
|
|
Amines
|
-NH2
|
-amine
|
Example:
A molecule of ethyl alcohol contains two carbon atoms, so the root
word should be “eth”.
It is saturated so the primary suffix should be “ane” but as there is a
functional group (alcohol) "–OH" in the molecule, remove the “e” from
the name of the molecule and add the secondary suffix “ol”.
Therefore, the IUPAC name of ethyl alcohol is “ethanol”.
CH3-CH2-OH : Eth + an+ol : Ethanol
Similarly:
The IUPAC name of the propanaldehyde molecule can be written
as Propanal,
CH3-CH2-CHO :
Root word:Prop
Primary suffix: an
Secondary suffix: al
Root word + Primary suffix + Secondary suffix: Propanal
The IUPAC name of acetone can be written as propanone.
CH3-CO-CH3:
Root word:Prop
Primary suffix: an
Secondary suffix: one
Root word + Primary suffix + Secondary suffix: Propanone
And IUPAC name of acetic acid can be written as ethanoic acid
CH3-COOH :
Root word:Eth
Primary suffix: an
Secondary suffix: oic acid
Root word + Primary suffix + Secondary suffix: Ethanoic acid
Prefix:
The parts of the name that precede the root word are
called prefixes. For example, in the
compound, cyclobutane, “cyclo” is the prefix that indicates
the alicyclic nature of the compounds.
A primary prefix is used to differentiate acyclic and cyclic compounds. But the
rules for using these are slightly different.
Ex: In cyclic compounds, the prefix cyclo is added before the word root.
Functional groups with halogen as the hetero atom are,
|
Functional
group
|
Formula
|
Prefix to be
used
|
|
Flourine
|
-F
|
Flouro
|
|
Chlorine
|
-Cl
|
Chloro
|
|
Bromine
|
-Br
|
Bromo
|
|
Iodine
|
-I
|
Iodo
|
Nomenclature of molecule with halogen as functinal group:
IUPAC nomenclature of molecule of ethyl chloride.
CH3-CH2-Cl
Root word: Eth
Primary suffix: ane
Prefix: Chloro
Prefix + Root word + primary suffix: Chloro ethane
In case molecules with more than three carbon atoms, it is important to specify
the position of halogen.
Example:
CH3-CH2-CH2-Cl
Root word: Prop
Primary suffix: ane
Prefix:: 1-Chloro
Prefix + Root word + primary suffix: 1-Chloro propane
CH3-CH(Cl)-CH3
Root word: Prop
Primary suffix: ane
Prefix: 2-Chloro
Prefix + Root word + primary suffix: 2-Chloro propane
Chemical Properties of Carbon Compounds
arbon compounds undergo
different types of chemical reactions.
•Substitution
•Addition
•Polymerisation
•Combustion
•Thermal cracking.
Combustion:
All carbon compounds react with oxygen to
produce heat and light along with carbon
dioxide and water. This reaction of carbon with oxygen is
called combustion.
Carbon Compound + Oxygen → Carbon dioxide + water + heat and light
CH4 + 2O2 → CO2 + 2H2O + Heat and light.
• Aliphatic compounds on
combustion produce a non-sooty flame.
• Aromatic compounds on
combustion produce sooty flame.
Oxidation:
Alcohols undergo oxidation in presence of oxidising agents like alkaline potassium permanganate
or acidified potassium dichromate to form carboxylic
acids.
Example:
Ethyl alcohol on oxidation with alkaline potassium permanganate or
acidified potassium dichromate gives acetic acid.
CH3-CH2-OH Alkaline KMnO 4 or Acidified K 2 Cr 2 O 7 →
CH3-COOH
Addition
reaction:
A chemical reaction is said to be an addition reaction if two substances
combine and form a third substance. In general unsaturated hydrocarbons like
alkenes and alkynes prefers to undergo addition reactions.
In addition reactions molecules add across double bond or triple bond.
Hydrogenation reaction involves the addition of hydrogen to
unsaturated hydrocarbons in presence of catalyst like nickel or
platinum to form saturated hydrocarbons.
Example:
Addition of hydrogen to ethene
Addition of hydrogen ethyne.
CH ≡ CH + 2H2 Ni or Pt →
CH3-CH3
Addition of halogens to alkenes.
CH2 = CH2 +
X2 → CH2X
- CH2X
Similar to alkenes, addition reactions are also characteristic of
alkynes.
Example:
Ethyne reacts readily with hydrogen in the presence of a suitable catalyst to
form ethene, an intermediate and then adds another hydrogen molecule to give
ethane.
CHΞCH + H2 +
(Catalyst) → CH2=CH2 + H2 → CH3-CH3
Halogens, especially chlorine, react readily with alkynes to produce
tetra-halogen derivatives.
The addition of one molecule of chlorine to ethyne produces 1,2-dichloroethene.
The product obtained contains a carbon-carbon double bond and can further
add one molecule of chlorine thus yielding a tetra halogen derivative,
1,1,2,2-tetrachloroethane.
CHΞCH + Cl2 → CH(Cl)=CH(Cl) + Cl2 → CH(Cl2)-CH(Cl2)
Addition
of unsymmetrical reagents:
When unsymmetrical reagents like HCl, HBr or H2O across the double
bond in such a way that one part of the molecule attaches itself to one
carbon of the double bond, while the other part of the molecule attaches itself
to the other carbon of the double bond.
Example:
Ethene on reaction with HCl, produces chloroethane.
CH2=CH2 +
HCl → CH3-CH2Cl
The addition product of ethene and HBr is bromoethane.
CH2=CH2 +
HBr → CH3-CH2Br
Substitution
reaction:
A reaction in which an atom or group of atoms replaces another atom or group of
atoms is called substitution reaction. Alkanes undergo substitution
reactions.
Example:
Chlorination of methane in presence of sunlight gives a mixture of products like methyl chloride,
methylene chloride, chloroform and carbon tetrachloride.
CH4 + Cl2 Sunlight →
CH3Cl + HCl
CH3Cl+Cl2 Sunlight →
CH2Cl2 +
HCl
CH2Cl2+Cl2 Sunlight →
CHCl3+HCl
CHCl3+Cl2 Sunlight →
CCl4+HCl
Polymerization
reaction:
Alkenes and alkynes at higher temperatures under polymerization to form bigger
molecules called as polymers.
Example:
Ethene at 400 °C undergoes polymerization to form polyehene.
nCH2 = CH2 → [-CH2 -CH2 -
CH2 - CH2-]n
The polymer is usually named by adding the word “poly” to the name of the
monomer. Thus, the polymer of ethene is named polyethene or polythene.
A variety of industrially important polymers are obtained by using substituted
ethenes in place of ethene.
Propene gives polypropene on polymerisation.
Chloroethene, commonly known as vinyl chloride, yields poly vinyl chloride or
PVC, on polymerisation.
(Teflon) Tetra fluoro ethene, on polymerisation, yields poly tetra fluoro
ethene, commonly known as Teflon.
Applications
of polymers:
Polythene, polypropene and PVC are common plastics widely used to make plastic
bags, bottles, electrical insulation, pipes and many more things.
Teflon is used in the manufacture of non-stick cookware.
Cracking:
When hydrocarbons of high molecular masses are heated to high temperatures
under high pressures, they decompose, forming hydrocarbons of lower
molecular masses. This breaking up of large hydrocarbon molecules into
smaller at high temperatures is known as thermal cracking. The hydrocarbon
molecules are broken up in a fairly random way to produce mixtures of
smaller hydrocarbons.
The products of thermal cracking depend upon the nature of the hydrocarbon,
temperature, pressure, and the catalyst used. Thermal cracking of decane
gives hexane and butene.
Example:
C10H22 Cracking at 600 - 700 ℃ →
C6H14 + C4H8
Important Carbon Compounds
The two important
carbon compounds are Ethanol and Ethanoic acid
Alcohol:
Molecules in which hydroxy group attached to alkyl groups are the alcohols.
The formula of alochols can be written by replacing hydrogen ("H")
from alkanes with hydroxy group ("OH").
R - H + OH → R - OH
Alcohols can be named by replacing "e" from alkanes with
"ol".
Alkan -e + ol → Alkanol
Some of the important alcohols are:
|
Name of the alcohol
|
Chemical formula of alcohol
|
|
Methanol
|
CH3-OH
|
|
Ethanol
|
CH3-CH2-OH
|
|
Propanol
|
CH3-CH2-CH2-OH
|
|
Butanol
|
CH3-CH2-CH2-CH2-OH
|
|
Pentanol
|
CH3-CH2-CH2-CH2-CH2-OH
|
Ethanol:
Ethanol is considered as one of the important organic compound.
The molecular formula of ethanol is C2H5OH. It is also
called as ethyl alcohol.
Preparation of Ethanol:
Ethanol can be manufactured through fermentation of molasses.
The process involves slow decomposition of a complex organic compound like
molasses into simpler compounds including ethanol, by means of microorganisms
like yeast.
Physical Properties of ethyl alcohol:
• It is a colourless inflammable and sweet
smelling liquid
• Is miscible with water
• It is a good solvent that dissolves most known
substances.
• Ethanol can cause drunkenness on consumption,
even in small quantities of dilute ethanol.
• Extremely poisonous when consumed in pure form
(absolute alcohol)
Chemical properties of Ethanol:
It involves in different chemical reactions due to the presence of hydroxy
group (-OH).
Reaction of ethanol with sodium:
Ethanol readily reacts with sodium to form sodium ethoxide and hydrogen gas.
2Na + 2CH3CH2OH → 2CH3CH2O–Na+ +
H2
Reaction with concentrated sulphuric acid:
Ethanol on heating to a temperature of 443 K with excess concentrated
sulphuric acid, gives ethene.
CH3-CH2-OH Hot
Conc. H ₂ SO ₄ →
CH2=CH2+H2O
Oxidatation:
Ethanol undergoes oxidation in presence of Potassium dichromate to form
intially ethanal and finally formsfurther oxidised ethanoic acid.
CH3-CH2-OH + K2Cr2O7 → CH3-CHO → CH3-COOH
Esterification:
Reaction of ethanol with carboxylic acids is called esterification reaction.
The product formed in this reaction is an ester along with water.
Esters are sweet smelling substances which are used in
making perfumes and as flavoring agents.
Example:
CH3-CH2-OH + CH3-COOH → CH3-COOC2H5 +
H2O
Uses of Ethanol:
• Ethanol is used in pharmaceutical preparations
like tincture of iodine, cough syrups, and tonics.
• Ethanol is used in the manufacture of organic
compounds like acetaldehyde, acetic acid and chloroform.
• Ethanol is used as a preservative for
biological specimen.
Acetic acid:
The molecular formula of acetic acid is CH3COOH.
5-8% solution of acetic acid in water is called vinegar.
Preparation of Ethanoic acid:
Ethanoic acid is prepared by the oxidation of ethanol in the presence of
oxidising agents like Alkaline KMnO4 or acidified K2Cr2O7.
CH3-CH2-OH Alkaline
KMnO 4 or Acidified
K 2 Cr 2 O 7 →
CH3-COOH
Physical Properties of Ethanoic acid:
• Ethanoic acid is a colourless corrosive liquid
with a pungent odour.
• The melting point of pure ethanoic acid is
17 0C.
• Ethanoic acid freezes during the winter and is
known as glacial acetic acid.
• Miscible with water, ether and ethyl alcohol.
Chemical Properties of Ethanoic acid:
Reaction with sodium carbonate:
Ethanoic acid reacts with sodium carbonate to give sodium acetate ,carbon
dioxide and water
2CH3-COOH + Na2CO3 → 2CH3COO-Na+ +
CO2 + H2O
Reaction with sodium hydrogen carbonate:
Ethanoic acid reacts with sodium hydrogen carbonate to give sodium acetate
,carbon dioxide and water.
CH3-COOH + NaHCO3 → CH3COO-Na+ +
CO2 + H2O
Reaction with base:
Ethanoic acid reacts with bases to give salt and water.
Example:
Reaction of ethanoic acid with sodium hydroxide to form sodium acetate and
water.
CH3-COOH + NaOH → CH3COONa + H2O
Reaction with sodium hydrogen carbonate, sodiumhydrogen carbonate and with
bases are the acidic properties of ethanoic acid.
Saponification:
Esters react in the presence of an acid or a base to give back the alcohol and
carboxylic acid. This is called saponification reaction. This is reverse
reaction of esterification reaction.
CH3COOC2H5 Sodium
Hydroxide → CH3-COOH + CH3-CH2-OH
Reaction with active metals:
Ethanoic acid reacts with active metals to form metal ethanoate and hydrogen
gas.
Example:
2CH3COOH + 2Na → 2CH3COONa + H2
2CH3COOH + Ca → (CH3COO)2Ca + H2
Reduction:
Ethanoic acid is reduced to ethanol in presence of reducing reagnets like LiAlH4 (Lithium
aluminum hydrate), NaBH4(Sodium borohydrate).
CH3COOH + LiAlH4 → CH3-OH
Uses of Ethanoic acid:
• Preserve food items
• Manufacture of artificial fibres
• Ethanoic acid is used for coagulating latex to
prepare rubber from it.
• It is used as a reagent in the laboratory.
• It is used in the preparation of perfumes.
Soaps and Detergents
Soaps:
Soapnut powder has been in use for almost 3,000 years. And still in many parts
of India, soap nut powder is using as a natural soap to remove oil.
Soap is a sodium salt or potassium salt of long chain fatty acids having
cleansing action in water. They are using as cleansing agents to remove
dirt, oil from the skin and clothes.
Examples:
Sodium stearate, sodium oliate and sodium palmitate formed using stearic acid
oleic acid and palmitic acid.
Preparation of soap in laboratory:
Animal fat or vegetable oil act as glyceride or glyceryl ester. And sodium
hydroxide and potassium hydroxide act as bases.
Take about 30 ml of vegetable oil in a beaker. Then add 60 ml of 20% sodium
hydroxide solution to it.
This mixture is heated slowly till it boils. After the mixture has boiled for
five to ten minutes add 5grams of sodium chloride in order to separate soap
from the solution. Allow the solution to cool. The creamy layer floating on top
of the solution is the soap.
Thus soap is prepared by hydrolysing fat or oil with bases such as sodium
hydroxide or potassium hydroxide. This process of soap preparation is known as
saponification
Generally soaps are prepared by heating animal fat or oil with alkalies like
sodium hydroxide or potassium hydroxide. This is saponification reaction.
Fat or Oil + Alkali → Soap + Glycerol
Commercial preparation of soap:
It involves mixture of oil or fat and a strong solution of sodium hydroxide is
boiled in an iron tank which leads to the formation of a sodium salt of fatty
acid or soap and glycerol.
Once the soap is formed, it is separated with the help of sodium chloride.
Sodium chloride also reduces the solubility of soap. Since the soap is lighter,
it floats like cream on the solution.
It is separated from the solution, suitable chemicals are added for colour and
odour and then it is cast into moulds.
When the soap cools and solidifies, it is cut out into desired shapes and
packed.Glycerol, which exists in a dissolved state in the solution, is
separated with the help of distillation.
It is possible to prepare different types of soaps from different salts of
fatty acids.
Glycerol is by -product formed in the saponification reaction. This is used in
the preparation of cosmetics, paints and even explosives.
The Soap molecule has two ends with different properties. They are hydrophillic
end and hydrophobic end.
Hydrophillic end :
Hydrophillic end dissolves in water.
Hydrophobic end:
Hydrophobic which dissolves in hydrocarbons.
Cleaning action of soap:
The cleaning action of soap is due to micelle formation and emulsion
formation. Inside water a unique orientation forms clusters of molecules
in which the hydrophobic tails are in the interior of the cluster and the ionic
ends on the surface of cluster. This results in the formation of micelle.
Soap in the form of micelle cleans the dirt as the dirt will be collected at
the centre of micelle.
This property of soap makes it an emulsifier. The dirt suspended in
micelles is easily rinsed away. This is known as cleaning action of soap.
Scum:
In hard water soap don't give lather .Hard water contains calcium and magnesium
salts, which combine with soap molecules to form insoluble precipitates known
as scum.
Detergents:
Detergents have almost the same properties as soaps but they are more effective
in hard water. Detergents are generally ammonium or sulphonate salts of
long chain carboxylic acids. The charged ends of these compounds do not form
insoluble precipitates with the calcium and magnesium ions in water.
History of Periodic Table
History of Periodic Table
he earliest
classification categorized elements into metals and
non-metals. It was difficult to classify the elements, such as boron,
which exhibited the properties of both metals as well as non-metals. After
further research a German scientist, Dobereiner arrived at a hypothesis in
the year 1829.
According to Dobereiner, all elements occurred in groups of three, when
arranged in increasing order of atomic masses. He referred to these groups as
triads. In a traid the elements had similar chemical properties.
Traids of the Dobereiners classification:
Traid1:
|
Element
|
Atomic mass
|
|
Lithium
(Li)
|
7
|
|
Sodium (Na)
|
23
|
|
Potassium (K)
|
39
|
Traid2:
|
Element
|
Atomic mass
|
|
Chlorine (Cl)
|
35.5
|
|
Bromine (Br)
|
80
|
|
Iodine (I)
|
127
|
Traid3:
|
Element
|
Atomic mass
|
|
Calcium (Ca)
|
40
|
|
Strontium (Sr)
|
88
|
|
Barium (Ba)
|
137
|
Dobereiner’s law of triads states that, the atomic mass of
the middle element of a triad is the arithmetic mean of the atomic
masses of the other two elements.
Example:
In the triad of lithium, sodium and potassium. The atomic mass of
lithium is 7 and the atomic mass of potassium is 39. The average of
masses of lithium and potassium gives atomic mass of sodium 23.
Drawbacks:
All the known elements could not be arranged in the form of triads.
This law did not hold good for elements with very low or very high atomic
mass.
Example: The arithmetic mean of the atomic masses of fluorine 19 and bromine
80, which comes to 49.5, varies significantly from the atomic mass of chlorine,
which is 35.5.
Since Dobereiner’s law could not successfully group elements, the attempts at
classification continued. The next attempt came in 1864, when an English
chemist, John Newlands, stated his observations in the form of Newlands Law of
Octaves.
Newlands Law of Octaves:
When Newlands arranged elements in according to their atomic weights then there
was similarity of every eighth element. Newland described it as "law of
octaves".
According to this law every eighth element is similar to that of
the first element, similar to the first and the eighth notes in
the musical scale.
Newlands classification of elements:
|
Li
|
Be
|
B
|
C
|
N
|
O
|
F
|
|
Na
|
Mg
|
Al
|
Si
|
P
|
S
|
Cl
|
|
K
|
Ca
|
|
|
|
|
|
Example: When starting from lithium, the eighth element is sodium. Similarly,
the eighth element from sodium is potassium. Lithium, sodium and potassium
show similar properties.
Drawbacks:
- Not valid
for elements having atomic masses higher than calcium.
- Newly
discovered elements could not find a place in Newlands table.
Mendeleev's periodic table:
Mendeleev based his work on the research by Newlands and took it further. He
felt that effective grouping of elements and prediction of properties could be
based on two parameters:
- Atomic
mass
- Chemical
reactivity
Mendeleev’s
periodic law states that "the physical and chemical properties of all
elements are the periodic function of their atomic masses".
|
Row
|
Group I
|
Group II
|
Group III
|
Group IV
|
Group V
|
Group VI
|
Group VII
|
Group
VIII
|
|
1
2
3
|
H = 1
Li = 7
Na = 23
|
Be = 9
Mg = 24
|
B = 11
Al = 27
|
C = 12
Si = 28
|
N = 14
P = 31
|
O = 16
S = 32
|
F = 19
Cl = 35.5
|
|
|
4
5
|
K = 39
Cu = 63
|
Ca = 40
Zn = 65
|
|
Ti = 48
|
V = 51
As = 75
|
Cr = 52
Se = 79
|
Mn = 35
Br = 80
|
Fe = 56
Co = 58.94
Ni = 58.68
|
|
6
7
|
Rb = 85
Ag = 108
|
Sr = 87
Cd = 112
|
Y = 89
In = 113
|
Zr = 90
Sn = 118
|
Nb = 94
Sb = 120
|
Mo = 96
Te = 128
|
I = 127
|
Ru = 103
Rh = 104
Pd = 106
|
|
8
9
|
Cs = 133
|
Ba = 137
|
La = 138
|
Ce = 140
|
|
|
|
|
|
10
11
|
Au = 198
|
Hg = 200
|
Yb = 173
Tl = 204
|
Pb = 206
|
Ta = 182
Bi = 208
|
W = 184
|
|
Os = 191
Ir =193
Pt = 196
|
|
12
|
|
|
|
Th = 232
|
|
U = 240
|
|
|
The main features of Mendeleev’s periodic table:
- The known 63
elements were classified into groups and periods.
- The table
had 8 vertical columns called groups and 12 horizontal
rows called periods.
- In every
group, a gradation of physical and chemical
properties of elements was observed.
- The table
provided gaps for undiscovered elements.
- The table
helped to predict the properties of three unknown elements of that time.
These elements
were named eka-boron, eka-aluminium and eka-silicon.
When these elements were discovered, they were
named scandium, gallium and germanium. The properties
of these elements were very close to those predicted by Mendeleev.
Merits:
The table helped in the correction of atomic mass for many
elements. It predicted the existence of some
elements that have not been discovered at the time the table was
created.
Demerits:
The atomic weights of two pairs of elements
were reversed.
Alkali metals and coinage metals were placed in the same
group.
Lanthanides and actinides were not given proper place in the
periodic table.
Isotopes were not placed in the periodic
table.
The position
of hydrogen was not clearly discussed
Modern Periodic Table
The systematic
arrangement of elements into groups and periods is called periodic table.
In 1913, Henry Moseley showed that the atomic number of an element is a more
fundamental property than its atomic mass.
So Mendeleev’s Periodic law was modified and atomic number was adopted as the
basis of the Modern Periodic Table.
The Modern Periodic Law is stated as: "Properties of elements are a
periodic functions of their atomic number". Atomic number is the
basis for modern periodic table.
Atomic number is the number of protons in the nucleus, it is
also equal to the number of electrons in the atom.
Example: In Carbon
The main features of modern periodic table:
• Elements are arranged
in the increasing order of atomic numbers.
• Horizontal rows in the
periodic table are called periods and vertical columns in the table are called
groups.
• Elements in the modern
periodic table are arranged in 7 periods and 18 groups.
Filled orbitals
and number of elements in different periods:
|
Period
|
Nature of
period
|
Filled orbitals
|
Number of
electrons accomdated
|
Strating -Last
element
|
Number of
elements
|
|
1
|
Shortest period
|
1s
|
2
|
Hydrogen -
Helium
|
2
|
|
2
|
Short period
|
2s 2p
|
2 + 6
|
Lithium - Neon
|
8
|
|
3
|
Short period
|
3s 3p
|
2 + 6
|
Sodium - Argon
|
8
|
|
4
|
Long period
|
4s 3d 4p
|
2 + 10 + 6
|
Potassium -
Krypton
|
18
|
|
5
|
Long period
|
5s 4d 5p
|
2 + 10 + 6
|
Rubidium -
Xenon
|
18
|
|
6
|
Longest period
|
6s 5d 4f
5d 7p
|
2 + 1 + 14 + 9
+ 6
|
Cesium - Radon
|
32
|
|
7
|
Longest period
|
7s 6d 5f 6d 7p
|
2 + 1 + 14 + 9
+ 6
|
Francium - Uuo
|
32
|
Elements were classified into groups based on the number of valence electrons.
According to IUPAC nomenclature the 18 groups in modern periodic table are
numbered as 1 to 18.
Types of elements:
The elements in the modern periodic table were classified into four
types. They are
Representative elements
Transition elements
Inner transition elements
Noble gases
Representative elements:
The elements of group -1, group-2 and group-13 to group-17 are the
representative elements.
Group-1:
Lithium, Sodium, Potassium, Rubidium, Cesium and Francium
are the elements of this group. Their general electronic
configuration is ns1.
These elements have one electron in their valence shell.
This group elements are also known as alkali metals as the hydroxides
of these group elements are basic in nature and soluble in water.
Group-2:
Beryllium, Magnesium, Calcium, Strontium, Barium and Radium are the
elements of this group. Their general electronic
configuration is ns2.
These elements have two electrons in their valence shell.
The hydroxides of these group elements are basic in nature and soluble in
water. These elements obtained from earth crust because of these
reasons these elements are called as alkaline earth metals.
Group-13:
Boron, Aluminium, Gallium, Indium and Thallium are
the elements of this group. Their general electronic configuration is ns2np1.
These elements have three electrons in their valence shell.
These group elements mostly form covalent compounds.
Group-14:
Carbon, Silicon, Germanium and Tin are
the elements of this group. Their general electronic
configuration is ns2np2.
These elements have four electrons in their valence shell.
Group-15:
Nitrogen, Phosphorous, Arsenic, Antimony and Bismuth are
the elements of this group. Their general electronic
configuration is ns2np3.
These elements have five electrons in their valence shell.
These group elements are also called as pnictogens.
Group-16:
Oxygen, Sulphur, Selenium, Tellurium and Polonium are
the elements of this group. Their general electronic
configuration is ns2np4.
These elements have six electrons in their valence shell.
This group elements are also known as chalcogens.
Group-17:
Fluorine, Chlorine, Bromine, Iodine and Astatine are
the elements of this group. Their general electronic
configuration is ns2np5.
These elements have seven electrons in their valence shell.
This group elements are also called as halogens.
Group-18:
Helium, Neon, Argon, Krypton, Radon and Xenon are
elements of this. This group also referred as zero group. Their
general electronic configuration is ns2np6.
These elements have eight electrons (octet configuration) in their valence
shell.
This group elements are also known as inert gas elements.
Transition elements:
Elements which contains incomplete penultimate ((n-1):d -sub shell) shell with
electrons are called transition elements. Elements present between the group -2
and group-13 in the modern periodic table are the transition elements. In
transition elements the valency electrons goes to d - sub shell.
General electronic configuration of transition elements is ns2 (n-1)d 1-10.
Transition elements are classified into four series of elements.
They are 3d-
series (1st transition series), 4d –series (2nd transition
series), 5d - Series (3rd transition series) & 6d – series
(4th transition series).
Lanthanides and actinides:
Elements which kept kept separately under the table in two seperate rows
in the Modern periodic table are called lanthanides and actindes.
Theses elements contains incomplete anti-penultimate shells ((n-2): f
-sub shells). So these elements are also called as inner transition
elements.
General electronic configuration lanathanides and actindies is (n-2) f1-14 (n-1)d0-1 ns2.
Position of Hydrogen in the periodic table:
There is an anomaly when it comes to the position of Hydrogen in the periodic
table as it can be placed either in group I or 17 group of the first
period.
Reasons for abnormality regarding the position of hydrogen:
Hydrogen can show properties similar to alkali metals and it has one electron
in it valence shell just similar to alkalimetals.
Just similar to alkali metals it loses one electron to form cation.
Similar to alkali metals it combines with Oxygen, Sulphur and Halogens to form
similar compounds.
Hydrogen shows similar properties to halogens.
It exists as a diatomic molecule (H2). Just similar to halogens
which exists as X2 (X =F, Cl, Br, I).
Hydrogen combines with metals and non metals to form covalent compounds.
Example:
Hydrogen combines with metals to form metal hydrides just similar to halogens
which forms halides with metals.
H2 + 2Na → 2NaH
Cl2 + 2Na →2NaCl
Because of the above reasons their is uncertainity regarding the position of
hydrogen.
Periodic Properties
The term periodic properties in
elements, refers to the properties that recur at regular intervals. The trend of
recurrence of properties is called periodicity. Important periodic
properties are:
• Atomic radius
• Ionization energy
• Electron affinity
• Electronegativity
• Metallic and non-metallic
character
Atomic
radius:
Atomic radius is the distance from the centre of the nucleus to
the valence electron in an energy level. Atomic
radius is expressed in angstrom units.
Trend
in atomic radius:
The atomic radius decreases across a period due to increase in
nuclear charge.
Example:
The graph below shows decreasing order of atomic radius in period:
Li > Be > B > N >
O
Atomic radius increases down the group due to addition of new shell.
Example:
Following graph shows increasing order of atomic radius in group:
Li < Na < K < Rb
Ionization
energy:
Ionization Energy is the minimum energy required to remove
the outermost electron from a gaseous neutral atom to form
a cation.
The unit for ionization energy is electron
volts or kilo joules per mole.
Trend
in Ionization energy:
Ionization energy increases across a period due to increase in the
nuclear charge.
The following depicts the increase of IE in period.
Ionization energy decreases down the group due increase due to
increase in the atomic size (addition of new shell).
The following graph gives decrease of IE in group-1.
Helium has the highest ionization energy in the periodic
table while cesium has the lowest ionization energy.
Electron
affinity:
The energy released when an electron is added to
a neutral gaseous atom is known as electron
affinity. The unit for electron affinity is kilo
joules per mole.
It depends mainly on two factors. They are atomic size and nuclear charge.
Atomic size: As the atomic size increases the nucler attraction force on
the valence shell decreases. Thus electron affinity will be more for smaller
atomic size elements.
Nuclear charge:
Electron affinity increases with increase in the nuclear charge. With the
increase in nucler attraction force the electron in the valence shell binds
strongly to the atom.
Trend
in electron affinity:
The electron affinity increases across a period while
it decreases down a group.
The zero group elements have the lowest electron
affinity values. Halogens posses highest electron affinity in the periodic
table. In halogens chlorine posses highest electron affinity in the periodic
table.
Electronegativity:
The tendency of an atom to attract the shared pair of
electrons towards itself is known as electronegativity.
Trend
in electronegativity:
Electronegativity increases across a period.
Example:
In second period electronegativity increases from lithium to fluorine.
Electronegativity decreases while moving down the group.
Example:
In group-1 electronegativity decreases while moving from top to bottom.
In the periodic table, halogens have high electronegativity. Among halogens
Fluorine has the highest electronegativity of 4.0 than Chlorine,
Bromine and Iodine.
In the periodic table alkali metals possess very low electronegativity values.
Among alkali metals Cesium has the lowest value of 0.7.
Metallic
character:
The tendency of an atom to lose electrons is known as metallic
character.
Metallic character decreases across a period and increases down the group.
Metals are highly electropositive in nature.
Non-metallic
character:
The tendency of an atom to gain electrons is known as non-metallic
character.
Non-metallic character increases across a
period and decreases down the group.
Non-metals are more electronegative in nature.
In the periodic table:
• Metals are placed on the
left side of the periodic table.
• Non-metals are placed on the
right side of the periodic table.
• Metalloids are placed
between the metals and the non-metals.
Life Processes
Photosynthesis
Life
processes
The processes performed by living organisms in order to maintain and continue
life are called as life processes. Life processes include nutrition,
respiration, circulation or transport, excretion, and reproduction.
Nutrition
It is the process by which organisms can assimilate and utilise food for their
basic needs. Nutrition is of two different types, namely, autotrophic and
heterotrophic.
Photosynthesis:
Photosynthesis is an autotrophic mode of nutrition by plants and some bacteria.
Photosynthesis is the physico-chemical process by which plants can convert
light energy into chemical energy, in the form of carbohydrate from simple
inorganic substances like atmospheric carbon dioxide and water.
Basic raw materials for photosynthesis
Photosynthesis requires carbon dioxide, sunlight, water and chlorophyll as its
basic raw materials.
Sites of photosynthesis
- Leaves are
considered to be the sites of photosynthesis. Hence, they are called as
food factories of the plant.
- Leaves
possess small pores called as stomata on both their surfaces. Stomata are
the structures which help in the exchange of gases. Opening and closing of
the stomata are brought about by the guard cells present in them.
- Leaves are
rich in plastids. Green coloured plastids are chloroplasts rich in
chlorophyll pigment. Chlorophyll is responsible for trapping the
energy from sunlight.
Overall reaction of photosynthesis
Light Energy
6CO2 + 12H2O
Chlorophyll → C6H12O6 +
6O2 + 6H2O
Photosynthesis involves two types of reactions namely, light reactions and dark
reactions.
a) Light reactions: Light reactions are light dependent reactions. These
reactions happen only in the presence of sunlight. The photosynthetic pigments
trap the energy from the sunlight. PS-I and PS-II collectively bring in the
cyclic photophosphorylation and non-cyclic photophosphorylation reactions. As a
result of these reactions energy rich molecules like ATP and NADPH2 are
synthesised. Photolysis of water molecules results in the release of oxygen as
a by-product.
H2O → 2H+ + 2e- +
½O2
b) Dark reactions: Dark reactions are independent of light. Energy rich
molecules like ATP andNADPH2 are utilised in these reactions. Dark reactions involve
Calvin cycle during which carbon dioxide is reduced to carbohydrate.
C3 pathway is also known as Calvin cycle.C3 pathway involves set of carbon
reactions which are catalysed by the enzyme Rubisco to synthesise 3 carbon
compound, 3-phosphoglycerate from 5-carbon compound, Ribulose bisphosphate.
- Ribulose
bisphosphate is the primary acceptor of CO2.
- Chloroplasts
present are only of one type.
- Anatomy of
leaves does not resemble Kranz anatomy.
- Phosphoglyceric
acid is synthesised as the product.
- Mesophyll cells
exhibit Calvin cycle.
- Photorespiration
is observed.
- Optimum
temperature required for photosynthesis is between 20 degree
celsius to 25 degree celsius.
- This cycle
is less efficient in utilising CO2.
|
LIGHT
REACTIONS
|
DARK REACTIONS
|
|
These are light
dependent reactions.
|
These are light
independent reactions.
|
|
Splitting of
water molecules releases oxygen as a by-product.
|
Carbon dioxide
is reduced to carbohydrates.
|
|
Grana of
chloroplasts are the sites of these reactions.
|
Stroma of
chloroplasts are the sites of these reactions.
|
|
ATP and NADPH2 are
the energy rich compunds synthesised in these reactions.
|
Energy rich
compounds are utilised in the synthesis of carbohydrates.
|
Events in photosynthesis
Photosynthesis can be split into three basic events.
Factors affecting photosynthesis
Rate of photosynthesis depends on many factors like light, carbon dioxide,
water and chlorophyll.
a) Light: Visible spectrum of the sunlight ranges from 380 to 750 nanometres in
wavelength.
- Quality of
the light also influences the rate of photosynthesis. Photosynthetic rate
is higher in red and blue light. It is very poor in green light.
- Intensity of
light also determines the rate of photosynthesis.
- Day-length
of plants is also an important factor for photosynthesis to be
effective.
- Essentiality
of sunlight and chlorophyll are demonstrated using starch test.
- Essentiality
of carbon dioxide is demonstrated by bell jar experiment.
- Plants
obtain water from the soil by the process of absorption performed by
roots.
b) Carbon dioxide: Carbon dioxide occupies 0.04% of the total atmosphere.
- Carbon
dioxide plays an important role in providing carbon for the process of
photosynthesis.
- Increased
concentration of carbon dioxide content enhances the rate of
photosynthesis.
- But too much
of its concentration proves to be toxic to the plants.
- Carbon
dioxide is reduced to carbohydrate in the dark reaction.
c) Water: Water being a universal solvent, almost all the minerals present
in the soil dissolve in it.
- It plays a
vital role in the process of photosynthesis.
- Water along
with minerals is absorbed by roots and is carried to the sites of
photosynthesis through xylem tissue.
- 1% of
absorbed water is utilized and the remaining water is released during
photosynthesis.
- Water serves
as a source for oxygen which is released as a by-product.
d) Chlorophyll: Chlorophyll, green coloured pigment, present in the
chloroplasts plays a vital role in the process of photosynthesis.
- Chlorophyll
absorbs blue light effectively and then the red light, but proves to be a
poor absorber of green light.
- It traps the
solar energy and converts into chemical energy which is utilised in the
dark reaction of photosynthesis to form glucose.
- Chlorophyll
a and chlorophyll b are most prominent forms of chlorophyll found in
plants.
Digestion
Heterotrophic
nutrition
Heterotrophic nutrition is the mode of nutrition exhibited by heterotrophs.
Heterotrophs are the organisms that depend on plants or other organisms for
their food. Heterotrophic mode of nutrition is of different types –
saprophytic as in fungi, parasitic as in leeches and symbiotic as in hermit
crab.
Unicellular organisms exhibit holozoic type of nutrition. e.g. Amoeba and
Paramecium. This type of nutrition involves ingestion of liquid or solid
organic material, digestion, absorption and assimilation to utilise it.
e.g.Food in the food vacuoles of the amoeba and paramecium is digested by lytic
enzymes.
Multicellular organisms exhibit a complex process in obtaining their
nourishment.
Digestion: The process of breaking down complex food substances into
simple molecules is called as digestion.
Digestive system in human beings consists of alimentary canal and digestive
glands.
- Alimentary
canal is made up of mouth, buccal cavity, pharynx, oesophagus, stomach,
intestine, rectum and anus.
- The
digestive glands are the salivary glands, the gastric glands, the liver,
the pancreas and the intestinal glands.
Digestion in buccal cavity is brought about by three pairs of salivary glands
opening into the oral cavity.
- Salivary
glands include submaxillary, sublingual and parotid glands.
- Amylase, a
digestive enzyme in saliva, breaks down the starch in food into simpler
sugar.
- Saliva also
prevents tooth decay due to the presence of amylase, lysozyme and
minerals.
Peristalsis includes a series of muscular contractions in the oesophagus that
push the food forward to the stomach.
The stomach is divided into three compartments namely cardiac, fundus and
pylorus. The junction of oesophagus and stomach is guarded by valve which
does not allow the food to travel in backward direction.
• In the stomach, food is
mixed with the gastric juices secreted by the gastric glands.
• Gastric juice is a combination
of hydrochloric acid, enzymes like pepsin, lipase and mucous. Gastric
glands secrete HCL, pepsinogen, mucous.Gastric juice is a secretion of gastric
glands located in the lining of the stomach. It is mainly made up of
electrolytes, mucus, enzymes, hydrochloric acid, intrinsic factor etc. HCl
secreted by parietal cells provides acidic medium for many enzymes to get
activated. Neck cells secrete mucus which lubricated the passage of the food.
Chief cells secrete pepsinogen which helps in the digestion of proteins after
getting activated into pepsin by HCl. Enzymes of the gastric juice bring about
digestion of different components of the food. Gastric lipase helps in
emulsification of lipids in the stomach. Partially digested food in the stomach
is called as chyme and this passes on into small intestine
• Partially digested food in the stomach becomes acidic and
is known as chyme.
Liver is the largest gland in our body. The liver secretes a yellowish green
watery fluid called bile. It is temporarily stored in a sac called the gall
bladder. Bile plays an important role in the digestion of fats. Bile is
sent into duodenum through a narrow tube-like structure called the bile duct.
Bile breaks the larger fat molecules into tiny droplets, thereby increasing
their surface area, which helps in the digestion of fats easily. Bile is a
dark green alkaline fluid secreted by liver. It comprises of water, bile salts,
bile pigments, fats and inorganic salts. Bile comprises of yellow pigment
bilirubin which oxidizes to form green pigment biliverdin only when it enters
the intestine.
• Bile makes the food alkaline for the action of pancreatic
and intestinal enzymes in the small intestine.
• Bile brings about emulsification of fats which are later digested by
intestinal lipases.
Pancreas is the mixed gland. It acts as a both endocrine and exocrine gland.
The pancreas secretes the pancreatic juice that helps to digest carbohydrates,
proteins and fats. The pancreatic juice converts carbohydrates into simple
sugars and glucose, proteins into amino acids, and the lipids into fatty acids
and glycerol.
The exocrine part
of pancreas secretes pancreatic juice which includes trypsin and lipase that
help break down proteins and fats. Trypsin and chymotrypsin help in the
digestion of proteins.
Liver and pancreas open into intestine through hepato-pancreatic duct to throw
their secretions for further digestion of food.
Small intestine is made up of three regions namely duodenum, jejunum and ileum.
Acidic chyme from the stomach is received by the duodenum for further
digestion.
- Duodenum
receives bile form the liver. Bile provides an alkaline environment
for many enzymes to get active. It also reduces the acidity of chyme. Bile
plays an important role in the digestion of fats.
- Duodenum
also receives pancreatic secretions which help in the digestion of food.
Pancreas secretes the pancreatic juice that helps to digest carbohydrates,
proteins and fats.
- Duodenum
also secretes some enzymes on its own. Cells lining the inner lining of
intestine secrete enzyme rich intestinal juice. Intestinal juice comprises
of many enzymes like enterokinase, invertase, maltase and lipase. The
intestinal enzymes act upon partially digested proteins, carbohydrates and
fats.
- All these
substances bring about digestion of food in the duodenum. The inner walls
of small intestine are thrown into many folds which have millions of small
finger like projections called villi.
- Intestinal
glands are present in the inner lining of small intestine. These secrete
various enzymes which aid in the process of digestion of all the
components of food. Maltase, sucrase and lactase bring about digestion of
carbohydrates. Peptidases help in digestion of proteins. Enterokinase
helps in the activation of other enzymes.
- Proteins,
carbohydrates and fats are simplified into amino acids, glucose, fatty
acids and glycerol in a liquid medium known as chyle.
- Specific
structures called as villi in the small intestine increase its surface
area to ensure efficient and rapid absorption of nutrients. Villi
increase the surface area for digestion as well as absorption of digested
food by eight times. Blood capillaries in the villi absorb nutrients
and transport the food to all the cells in the body.
The large intestine comprises caecum, appendix, colon, rectum and
anus. The large intestine absorbs water from undigested food and forms
solid waste.
• The rectum stores the solid
excreta until it is ready to be excreted from the digestive system through anus.
• The appendix is a small,
hollow, finger-like pouch, which hangs at the end of the cecum. It does not
have any function in the digestive system of humans. However, it is functional
in herbivores such as cows.
Respiration
Respiration
It is the process by which chemical energy stored in the food is released
in the form of ATP along with carbon dioxide and water.
Respiration begins with breathing, a combined process of inhaling oxygen and
exhaling carbon dioxide.
Types of respiration
Respiration can be of two types – Aerobic and Anaerobic. Both of
these respirations take place inside the cell.
- Aerobic
respiration involves breakdown of glucose into carbon dioxide and water in
the presence of oxygen. In aerobic organisms, the pyruvate molecule is
further broken down in the mitochondria of a cell. The pyruvate molecule
that contains three carbon atoms is broken down into three molecules of
carbon dioxide and three molecules of water by the action of mitochondrial
enzymes.
- Anaerobic
respiration involves the breakdown of food into alcohol and carbon dioxide
in the absence of oxygen. The breakdown of glucose to release
energy from the cells in anaerobic conditions is fermentation. Under
anaerobic conditions prevailing in our muscle cells, the insufficiency of
oxygen converts the pyruvate molecules into lactic acid and energy.
Accumulation of lactic acid in our muscle cells causes cramps.
Process of
respiration
During
respiration, a glucose molecule that contains six carbon atoms is broken down into
pyruvate. Pyruvate is a molecule that contains three carbon atoms.
1) In aerobic organisms, the pyruvate molecule is further broken down in the
mitochondria of a cell. The pyruvate molecule that contains three carbon atoms
is broken down into three molecules of carbon dioxide and three molecules of
water by the action of mitochondrial enzymes.
- Glycolysis
is the process which involves breakdown of glucose molecule to release two
molecules of pyruvate. It is multi-step procedure occurring in the
cytoplasm of the cells. The process is same for plant cells and animal
cells. This process results in the formation of pyruvate molecules along
with some ATP molecules. Pyruvate molecules act as substrate molecules for
the Krebs cycle which occurs in the mitochondria of both animal and plant
cells. Krebs cycle also finally releases ATP molecules, energy coins of
the cell.Glycolysis is made up of preparatory phase and pay-off phase. The
net gain of glycolysis is 2 ATP and 2 NADH2. Pyruvate can be utilised in
Kreb's cycle, lactic acid or alcohol fermentation, based on the
availability of oxygen.
- Krebs' cycle
involves a set of enzymatic reactions taking part in mitochondria in the
presence of oxygen to yield energy rich molecules. It is also called as
Tricarboxylic acid cycle. The net gain of aerobic respiration at the end
of Krebs' cycle is 2 ATP molecules, 8 molecules of NADH+H+ and 2
molecules of FADH2. As we know, ATP is the energy rich coin of the cell
utilised for different purposes.
- Electron
Transport Chain is a step wise process which generates energy in the form
of ATP molecule from NADH and FADH2 produced during glycolysis, Krebs
cycle and other catabolic processes. Electron Transport Chain is an
important step of cellular respiration. The mechanism by which Electron
Transport Chain generates ATP is called as chemiosmotic
phosphorylation. Electron Transport Chain is made up of different
complexes and enzymes which participate in ATP synthesis. ETS
comprises of several energy carriers which include NADH dehydrogenase
complex (Complex I), Ubiquinone (Complex Q), Succinate dehydrogenase
complex (complex II), Cytochrome bc1 complex (Complex III), Cytochrome c,
Cytochrome c oxidase (Complex IV)
2) Under anaerobic conditions prevailing in our muscle cells, the insufficiency
of oxygen converts the pyruvate molecules into lactic acid and energy.
Accumulation of lactic acid in our muscle cells causes
cramps. Fermentation is an anaerobic process which takes place in the
absence of oxygen. It converts sugar substrates into alcohol and carbon
dioxide. Fermentation process also releases certain amount of energy
Both aerobic and
anaerobic respiration release energy in the form of ATP. The energy
released in the aerobic process is 19 times greater than the energy released in
anaerobic process. The energy in the form of ATP is used for many activities
such as the contraction of muscles, protein synthesis and conduction of nervous
impulses etc.
Respiration in plants
Respiration in plants is just opposite to that of photosynthesis. Exchange of
gases takes place in plants through special structures called as
stomata. Stomata are small pores present on the surface of leaves and
green parts of plant. Opening and closing of stomata are controlled by guard
cells.
- Dark
respiration taking place in plants is independent of the presence of
light. Plant cells after synthesizing sugar molecules through
photosynthesis, undergo cellular respiration to break down food molecules
to obtain energy in the form of ATP molecules. Dark respiration is a form
of respiration where carbon dioxide is released without the aid of
sunlight.
- Light phase
or photorespiration is an inevitable process which occurs in C3 plants.
There is a decreased output of photosynthesis. ATP is not synthesized in
photorespiration and carbon is released in the form of carbon dioxide.
Nitrogen is also released in the form of ammonia.
Respiration in aquatic forms
The rate of breathing in aquatic organisms is much faster than in terrestrial
organisms. Respiration in aquatic animals is performed by diffusion
through body surface and special respiratory organs called as gills.
Fish are the aquatic vertebrates which respire through structures called as
gills. This is called as branchial respiration.
- Gills are
present on either side of the head and are supplied by rich blood
vessels. Fish obtain oxygen dissolved in water.
- During
respiration, water enters the body through mouth, passes through gills and
comes out of the operculum.
- Exchange of
gases takes place in the gills of fish supplied by numerous blood
vessels. They accept oxygen into the body and expel out carbon
dioxide.
Respiration in
terrestrial forms
Terrestrial animals have special organs for taking in oxygen from the
atmosphere. For instance, cockroaches respire through the trachea, and
scorpions through the book lungs. Breathing is the physical act of
inhaling and exhaling. Breathing involves taking in oxygen from the environment
and removal of carbon dioxide from the body. The diaphragm is a thin thin
sheet of muscle separating the thorax and the abdomen, and helps in
respiration.
Path taken by air
Air enters a human body through the nostrils. It passes through nasal cavity
and then enters trachea. From the trachea, air enters the
bronchi and then goes into the lungs. The bronchi form a network of
bronchioles. Each bronchiole has alveoli at the end in the lungs. The thin
membranes of alveoli allow the exchange of gases. Alveoli are richly supplied
with blood vessels.
- Haemoglobin
present in RBCs is a metallo-globulin which is made up of 2 alpha
chains and 2 beta chains. The respiratory pigment, haemoglobin
present in blood absorbs oxygen from the lungs and carries it to tissues
all over the body. In return it carries carbon dioxide from the tissues to
the lungs.
Transportation in Animals
Circulatory
system
The system which pumps the fluid tissue to transport it throughout the body is
called the circulatory system. Human circulatory system comprises of
heart, blood and a network of blood vessels. The system transports
oxygenated blood from lungs and the heart throughout the body via arteries. The
oxygenated blood is supplied to all the organs by arteries branching out as
capillaries. The deoxygenated blood is returned to veins through capillaries.
These veins carry deoxygenated blood to the heart and the lungs.
Human heart
The heart is the
central organ for pumping the blood throughout the body. Heart is made up
of strong cardiac muscles. It is located in the chest cavity with its lower
part pointing towards the left. Its size is that of the person’s fist. It
pumps blood rich in carbon dioxide to the lungs and oxygen-rich blood to other
parts of the body.
- The heart
consists of four chambers namely auricles and ventricles. The two upper
chambers of the heart are known as the auricles.
- The two
lower chambers of the heart are the ventricles. Left and right parts of
the heart are separated by a muscular partition called as septum.
- Heart has
number of valves which allow the blood to flow in one direction. These
prevent the oxygenated blood mixing with de-oxygenated blood.
- SA node, the
natural and primary pace maker of the heart is located in the upper wall
of the right atrium in the heart.
- AV node, the
secondary pace maker is located in the bundles of tissues on the border
between right atrium and right ventricle of the heart.
Blood vessels
Blood vessels are tube like structures which form an intricate network to
transport blood to various parts of the body. They are classified as arteries,
veins and capillaries.
a) Arteries are the blood vessels which carry pure oxygenated blood from the
heart to different tissues in the body. Arteries are with thick walls as the
heart pumps blood with greater pressure into the arteries. Inturn arteries also
offer some pressure on the blood. This is called as peripheral
resistance. Pulmonary artery carries impure blood to the lungs from
heart
b) Veins arise
from the bodily tissues. Thus deoxygenated blood is carried by veins and is
returned to heart. All the veins carry impure blood to the heart except for
pulmonary veins which carry pure blood from lungs to the heart. Veins have
wider inner diameters and valves to prevent the back flow of blood. Blood is
just allowed to go towards the heart and not in any other way. The walls of
veins are thinner when compared to the walls of the artery. Pulmonary
veins carry pure blood from lungs to the heart. Pulmonary veins need not
have thicker walls as such as blood is not pumped by the heart in to these
veins. They carry pure blood from lungs. They have valves in them so as to
prevent backward flow of the blood. There are totally four pulmonary veins
and all of them are connected to left atrium of our heart.
c) Blood
capillaries are the structures which branch out form arteries on entering the
tissues. Blood capillaries supply pure blood to inner parts of the
tissue. These capillaries in turn collectively form a single vein from the
tissue. The heart pumps deoxygenated blood into the lungs through
pulmonary arteries.
Pulmonary artery carries impure blood to the lungs from heart . Blood gets
purified in the lungs. Pulmonary veins carry pure
oxygenated blood from lungs to the heart.
Functions of the heart
- All parts of
our body require oxygen to carry out life processes. We take in oxygen by
the process of respiration. But this oxygen should be carried over to all
parts of the body.The oxygen in the lungs binds to hemoglobin
present in the blood. This oxygenated blood is taken to heart. This oxygen
carrying blood should be transported to all the parts of our body. To pump
this blood with pressure we need a central pumping organ called as
heart. This is the reason why our heart pumps continuously.
- It is a
central pumping organ of the circulatory system which pumps oxygenated
(pure) blood into the blood vessels to be carried over to different parts
of the body.
- It receives
deoxygenated (impure) blood from different parts of the body and sends it
to the lungs for purification.
Blood
Blood and lymph are the important modes of transport in the circulatory
system. Blood is a fluid tissue made from plasma and formed elements.
- Plasma is a
pale yellowish fluid that contains albumin (the chief protein
constituent), fibrinogen (responsible, in part, for the clotting of blood)
and globulins (including antibodies). Plasma is obtained by separating the
liquid portion of blood from the cells. Plasma serves a variety of
functions like maintaining a satisfactory blood pressure and volume,
serving as the medium for exchange of vital minerals, maintaining a proper
pH in the body. It also helps in transporting gases, nutrients and
nitrogenous waste.
- Red blood
cells in the blood are flattened disc like structures responsible of
transporting oxygen and carbon dioxide gases. Red blood cells consist of
red iron-containing pigment called as haemoglobin. Haemoglobin is a
respiratory pigment that carries oxygen through red blood cells.
Oxygenated blood is carried to tissues.
- White blood
cells are otherwise known as leukocytes. WBCs help the body in fighting
against the diseases. Different types of WBCs are Granulocytes, Monocytes
and Lymphocytes. Granulocytes are further divided into Neutrophils,
Eosinophils and Basophils. Monocytes can transform themselves into
two types of cells namely, Dendritic cells and Macrophages. Lymphocytes
can be of two types namely B-lymphocytes and T-lymphocytes.
- Platelets
are the non nucleated, irregular cells which bring about clotting of the
blood.These are also called as thrombocytes as they release thromboplastin
which plays an important role in clotting of blood. Platelets immediately
come to the place of injury and lyse themselves to release thromboplastin.
The remnants aggregate in large amounts to form a plug on the injury
preventing the blood loss.
Functions of
blood
Blood plays a vital role in transporting many substances to all parts of the
body.
- As the blood
contains RBCs, it transports oxygen from lungs to cells and in turn
carries carbon dioxide in the opposite direction.
- Urea , the
main excretory product formed in the liver is carried away by the blood to
kidneys.
- Blood
transports soluble digested food materials which are absorbed in the
small intestine.
- Blood
provides a medium of transport for the hormones secreted by different
endocrine glands to reach their target organs.
- Blood also
transports water required by the cells to perform various biochemical
reactions.
Lymph
Lymph is a clear fluid sometimes white in colour comprises of white blood cells
mainly lymphocytes. Lymph is a colourless fluid that contains less protein
than plasma, and lacks RBC. These cells also attack bacteria entering the
cells. Lymph also contains the fluid from the intestine containing proteins and
fats. Lymph helps in carrying absorbed fat molecules from the
intestine to different parts of the body.The composition of lymph varies with
that of blood plasma. When the lymph is produced from the intestine, it
is thick milky white solution rich in triglycerides.
Types of
circulation
The two types of circulation are single circulation and double
circulation.
- Single
circulation is the type of circulation in which blood passes through the
heart only once through the heart. For example, it is seen in
fishes. Fish is a lower vertebrate with a two chambered heart. Fish
has a two chambered heart comprising of one atrium and one ventricle.
Gills help in purifying the deoxygenated blood. This two chambered heart
exhibits single mode of circulation. Impure blood is pumped to gills for
oxygenation. This oxygenated blood from gills is supplied directly to the
body tissues without sending to the heart.
- Incomplete
double circulation is observed in amphibians and reptiles which have
three-chambered hearts with two atria and one ventricle.
- Double
circulation is the type of circulation during which blood passes twice
through the heart. Higher vertebrates like birds and mammals exhibit
double circulation.
Blood pressure
Blood pressure is
the pressure exerted by the blood on the walls of the arteries.
- The pressure
can be systolic pressure during contraction and diastolic pressure at
relaxed state.
- The pressure
exerted by blood against the wall of an artery during ventricular
contraction or systole is called systolic pressure, and that exerted
during ventricular expansion or diastole is called diastolic
pressure.
- Normal blood
pressure is 120/80mmHg. If the blood pressure is less than 100/50 then it
is termed to be low blood pressure or hypotension. If it exceeds 140/90,
it is termed to be high blood pressure or hypertension.
- An
instrument called the sphygmomanometer is used to measure blood pressure.
The normal systolic pressure is about 120 mm of Hg, and diastolic pressure
is 80 mm of Hg.
Transport of
gases
We take in oxygen during inhalation and it reaches lungs through respiratory
tract. Hemoglobin, an intracellular protein is the primary vehicle for
transporting 97% of oxygen in the blood. 3% of Oxygen is carried by plasma.
Hemoglobin is contained in erythrocytes.
- The amount
of oxygen bound to the hemoglobin at any time is related to the partial
pressure of oxygen to which the hemoglobin is exposed. In the lungs, at
the alveolar-capillary interface, the partial pressure of oxygen is high,
and therefore the oxygen binds readily to hemoglobin. As the blood
circulates to other body tissue in which the partial pressure of oxygen is
less, the hemoglobin releases the oxygen into the tissue because the
hemoglobin cannot maintain its full bound capacity of oxygen in the
presence of lower oxygen partial pressures.
- Red blood
cells in the blood are flattened disc like structures responsible of
transporting oxygen and carbon dioxide gases. Red blood cells consist of
red iron-containing pigment called as haemoglobin. Haemoglobin is a
respiratory pigment that carries oxygen through red blood cells.
Oxygenated blood is carried to tissues.
- The exchange
of gases at tissue level is called as peripheral gas exchange. The
capillaries of circulatory system deliver the oxygen rich blood to the
tissues of the body. This oxygen diffuses across the walls of the
capillaries into tissues. In turn carbon dioxide diffuses into the blood
from tissues. The carbon dioxide diffused into the blood binds to
haemoglobin present in the blood to form carboxyhaemoglobin. This
de-oxygenated blood is carried to lungs for purification. In the lungs,
carbon dioxide from carboxyhaemoglobin dissociates leaving behind
haemoglobin. The cycle continues to cary oxygen from lungs to tissues and
carbon dioxide from tissues to lungs by haemoglobin.
Transportation in Plants
Plants obtain
minerals from soil, water and fertilisers. Need for transportation in plants is
to distribute water and nutrients to various parts. Transportation in a
plant is a method of circulation of water and minerals from soil throughout the
body of a plant.
Vascular tissues in transport
Vascular tissues like the xylem and phloem help in the conduction of water,
minerals and nutrients throughout a plant’s body.
a) Xylem is the vascular tissue extending from top to bottom of the plant.
- Xylem tissue
is present in the roots, stems and leaves.
- It helps in
the transport of water molecules and dissolved substances from the root
hairs to aerial parts of the plant.
- Xylem mainly
comprises of tracheids, vessels, xylem parenchyma and xylem sclerenchyma.
- The
transport in xylem is unidirectional.
- Xylem mostly
occupies the centre of the vascular bundle.
- The xylem
transports water and minerals from the roots to the leaves.
- Tracheids
and vessels are interconnected to form a continuous system of
water-conducting channels that reach all parts of a plant.
- Cells in the
roots take up ions to create a high ion concentration. This causes water
to move into the roots.
b) Phloem is the vascular tissue which transports food molecules to the place
of necessity in the plant.
- The elements
in the phloem are sieve elements, fibres, phloem parenchyma and companion
cells.
- The
transport in the phloem tissue is bidirectional.
- It forms
vascular bundles in association with xylem.
- Phloem
occupies the edges of the vascular bundle.
Transpiration
Transpiration is
the evaporation of water from the leaves in the form of water vapour.
Transpiration occurs in leaves through special structures present on them
called as stomata.Transpiration is the process which helps the plant in many
ways.
- Transpiration
always occurs against the gravity.
- Transpiration
involves mainly the xylem cells which become active during absorption
process by the roots.
- Excess water
is removed from the cells of the plant to prevent plant decay.
- Osmotic
balance of the cell is maintained by the process of transpiration.
- Transpiration
is the process which helps all the parts of the plant to cool them.
- Transpiration
helps in the distribution of dissolved substances to all parts of the
plant.
Translocation
Translocation is
the process of the movement of synthesised products from the leaves to the
roots and other parts of a plant’s body through the phloem.
- The phloem
is a conducting tissue for nutrients from the leaves to the other parts of
a plant’s body. Translocation does not always occur against gravity.
- Translocation
involves both xylem and phloem cells to carry the synthesized food
materials within the plant.
- As sugar is
synthesised in the leaves by the process of photosynthesis, a high
concentration of organic substance inside the phloem cells of the leaf
creates a diffusion gradient by which more water is sucked into the cells.
- Translocation
takes place in the sieve tubes, with the help of adjacent companion cells.
Types of transport
a) Passive transport can be explained by diffusion. Diffusion is the movement
of molecules in a random manner that is from a region of higher concentration
to a region of lower concentration. Diffusion involves no expenditure of energy
as it does not involve any semi-permeable mebrane.Diffusion is a process which
can occur in all media which involve solid, liquid and gaseous molecules.
Diffusion is a passive process which occurs in the transportation of substances
in plants.
b) Active transport involves the movement of ions against concentration
gradient through membranes. It is carried out with expenditure of energy.
Active transport requires carriers for transport across the cell membrane.
Active transport is involved in translocation os minerals in the plant body and
accumulation in the plant cells. e.g Glucose molecules in the leaves are
transferred to the phloem tissue using energy from ATP.
c) Osmosis is the process of diffusion of solvent particles from the region of
less solute concentration to a region of high solute concentration through
semi-permeable membrane. Osmosis can be observed in human beings in the
phenomenon of membrane transport. Cells possess cell membranes. These
cell membranes are selectively permeable and many molecules move in and out of
the cell by the process of osmosis.
Types of solutions
Osmosis can occur in hypertonic solutions, hypotonic solutions and isotonic
solutions. Sometimes cell can even undergo the phenomenon called as
plasmolysis.
- Hypotonic
solutions are the ones which have a lower concentration of solute than the
cell. Water diffuses into the cell to balance the solute concentration on
either side (outside and inside) equal. Here the cell swells up due to
entry of water.
- Hypertonic
solutions are the ones which have higher solute concentration than the
cell. Water moves out of the cell through cell membrane to balance the
concentration of the solute on either side. It results in cell shrinking
.This may also lead to desiccation of the cell.
- Isotonic
solutions have the same concentration of the solute as the cell. Water
moves in and out of the cell with no net change.
Excretion
Excretion
Excretion is the process of removing harmful metabolic wastes such as urea,
uric acid and salts from the body.
Excretion in organisms
- Unicellular
organisms, like amoeba, remove wastes by simple diffusion from the body
surface into the surrounding water.
- Lower
multi-cellular organisms like flat worms use flame cells while earthworms
use nephridia for excretion.
- Higher
multi-cellular organisms like fish, frogs, lizards, birds and humans use
kidneys for excretion. Homeostasis is the tendency of the
physiological system of higher animals to maintain internal stability of
the body.
Excretory system in humans
The excretory system in human beings includes a pair of kidneys, a pair of
ureters, a urinary bladder, and a urethra. This is also known as the urinary
system.
1) Kidney
Kidney is an excretory organ present in the human body. Kidneys act as
excretory organs and also control the balance of water and mineral ions in the
body. Kidney is divided into two parts namely, external region and internal
region.
- External
region is made up of a thick layer followed by a layer of fat. Fat acts as
a shock absorber.
- Inner region
comprises of renal cortex and renal medulla. The medulla is composed of
conical masses of tissue that lead to pelvis. The cortex has a random
arrangement of tiny tubules called nephrons which are the functional units
of the kidney.
Nephrons are the
microscopic basic filtration units of the kidney. Nephrons carry out an
important process of urine formation in the kidney. Ultra-filtration is the
first step in the urine formation in which nephrons filter minerals, waste and
water but retain red cells, proteins and large molecules. A single nephron
is made up of renal corpuscle and a renal tubule.
a) Renal corpuscle is made up of tangled clusters of tiny blood
capillaries called glomerulus and Bowman’s capsule.
- Glomerulus
is called the filtration unit.
- Bowman's
capsule surrounds the glomerulus.
b) Renal tubule
is made up of proximal convoluted tubule, Henle’s loop and distal convoluted
tubule.
- Renal tubule
leads away from Bowman's capsule and becomes highly coiled to form the
proximal convoluted tubule.
- The tubule
makes a hairpin loop, called the loop of Henle. It joins the distal
convoluted tubule.
- The distal
convoluted tubule opens into a collecting duct, which passes into the
renal medulla.
2) Ureter
Each ureter is a tubular structure which arises on from each kidney and join to
form a single tube which opens From each kidney, a ureter arises which opens
into the urinary bladder.
3) Urinary bladder
It is a muscular sac situated at the lower part of the abdomen which receives
urine from the kidney through ureters. It stores this urine until it becomes
full. Urinary bladder opens out through urethra. Urethra passes urine to the
outside of the body. The urethra emerges through the penis in males and close
to the vagina in females.
Excretory pathway in kidney – Blood is carried by the renal artery to the
nephron from there to renal pyramid leading to pelvis to the ureter, then to
the urinary bladder and finally to the urethra which passes it to outside.
Other organs of excretion
a) Skin
- Sweat glands
in the skin allow evaporation of excess water along with some salts which
have to be excreted out of the body. Sweating is a vital function of
your body. Sweating helps in thermoregulation of the body. Sweat glands
secrete fluids that will cool your body in cases of extreme heat.
- Sebaceous
glands in the skin excrete excess oil outside in the form of sebum.
b) Lungs
Lungs are the respiratory organs in human beings. Pulmonary artery carries
impure blood to the lungs from the heart.The alveolar cells of the lungs help
in exchange of oxygen with carbon dioxide to provide the former to
the bodily tissues. Lungs excretel carbon dioxide out of the body.
c) Anus
Anus is the opening of the alimentary canal to the exterior. Undigested waste
is stored in the rectum for defecation. Anus helps in the excretion of
faeces by the process of egestion.
Excretory pathway in kidney – Blood is carried by the renal artery to the
nephron from there to renal pyramid leading to pelvis, to the ureter, then to
the urinary bladder and finally to the urethra which passes it to outside.
Steps in urine formation
The kidney performs three functions as steps involved in urine formation -
ultra-filtration, selective re-absorption and tubular secretion.
- Ultra-filtration
is the process in which nephrons filter minerals, waste and water but
retain red cells, proteins and large molecules.
- Selective
re-absorption involves reabsorption of some substances of the initial
filtrate, such as glucose, amino acids, salts, and a major amount of
water. Urine is allowed to flow along the tube.
- Tubular
secretion involves the secretion of substances not required by the body
into the filtrate by the cells of the distal convoluted tubule before it
leaves the kidney.
Excretory substances
Excretory sunstances can be ammonia, urea and uric acid.
a) Ammonia is generated as a result of oxidative deamination
reactions occurring in the body. Ammonia is a toxic nitrogeneous waste and need
to be eliminated. It is very toxic to the body and requires more amount of
water to excrete it. Aquatic organisms excrete ammonia as they have water
around them. Terrestrial animals either convert ammonia into urea or uric
acid. Ammonia reaches the liver, the key site which converts this ammonia
into urea.
b) Urea is
the excretory waste of human beings. As a result of amino acid metabolism, many
nitrogeneous wastes like ammonia. As ammonia is toxic to human body when
retained, it is coverted into urea by the liver. Urea is also called as
carbamide. Urea , the main excretory product formed in the liver is carried
away by the blood to kidneys.
c) Uric
acid is a bicyclic, heterocyclic compound made by the combination of
carbon, hydrogen, oxygen and nitrogen. It is formed in the body during protein
metabolism. Animals that excrete their waste in the form of nucleic acid form
shelled eggs which are permeable to soluble gases. Most of the terrestrial
organisms which do not have much access to water excrete uric acid as their
excretory product. e.g.Reptiles, Birds. In human beings, it is formed as a
result of metabolism of food mainly containing purines. Uric acid formed
dissolves in the blood and taken to kidneys for excretion. It is very
concentrated and requires very less amount of water to be excreted along with
it. Excess of uric acid in the blood causes the disease called as gout.
Dialysis:
Dialysis is the process which involves separation of nitrogeneous wastes from
the blood artificially. Dialysis is performed using a device which removes
nitrogenous wastes from blood in case of kidney failure.
- An
artificial kidney contains a number of tubes with a semi-permeable lining
suspended in a tank filled with dialysing fluid.
- The
patient’s blood is passed through these tubes.
- During this
passage, waste products from the blood diffuse into the dialysing fluid.
- The purified
blood is pumped back into the patient.
Excretion is also observed in plants. Plants get rid of excess water by the
process of transpiration. Resins, gums and dead leaves are some excretory
products of plants.
How do
organism reproduce
Reproduction and Its
Significance
Reproduction
Reproduction is the biological process by which existing organisms give rise to
their offspring. Reproduction is carried out by different living organisms to
perpetuate their species. Reproduction can be of two types – Sexual mode
and Asexual mode.
- Reproduction
prevents all kinds of organisms from becoming extinct.
- Reproduction
is not necessary for carrying out life processes of an individual but
helps in increasing the individuals in a population.
- Reproduction
is essential in creating variations in species through genetic
recombination.
- Reproduction
is necessary in the process of evolution by carrying favourable variations
from one generation to another generation.
Evolution
It is a long, drawn out process with gradual changes that take place over
millions of years. Evolution operates on different factors like
variations, natural selection and adaptation. Evolution results in group
of organisms living together in a well-defined environment. Organisms
living in this specific environment reproduce the offspring which are adapted
to that specific environment. e.g. Over generations, giraffes developed long
necks to eat leaves growing high up on trees.
Evolution occurs by stages
Evolution is a step by step process, it does not happen in few years. It takes
generations by generations to exhibit variations over a large range. Organisms
get adapted to their habitat by bring about certain changes in their structure.
These changes are called as adaptations which bring about variations in the
evolution. These variations are carried on to successive generations by natural
selection.
- A classic
example which supports the statement 'Evolution by stages' is the
evolution of eye.
- In lower
organisms like planaria, optic sensory structures are present as
patches which act as eye spots.
- In organisms
like cockroaches, compound eyes are present which help them to see around
their body.
- In organisms
like octopus, eye is remarkable having iris, circular lens, vitreous
cavity, retina with photoreceptor cells. They lack a cornea. The lens in
octopus does not change its shape but focusses through movement.
- In
vertebrates, eye is a well-developed sensory structure with iris, ciliary
muscles, pupil, cornea and a lens. The size of the pupil can be regulated.
Shape of the lens can be adjusted in order to focus the image on the
retina.
Evolution cannot
be equated with progress
- Evolution is
not exactly taking place from lower organisms to higher organisms but it
can be related to the fact that higher and complex body forms evolved even
when the low and simple forms are still existing. An individual also plays
an important role in the evolutionary process. An individual contributes
its specific genes into the gene pool of the population during
transferring its genetic variations to its offspring.
- These
variations are carried on to successive generations by natural selection.
- If these
genetic variations get accumulated over a period of time, alter the
individuals of the subgroup and later give rise to new species.
Variations
These are the changes caused in the genetic material thereby bringing about
changes in the offspring.
- Deoxyribonucleic
acid is a genetic material present in chromosomes.
- It carries
information from parents to children.
- DNA
replication is the process of creating similar copies of DNA during
reproduction.
- Mutation
leads to variation in DNA.
- Variations
accumulated over a period of time are carried on to successive generations
by natural selection. These genetic variations alter the individuals of
the subgroup and later give rise to new species.
- Variations
in species bring about diversity.
Variations caused
by mutations can be beneficial or detrimental.
- Some
variations might cause new born cells to die or survive. The
surviving cells are similar to or different from each other.
- Variations
can help species to evolve and survive in adverse conditions. e.g.
Adaptation of giraffes, snakes and bacteria to the changing environment.
- Only
advantageous variations occurring in an individual are able to exist in
population. This is because variations which are detrimental cause the
death of the individual. Hence, there is no chance for the detrimental
variations to be carried to the next generation.
Varations are advantageous to species and not individuals
- Variations
are advantageous to species as the changes which are acquired by
variations are inherited by the offspring and certain alterations occur
over many generations to make the changes acquired by variations perfect.
- Variations
may prove to be advantageous or disadvantageous to the individual as the
life span of the individual is so small. Variations acquired by the
individual are not easily acceptable. Individual with variations is not
easily accepted into the group.
Adverse changes
in the environment can kill a species
Reproduction in
Unicellular and Multicellular Organisms
Reproduction
Reproduction is the phenomenon which involves the production of an offspring by
particular individual or individuals to propagate their species. Reproduction
is done during reproductive phase.
Reproduction
based on the number
Unicellular organisms are single celled forms whereas multicellular organisms
are made up of many cells. Depending upon the complexity of the body,
reproduction in unicellular organisms is different from that of multicellular
organisms.
- Unicellular organisms reproduce by asexual means. This
asexual mode of reproduction involves single parent to produce their
offspring. Different asexual modes of reproduction include binary fission,
multiple fission, fragmentation, budding etc.
- Multicellular organisms can chose both asexual and sexual
modes to reproduce their offspring. The mode of reproduction by organisms
depends upon the favourable and unfvourable conditions prevailing.
Types
of reproduction
Reproduction can be of two different types, namely, asexual reproduction and
sexual reproduction.
- Asexual mode of reproduction: It is a mode of reproduction in
which a single individual is responsible for creating a new generation of
species. Reproductive structures are not involved. Vegetative parts
of individuls are used for the process of reproduction. Gametes are
not formed. Single parent cell gives rise to daughter cell. Offspring
formed are exact individuals of the parents
- Sexual
mode of reproduction: It involves the union of two
opposite sex cells by the process of fertilisation to give rise to zygote,
the single cell. This type of reproduction involves two organisms, the
male and the female. Reproductive organs in humans produce gametes - eggs
and sperms. Egg is the female gamete produced by female reproductive
organ. Sperms are male gametes produced by male reproductive organ. A
zygote is the future individual formed by the fusion of an egg and a
sperm.
Types
of asexual reproduction
Different asexual modes of reproduction by which offspring can be produced are
binary fission, budding, fragmentation, regeneration, vegetative propagation,
spore formation etc.
1) Binary
fission: It
involves the longitudinal or transverse splitting of an organism into two equal
halves which develop into two separate individuals.
- Binary fission is generally seen in unicellular organisms
such as amoeba and paramecium falling into the category of protozoa.
- Amoeba is a simple, unicellular organism which reproduces by
transverse binary fission. The division begins with the division of
nucleus.
- Binary fission can also be observed in multicellular animals
like sea anemones and planarians.
- Binary fission observed in Leishmania is longitudinal binary
fission. Longitudinal binary fission is the division occurring in a
definite orientation in relation to the whip-like structures located at
one end of the cell.
2) Multiple fission: Multiple
fiision is the process by which organisms reproduce under unfavourable
conditions. Under unfavourable conditions, organism does not stop reproducing
but divides rapidly inside a cyst and forms many individuals inside the cyst,
when favourable conditions prevail, organism releases multiple individuals at
the same time which are formed by multiple fission
- Plasmodium is a malarial parasite which reproduces both
inside a mosquito and also in human being.
- It chooses multiple fission, asexual mode of reproduction for
producing the cells.
- Multiple fission is the division of mother cell into many
daughter cells simultaneously.
- A multinucleate mass is formed with rich cytoplasm which does
not undergo division until certain amount of time.
- The specific reason behind the organism reproducing by
multiple fission is that, it can divide itself into many cells at the same
time inside the cyst during unfavourable conditions in the host.
3) Budding: This is a form of asexual
reproduction which involves development of small mass of cells as protuberances
on the parental body to give rise to new structures called as buds.
- These buds separate out from the parental body and develop
into new individuals.
- Two types of budding are external budding and internal
budding.
- Yeast reproduces by beans of buds. Buds grow in chains or
detach from the parent and fall on the substratum. When buds are on the
substratum, they grow as new individuals.
4) Fragmentation: It involves breaking of parent
organism into two or many fragments. Each fragment develops into an individual
organism. Fragmentation is seen in sea stars which accidentally break their
body into fragments. Fragmentation is also observed in annelids, turbellarians
and some of poriferans. Spirogyra reproduces through fragmentation during
which each fragment grows into a new individual.
5) Regeneration: If the organism is cut up, its
pieces can grow into separate individuals. It occurs in some fully differentiated
organisms. Regeneration is also called morphallaxis. e.g. Hydra,
Planaria. Regeneration is referred to tissue repair to normal state. It is
restoration of normal structure and function of the organ. It is actually
replacement of damaged tissue with same type of cells. Some organisms like
lizards have the power of regenerating their tail.
6) Spore
formation: Spore
formation is one form of asexual reproduction. Spore formation is the method of
developing new individuals by forming reproductive structures called spores.
- A spore is a small spherical or oval structure which protects
the future individual in a thick protective covering.
- Spore germinates on a substratum under favourable conditions.
- Some organisms like ferns, some groups of fungi reproduce by
spore formation.
- Fungus reproduces by means of spores. Fungus like bread
mould produce spores which germinate on moist organic surfaces. The
cottony white mass on bread formed by fungus after spore germination is
called a mould. Spores can survive in extreme conditions because of the
protective hard coat.
7)
Vegetative propagation: Vegetative
propagation is one mode of asexual reproduction in plants.
- Vegetative propagation is the production of new plants
from the vegetative parts of the plant.
- Roots, stems and leaves are called the vegetative parts of a
plant. Any of these parts serve as vegetative propagules.
- Vegetative propagation takes place by different methods like
Grafting, Leaf propagation, Root propagation, underground stem propagation
etc.
- Though vegetative reproduction results in the production of
varieties of plants, offspring propagated through vegetative propagation
are more uniform to parents.
Vegetative
propagules
Vegetative propagules are the structures used to raise new plants. These are
the vegetative structures from the plant which are used to develop new
individuals. These can be like rhizome (ginger), runner(grass), bulbs(onion),
tuber (potato), leaves(bryophyllum).
Advantages
of vegetative propagation
- Vegetative propagation is an easier method than growing
plants from seeds.
- Vegetative propagation is used in plants which do not produce
seeds.
- Plants propagated through vegetative propagation require less
time to grow.
- Plants propagated through vegetative propagation are more
uniform to parents.
- Vegetative propagation helps in producing varieties in the
plants.
Disadvantages of vegetative propagation
- Plants produced by asexual reproduction are short lived than
the plants produced by sexual reproduction.
- The wood of vegetatively produced plants are small in size
hence is not costly.
- Vegetatively propagated plants cannot be cultivated on a
large scale.
- There os a reduction in plant vigour.
- Parent plants with diseases transfer their diseases to the
offspring.
Natural methods of vegetative propagation
a)
Leaf propagation: Bryophyllum
propagates vegetatively by the formation of leaf buds on the margins of a leaf.
When the buds come in contact with moist soil, each bud is capable of growing
into a new plant.
b)
Root propagation: Sweet
potato and Dhalia are capable of producing young ones from their roots.
c)
Stem propagation: Potato
giving rise to new plants is an example of stem propagation.
Artificial
methods of vegetative propagation
Many artificial methods are developed to propagate plants vegetatively.
Layering and grafting are some artificial methods of vegetative
propagation.
a)
Layering: This
involves bending of a young stem towards the ground and burying it under the
soil for development of roots . After a period of time, as the roots develop,
the bent stem is cut off from the parent plant. This acts as a new plant. e.g.
Jasmine.
b)
Cutting: It
involves planting a young cutting of the stem with buds into moist soil. This
develops roots which absorb nutrition from the soil and help in the growth of
new plant. e.g. Bougainvellia.
c)
Grafting: It
involves fusion of tissues of one plant with those of another plant. Grafting
is a vegetative method of propagation for apples and roses.
8)Tissue
culture: Plant
tissue culture is a method used to propagate exact copies of plants under
hygienic conditions. Tissue culture is the process of culturing single line
cells under sterile, controlled conditions, in vitro by exposing them to
nutrients, hormones and specific amount of sunlight. There are different steps
involved in the tissue culture process.
- Step 1: Material is selected and sterilized for propagation
of cells, in vitro initiating the process of culturing the cells.
- Step 2: The plant material is re-divided and placed in
separate plates with medium rich in plant growth regulators. These growth
regulators induce shoot formation. This process can be repeated till the
desired number of plants is obtained.
- Step 3: The hormones which induce the formation of root are
introduced into the medium. Now, complete plantlets are formed.
These plantlets are transferred from lab into the green house for further
growth.
9) Cloning
It is a type of asexual reproduction which involves the creation of an exact
copy of a biological entity.
- Cloning involves the process of forming a cell or a complete
individual from a body cell.
- A clone is created by inserting the complete genetic material
of a regular body cell from a donor into a recipient.
- Cloning is done in many animals including sheep, cattle, pigs
etc. But for the first time cloning of sheep was successful in producing a
clone of the parent sheep.
·
Reproduction in Animals
Reproductive
phase is the phase in the life of every individual which makes the individual
capable of reproducing the offspring. In the early reproductive phase,
individuals acquire changes in the body which result in the formation of germ
cells. Sperms are male germ cells and eggs are female germ cells. Reproductive
phase involves the changes in appearance and size of the bodily organs.
Puberty: It is the time during which there occur sexual and physical
changes which allow the transition of a child to an adult. Puberty starts at
the beginning of adolescence. The onset of puberty starts much earlier in girls,
between 8 and 13 years of age lasts 2 to 4 years. The onset of puberty is
marked by physical changes. A child becomes an adolescent.
- Different
changes in boys include change in the voice, active functioning of sweat
and sebaceous glands, growth of facial and body hair, enlargement of penis
etc.
- Different
changes in girls include growth of pubic hair, active functioning of sweat
and sebaceous glands, menstrual cycle, enlargement of breasts.
Adolescence: It is the period of life between the onset of puberty and
reaching adulthood, that is, the period that leads to reproductive maturity.
Adolescent is a general term for teenagers of both sexes. Adolescence is the
period of life that leads to reproductive maturity, making a person capable of
reproduction.
Male reproductive system: This system includes a pair of testis, vas
deferens and a muscular organ, the penis.
a) Testes: Testis is the main reproductive organ in males. A pair of
testis is placed in a structure called as scrotum which is located outside the
abdominal cavity. At lower temperature maintained by the scrotum, testes
produce sperms by the process of spermatogenesis. Sperms are the male gametes
possessing a head, body and a tail. Testes also secrete male sex hormones like
testosterone to regulate the development of sperms and the secondary sexual
characteristicsleading to puberty.
b) Vas deferens: Sperm duct is also known as vas deferens. They are two in
number, each one arising from testis placed on either side. They transport
sperms into penis. They also collect fluids secreted by different glands. These
secretions are rich in proteins to enrich the sperms. Sperms along with these
secretions form thick substance called as semen. Semen is conveyed to urethra
through which it is discharged outside. Prostate gland and seminal
vesicles secrete semen to make the movement of sperms easier.
c) Urethra: Urethra forms a common passage for both the sperm and urine as
it is just one tube that connects both the glands – urinary bladder and vas
deferens.
d) Penis: It is a part of male reproductive system. Penis is a muscular organ
which transfers semen into female reproductive tract. Penis receives both
urinary tube and sperm duct and serves as a common transporting organ for urine
and semen. It opens out through a small tube called as urethra. Penis is
underlined by thin blood vessels which give it continuous supply of blood.
Testes are placed in a structure called as scrotum which is located outside the
abdominal cavity. Scrotum helps in keeping the testes at lower temperatures.
Testes produce the male gametes known as sperms. Sperms are the male
gametes possessing a head, body and a tail. Testosterone is the male sex
hormone secreted by the testes. It regulates the development of sperms and the
secondary sexual characteristics leading to puberty.
Female reproductive system: This system includes a pair of ovaries,
a pair of oviducts, uterus and vagina opening out through urethra.
a) Ovary: A pair of ovaries forms the gonads in female. Ovaries are the
female sex organs that lie one on either side of the abdominal cavity. Ovaries
by the process of oogenesis form eggs or ova which are released as one per
month. Ovaries produce two hormones, namely, estrogen and progesterone.Estrogen
controls the changes that occur during puberty, like feminine voice, soft skin
and development of mammary glands, growth of pubic hair and controls the
release of mature eggs.Progesterone controls the uterine changes during
menstrual cycle, and helps in the maintenance of pregnancy.
b) Oviducts: A tube like structure arising from each ovary on either side
is called as an oviduct. This is also called as fallopian tube. The egg is
carried from the ovary to the uterus through a thin oviduct also known as the
fallopian tube.The two oviducts combine and open into an elastic bag-like
structureknown as the uterus.
c) Uterus: Uterus is a hollow muscular organ which has the capacity to
bear the child. It is otherwise called as womb. Zygote formed after
fertilisation in the fallopian tube travels downward by dividing itself
continuously to form an embryo. Embryo as it reaches the uterus gets implanted
into the wall of the uterus. After fertilisation, female reproductive hormones
bring in many changes to the uterus, so as to bear the growing embryo. As the
embryo grows, it transforms into foetus. Uterus is the organ which bears the
foetus.
d) Vagina: It is the reproductive part situated at the end of the uterus
in female reproductive tract. It connects uterus to the outside world. Vagina
secretes mucous to keep the tract wet. It opens out through vulva.
Eggs, the female gametes develop inside the ovaries. One mature egg is
released by either of the ovaries per month. Ovaries secrete two hormones
namely estrogen and progesterone which bring about secondary sexual characters
in females. The egg is carried from the ovary to the uterus through a thin
oviduct also known as the fallopian tube. The two oviducts combine and
open into an elastic bag-like structure known as the uterus. The uterus opens
into vagina through cervix. The uterus helps in the development of the foetus.
Fertilisation: Fertilisation is the fusion of male and female gametes to
give rise to a single cell – zygote. Fertilisation can be external
fertilisation or internal fertilisation.
- When male
and female gametes unite outside the body, it is called external
fertilisation
- When
fertilisation takes place inside the body, it is called internal
fertilisation.
- When
fertilisation takes place in a test tube, the offspring are called test
tube babies.
- Fertilisation
that takes place outside the human body is in vitro fertilisation.
Zygote: It is the super cell formed by the fusion of pronuclei of male
and female gametes. It divides repeatedly to form an embryo.
Embryo: It is transformed zygote with a three layers of cells.
This gets embedded in the wall of uterus, part of the female
reproductive system.The development of the embryo takes place in the mother’s
uterine wall.All parts of the body start developing in an embryo which finally
transforms itself into foetus.
Implantation: Embryo gets implanted in the lining of the
uterus for further development. The placenta is a connective tissue
established between foetus and the mother. It provides a large surface
area for the nutrients and oxygen to pass from mother to the embryo. It
also helps in transporting excretory wastes from embryo to mother.
Menstruation: The monthly cycle of changes in the ovaries and the
lining of uterus resulting in periodic discharge of blood, mucous and cellular
debris through vagina in the absence of fertilisation. This cycle takes
place roughly every month and is controlled by ovarian hormones. Menses lasts
for two to eight days.
Contraceptive devices: These are the devices which block the entry of
sperm into oviducts thereby preventing the egg from being fertilized.
- Condom is a
barrier method falling under the category of contraceptive methods.
Condoms are available for both males and females. These structures act as
barriers which prevent sperm from meeting the ovum. Condoms are made up of
thin rubber or latex sheath.
- The Copper T
is a simple intra-uterine device (IUD) made of a flexible, "T"
shaped piece of plastic wrapped with a thin copper containing wire. It is
a contraceptive device which prevents from getting pregnant. Copper ions
prevent pregnancy by inhibiting the movement of sperm as they are toxic to
sperm.
- Other than
this copper T cannot inhibit the action or kill bacteria or viruses which
cause different STDs.
- Vasectomy is
the surgical method executed for permanent birth control in males. It is
the sterilisation technique by which vas deferens from the testis is cut
or tied to prevent the mixing of sperm with the semen ejaculated from the
penis. Semen of vasectomised males will not have sperms in them. As semen
is devoid of sperms, there occurs no fertilisation of ovum produced by
females.
- Tubectomy is
a surgical method performed in females as a birth control method. It is a
permanent contraceptive method. Fallopian tubes emerging out of the
ovaries on either side are cut and tied. This is a permanent contraceptive
method as there occurs no fertilisation in the fallopian tube. Ovum cannot
reach the fallopian tube and wait there for the sperm coming to fertilise
it.
·
Reproductive health: It is a state of physical, emotional, mental and
social well-being in relation to sexuality. Reproductive health requires
positive approach to sexuality and healthiness of the individuals participating
in mating. Reproductive health also refers to the capability of satisfying the
partner. It also specifies the ability and freedom to reproduce.
Sexually transmitted diseases: STD stands for Sexually Transmitted
Diseases. These are the diseases which are transmitted from one person to
another during the sexual act between two individuals. STDs can be caused by
different microorganisms like bacteria, fungi, virus, protozoans etc. STDs can
mostly be prevented from transmission from one individual to another by using
protective or contraceptive devices. Gonorrhea, Syphillis, AIDS etc are some of
the examples of STDs.
·
Sexual Reproduction in Plants
·
Sexual reproduction:
This type of reproduction involves two organisms, the male and the female in
the process of producing the offspring. Sexual reproduction provides
greater variations in the DNA thereby making the offspring adapted for better
survival. Sexual reproduction ensures a mixing of the gene pool of the
species. Due to genetic recombination, variations occur in the process of
sexual reproduction.
Sexual
reproduction in plants:
Plants reproduce sexually by producing male gametes in the form of pollen and
the female gametes in the form of eggs.
Flower:
It is the main reproductive structure of a plant. A flower comprises sepals,
petals, stamens and carpels.
• Sepals and petals are considered to be
the accessory whorls of the flower as they do not take part in the process of
reproduction.
• Stamens and carpels are the reproductive
parts of a flower comprising germ cells. Germ cells help in the process of
reproduction.
• A unisexual flower contains either
stamens or carpels. For example, papaya and watermelon are unisexual flowers.
• A bisexual flower contains stamens as
well as carpels. For example, hibiscus and mustard flowers are bisexual.
• The stamen is the male reproductive
organ that consists of filament and anther. The anther produces male gametes in
the form of pollen grains.
• The carpel is the female reproductive
organ located at the centre of a flower. It consists of the ovary, style and
stigma. The ovary is the swollen part at the bottom of the carpel. Ovary
contains the female gametes in the form of eggs or ovules.
Pollination:
This is the transfer of pollen grains from the anther to the stigma of the
carpel.
• Different agents of pollination are
wind, water, animals, birds, insects, human beings etc.
• Petals attract insect or bird
pollinators by their colour, scent, and nectar, which may be secreted in some
part of the flower.
• Two types of pollination are
self-pollination and cross-pollination. Self-pollination involves the transfer
of pollen grains from anther to the stigma of the same flower.
Cross-pollination involves the transfer of pollen grains from anther of one
flower to the stigma of another flower.
• Pollen grains are trapped by sticky
stigma during the process of pollination.
• Pollen grains germinate on the stigma to
give rise to pollen tube which aids in the process of fertilisation.
Fertilisation:
This involves the fusion of male germ cell with the female germ cell resulting
in the formation of a single cell, the zygote. This process is also called as
syngamy.
• There occur many changes after
fertilisation. After fertilisation, the zygote divides repeatedly to form
an embryo which resides inside the seed.
• The ovule develops into a seed.
• The ovary ripens to form a fruit.
• Seed inside the fruit encloses the
embryo, the future plant.
Germination:
It is the growth of an embryonic plant residing inside the seed under
favourable conditions. It results in the formation of a new seedling
which further grows into a new plant. The factors essential for
germination are nutrients, water and proper temperature. Seed has an embryo
protected by reserved food materials in the form of cotyledons and also an
outer covering called as seed coat.
Heredity and Evolution
Heredity and
Variations
Trait is any characteristic that is
transferred from parent to offspring. e.g. height and colour.
The process of passing traits from parent to offspring is called heredity.
Variations are the minor differences between offspring and the parent.
Mendel
and his contributions
Gregor Johann Mendel was a pioneer among geneticists who put forward the
concept of inheritance of characteristics or traits from parent to offspring.
Mendel proposed the principle of inheritance and is known as the “Father of
Genetics”.
Mendel has chosen pea plants for his experimentation and found variations among
them.
Gene is a structural and functional unit of heredity and variations.
Gene is a DNA segment on the chromosome. Genes control the expression of
characteristics. Mendel called the genes to be factors.
Alleles are a pair of alternative forms of a gene. Each gene is present
in two alternative forms, each called an allele. Each allele controls a single
trait.
Traits can be either dominant or recessive. Tallness in a plant is a dominant
trait, controlled by a dominant allele and is represented by “T” (capital).
Shortness in a plant is a recessive trait, controlled by a recessive allele and
is represented by “t” (small).
• Homozygous is a condition in
which a gene possesses a pair of the same alleles (TT or tt) for a single
characteristic.
• Heterozygous is a condition
in which a gene possesses a pair of different alleles (Tt) for a single
characteristic.
Phenotype is a morphological expression of a single character. For example,
tallness or shortness represents the phenotype of the plant.
Genotype is the genetic make-up of a cell, an organism, or an individual (i.e.
the specific allele make-up of the individual), usually with reference to a
specific characteristic under consideration. Alleles combine to make a
genotype, such as TT or Tt or tt.
Punnett square is a statistical method that was used by Mendel to predict the
possible genotypes and phenotypes of the offspring.
Monohybrid
inheritance
It is the inheritance of a single characteristic controlled by different
alleles of the same gene.
• F1 generation is the first filial
generation offspring produced by crossing two parental strains. All the
progeny of F1 generation
were tall i.e. the traits of only one parent were visible.
• F2 generation is the second filial
generation offspring produced by crossing F1’s. The F2 progeny were not all tall. Instead,
one quarter of them was short indicating both the traits – that of tallness and
shortness were inherited in the F2 plants.
• Genotypic ratio – 1:2:1,
Phenotypic ratio – 3:1.
Dihybrid
inheritance
It is the simultaneous inheritance of two characters.
• Dihybrid inheritance is the
experimentation of two characteristics with their four contrasting traits.
• For instance, dihybrid
inheritance involves a plant producing round and yellow seeds (RR and YY)
crossing with a plant producing wrinkled green seeds (rr and yy).
• F1 progeny produces round and yellow
seeds (R and r, and Y and y) in which round and yellow are dominant traits.
• F2 progeny were similar to their parents
and produced round yellow seeds, while some of them produced wrinkled green
seeds. However, some plants of the F2 progeny even showed new combinations,
like round-green seeds and wrinkled-yellow seeds.
Sex
determination
It is a mechanism which determines the individual to be a male or a female
based on the sex chromosomes present in it. X and Y are the sex
chromosomes inherited one from each parent, determine the offspring to be a
male. X and X are the sex chromosomes inherited one from each parent,
determine the offspring to be a female. A child who inherits an X
chromosome from her father will be a girl, and one who inherits a Y chromosome
from him
Evolutionary
Relationships I
All the life on Earth has descended
from a common ancestor.
Evolution: It is the sequence of gradual changes
over millions of years in which new species are produced.
Charles Robert Darwin was an English naturalist who observed various species of
life on the earth and put forward the idea of “evolution of species by natural
selection.” He said that a species inherits its characters from its ancestors.
Variations: These are the differences among individuals
of a species caused by genetic and environmental factors.
Mutation: It is the change in the sequence of
the nitrogen base pairs in DNA. e.g. A mutation in the gene for green
colouration in green beetles leads to offspring with brown colouration.
Gene
flow: It is the
transfer of genes from one population to another due to migration. Breeding
between the brown and green beetles introduces new gene combinations into the
population.
Natural
selection: It
explains that organisms that are physiologically or behaviourally better
adapted for the environment are selected. Selected organisms can survive and
reproduce.
Genetic
drift: It is the
genetic variation in small populations caused by a specific environmental
factor.
Species: It can be defined as a group of
individuals of the same kind that can interbreed and produce fertile progeny.
Speciation: It is an event that splits a
population into two independent species which cannot reproduce among them.
• Process of speciation-Genetic drift: It occurs due
to changes in the frequencies of particular genes by chance alone. e.g. If a
hurricane strikes the mainland, and bananas with beetle eggs on them are washed
away to an island. This is called a genetic drift.
• Process of speciation - natural selection: These
are the variations caused in individuals due to natural selection which lead to
the formation of a new species. e.g. If the ecological conditions are slightly
different on the island as compared to the mainland, it leads to a change in
the morphology and food preferences in the organisms over the course of
generations.
• Process of speciation - splitting of population: A
population splits into different sub-populations due to geographical isolation
that leads to the formation of a new species.
Evolutionary
Relationships II
Characteristics
These are the hereditary traits transmitted from parent organisms to their
offspring.
Characteristics are of two types namely, homologous characteristics or
analogous characteristics
• Homologous characteristics
are organs that have the same basic structure and origin, but different
functions. For example, mammals, birds, reptiles and amphibians have four limbs
with the same basic limb layout because they have inherited the limbs from a
common ancestor. These limbs have been modified to perform different functions.
• Analogous characteristics
are organs that have different structures and are of different origin, but
perform same functions. For example, the design of the wings of bats and the
wings of birds look similar because they have a common purpose – to fly.
Fossils
Fossils are the remains or traces of a plant or animal that existed in a past
geological age, and that has been excavated from the soil.
Fossilisation is the process in which an organism is converted into a fossil.
Biological
convergence
This is a phenomenon by which two unrelated organisms become quite alike after
a period of time through few generations, if it is assumed that they have a
common ancestor. The eyes of the octopus and the eyes of vertebrates have
evolved independently. These similarities of structure, despite of different
origins provide a classic example of biological convergence.
Adaptation
A characteristic of a particular animal may, post-evolution be useful for
performing a totally different function.
For example, long feathers were considered to provide insulation in cold
weather. Some reptiles like the dinosaur had feathers but very few were
adapted for flying. In the present day, birds use feathers for flight, which is
an example of adaptation.
Artificial
selection
This is the usage of plants with desirable characteristics to produce new
varieties.
Broccoli, kohlrabi and kale are produced from its ancestor wild cabbage by
artificial selection.
The tools used to trace evolutionary relationships are excavation, time-dating,
studying fossils, and determining DNA sequences. These have been used for
studying human evolution.
LIGHT
- REFLECTION AND RAREFACTION
Reflection
Light
Light is
the form of energy, which enables us to interact with our surroundings in a most
effective way. Light causes the sensation of vision. There are two major
phenomena of light that takes place in the process of “seeing”. They are
“reflection” and “refraction”.
In general reflection is the process where the incident light on an object is
bounced back into the same medium.
Mirror
Most of all the objects reflect the light incident on them to different extent.
Some of the objects which have a smooth surface reflect the incident light to
the maximum extent. An object that reflects 100% of the incident light is
called a “mirror”. If the surface of the mirror is plane, it is referred to as
a plane mirror. Other types of mirrors are
curved mirrors.
We find our images in proper proportions in plane mirrors due to regular
reflection.
We cannot observe our images formed by plane mirrors on a screen as they are
virtual images unlike those which are formed on a screen and termed as real
images. The reflection that takes place on other surfaces other than plane
mirrors is irregular reflection. Irrespective of the type of reflection,
the light ray (which is the path of light) follows two laws of reflection.
Laws
of Reflection
The first law of reflection states
that the angle of incidence (i.e., the angle between the incident ray and the
normal at the point of incidence) is equal to the angle of reflection (i.e.,
the angle between the normal and the reflected ray). The second law of
reflection states that the incident ray, reflected ray and the corresponding
normal, all lie in the same plane.
Rear
View Mirror
The rear view mirror in a car is a plane mirror as it helps us to
estimate the distances of the vehicles that are behind our car in motion. In a
plane mirror, the object distance is equal to the image distance.
If we stand at any distance in front of one whose length is half your height we
can observe our full size image in a plane mirror.
If we rotate a plane mirror maintaining the object position, through certain
angle we find that the reflected ray rotates twice the angle.
Regular and Diffuse Reflection
The phenomenon of bouncing back of
light after falling on the surfaces of the objects is called reflection of
light.
The reflection of light is of of two types,
they are
In general, reflection is the process where the light incident on an object
bounces back into the same medium. This happens when light is incident on a
translucent or an opaque medium. When light is incident on a transparent
medium, all the incident light passes through the medium, and reflection does
not take place. In the case of translucent medium, a part of the incident light
is reflected, and the rest is transmitted through the medium.
We get light from a luminous object, which we refer to as a source of light. If
the size of the source of light is very small, then we call it a point source of light. If the size of the source
of light is considerable, then we say it is an extended source of light. Light rays from a point
source of light travel in all directions, moving away with time. Such a beam of
light is called a divergent beam of light.
If the light source is an extended source, then we get a parallel beam of light
from it. Consider a parallel beam of light from an extended source, incident on
a plane surface like a plane mirror. As the beam of light is parallel, and the
surface on which the beam is incident is a plane surface, the angle made by
each ray with the normal at the point of incidence on the surface is equal,
which implies that the angle of incidence of all the rays is equal.
Each ray of light follows the laws of reflection irrespective of whether it is
from a parallel beam or not. According to the laws of reflection, the angle of
reflection is equal to the angle of incidence.
Thus, for every ray of light incident
on the mirror, the angle of reflection is equal to its angle of incidence.
Regular
Reflection
As the angles of incidence of a
parallel beam of t all the ligh rays are equal for a smooth plane like a plane
mirror,the angles of reflection of all the rays equal. This implies that all
the reflected rays are parallel. When all the reflected rays, reflected from a
given surface, are parallel then it is called regular reflection.
Diffuse
Reflection
If the surface is not a plane surface,
then the reflected rays are not parallel to each other. In such a case, the
reflection is called diffused reflection.
The diffused reflection occurs at the rough or un polished or the slightly
polished non smooth or rough surfaces.
Figure above represents the light
falling over the rough surface.
As the rays of light falls on a rough surface at any angle of incidence then
the angle of reflection is equal to the angle of incidence.
Note:
Laws of reflection are valid for both
regular and irregular reflections of liht.
Spherical Mirrors
Terms
Associated with Spherical Mirrors
- Centre of curvature (C) is the centre of the sphere, of which
the mirror is a part.
- Radius of curvature (R) is the radius of the sphere, of which
the mirror is a part.
- Pole (P) is the geometric centre of the spherical mirror.
- Principal axis is the line joining the pole and the centre of
curvature.
- Principal focus (F) is the point on the principal axis, where
a parallel beam of light, parallel to the principal axis after reflection
converges in the case of a concave mirror and appears to diverge from in
the case of a convex mirror.
- Focal length (f) is the distance of the principal focus from
the pole of the mirror.
There are two types of images: real and virtual. Real images are those that can
be caught on a screen while virtual images are those that cannot be caught on a
screen.
Concave
Mirror
If a part of a hollow glass sphere is cut and the cut part of the sphere is
coated outside with silver or similar material, then its inner surface reflects
the entire light incident on it, and thus, forms a mirror. Since the inner
surface is a concave surface, the mirror so formed is called a concave mirror.
Concave mirrors converge the light incident on them and hence are called
converging mirrors. We can observe ourselves magnified when the
mirror is placed close to our face. This is due the position of the object
between the focus and the pole. As the object moves away from the mirror, the
size of its image reduces along with its distance from the mirror. If an object
is placed close to a concave mirror such that the distance between the mirror
and the object is less than its focal length, then a magnified and virtual
image is formed. Due to this property, concave mirrors are used as shaving
mirrors, and by dentists to view clearly the inner parts of the mouth.
Convex
Mirror
If the cut part of the glass sphere is coated from inside with silver or a
similar material, then its outer surface reflects the entire light incident on
it, and thus forms a mirror. Since the outer surface is a convex surface, the
mirror so formed is called a convex mirror.
Convex mirrors diverge the light incident on them and hence they are called the
diverging mirrors. Due to this they always form diminished, virtual and erect
images irrespective of the position of the object in front of them. Thus, the
magnification produced by these mirrors is always less than one. The field of
view for a convex mirror is greater than that for a plane mirror, the aperture
being the same. Hence, convex mirrors are used as rear-view mirrors in vehicles.
It is also installed behind automated teller machines as a security
measure.
Rules
for Construction of Ray Diagrams for Spherical Mirrors
Rule 1: A light ray incident parallel to the principal axis, after reflection,
either actually passes through the principal focus or appears to pass through
the principal focus.
Rule 2: A light ray which first passes through the principal focus or appears
to pass through the principal focus, after reflection, will travell parallel to
the principal axis.
Rule 3: A light ray which first passes through the centre of
curvature or appears to pass through the centre of curvature, after
reflection, retraces its initial path.
Image
Formation by Concave Mirror
Depending on the position of the object in front of the concave mirror, the
position, size and the nature of the image varies.
1. Object at infinity: A real, inverted, highly diminished image is
formed at the focal point F, in front of the concave mirror.
2. Object beyond C: A real, inverted, diminished image is formed between C
and F, in front of the concave mirror.
3. Object at C: A real, inverted, same sized image is formed at C, in
front of the concave mirror.
4. Object between C and F: A real, inverted, enlarged image is formed
beyond C, in front of the concave mirror.
5. Object at F: A real, inverted, highly enlarged image is formed at
infinity, in front of the concave mirror.
6. Object between F and P: A virtual, erect and enlarged image is formed behind
the concave mirror.
Image
Formation by Convex Mirror
Irrespective of the position of the object, a virtual, erect and diminished
image is formed between F and P, behind the convex mirror.
Mirror
Formula and Sign Conventions
The relation between the focal length (f), object distance (u) and the image
distance (v) is given by 1/f = 1/v + 1/u. This is called the mirror
formula. All the distances are measured from the pole of the mirror. If we
measure the distances in the direction of the incident light, then they are taken
positive or else they are taken negative. These constitute the sign
conventions.
Uses
of Concave Mirrors
- Concave mirrors are used as shaving mirrors to see a larger
image of the face.
- Dentists use concave mirrors to view the back of the tooth.
- ENT doctors use them for examining the internal parts of the
ear, nose and throat.
- They are used as reflectors in the headlights of vehicles,
search lights and in torch lights to produce a strong parallel beam of
light.
- Huge concave mirrors are used to focus sunlight to produce
heat in solar furnaces.
Uses
of Convex Mirrors
- Used as rear view mirrors in automobiles as it covers wide
area behind the driver.
Spherical Mirrors
Mirrors are the basic means of viewing our
own beauty. Generally we can classify the mirrors into the following two types
as
i. Plane mirrors
ii. Curved mirrors.
Generally mirrors refer to plane mirrors. But if the surface of a mirror
is curved it is said to be a curved mirror. If the curved mirror is a part of a
huge sphere, then the mirror is a spherical mirror.
Terms
Associated with Spherical Mirrors
- Centre of curvature (C) is the centre of the sphere, of which
the mirror is a part.
- Radius of curvature (R) is the radius of the sphere, of which
the mirror is a part.
- Pole (P) is the geometric centre of the spherical mirror.
- Principal axis is the line joining the pole and the centre of
curvature.
- Principal focus (F) is the point on the principal axis, where
a parallel beam of light, parallel to the principal axis after reflection
converges in the case of a concave mirror and appears to diverge from in
the case of a convex mirror.
- Focal length (f) is the distance of the principal focus from
the pole of the mirror.
Spherical
mirrors can be further classified into the following two types as
i. Concave mirrors
ii . Convex mirrors.
The images formed by the mirrors are of two types they are
i. Real images
ii. Virtual Images
Real images are those that can be caught on a screen while virtual images are
those that cannot be caught on a screen.
Formation
of Images by Spherical Mirrors
The image formed by a convex mirror is always erect, virtual, and diminished in
size. The location of the object does not affect the characteristics of the
image. Thus, as the object approaches the mirror, the image approaches the
mirror too but not proportionately. This is why, the rear view mirrors of the
cars and bikes are made of convex mirrors.
Hence, we have the caution “Objects seen in the mirror are closer than they
appear” printed on the outside rear view mirrors of vehicles.
Unlike in a convex mirror, the nature and size of the image in a concave mirror
depends on the distance of the object from the mirror.
Concave
Mirror
If a part of a hollow glass sphere is cut and the cut part of the sphere is
coated outside with silver or similar material, then its inner surface reflects
the entire light incident on it, and thus, forms a mirror. Since the inner
surface is a concave surface, the mirror so formed is called a concave mirror.
- The geometric centre of a concave mirror is called its
pole.
- The centre of the sphere from which concave mirror was cut is
called the centre of curvature of the concave mirror.
- The distance from any point on the concave mirror to its
centre of curvature is called the radius of curvature of the concave
mirror.
- An imaginary line passing through the centre of curvature and
the pole of the concave mirror is called principal axis of
the concave mirror.
- The area of a concave mirror that is exposed to
incident light is
called the aperture of
the concave mirror.
- The length along the principal axis from the pole to the
principal focus is called the focal length of the concave mirror.
If an object is placed close to a
concave mirror such that the distance between the mirror and the object is less
than its focal length, then a magnified and virtual image is formed. Due to
this property, concave mirrors are used in many applications. A concave mirror
can be used as a shaving mirror, and by dentists to view clearly the inner
parts of the mouth.
Concave mirrors converge the light incident on them and hence are called
converging mirrors. We can observe ourselves magnified when the
mirror is placed close to our face. This is due the position of the object
between the focus and the pole. As the object moves away from the mirror, the
size of its image reduces along with its distance from the mirror. If an object
is placed close to a concave mirror such that the distance between the mirror
and the object is less than its focal length, then a magnified and virtual
image is formed. Due to this property, concave mirrors are used as shaving
mirrors, and by dentists to view clearly the inner parts of the mouth.
Reflection
by Concave Mirrors
|
Incident
Ray
|
Reflected
Ray
|
|
Parallel
to principal axis
|
Passes
through focus
|
|
Passes
through C
|
Retraces
its path
|
|
Passes
through focus
|
parallel
to principal axis
|
|
Strikes
the pole at an angle eith principal axis
|
Makes the
same angle with principal axis
|
Image
Formation by Concave Mirror
Depending on the position of the object in front of the concave mirror, the
position, size and the nature of the image varies.
Object
at infinity
A real, inverted, highly diminished image is formed at the focal point F, in
front of the concave mirror.
Object
beyond C
A real, inverted, diminished image is formed between C and F, in front of the
concave mirror.
Object
at C
A real, inverted, same sized image is formed at C, in front of the concave
mirror.
Object
between C and F
A real, inverted, enlarged image is formed beyond C, in front of the concave
mirror.
Object
at F
A real, inverted, highly enlarged image is formed at infinity, in front of the
concave mirror.
Object
between F and P
A virtual, erect and enlarged image is formed behind the concave mirror.
Image
Formation by a Concave Mirror
|
Object Location
|
Image Location
|
Nature of Image
|
|
Infinity
|
At F
|
• Real
• Inverted
• Highly Diminished
|
|
Beyond C
|
Beyond F and C
|
• Real
• Inverted
• Diminished
|
|
At C
|
At C
|
• Real
• Inverted
• Equal to size of object
|
|
Between C and F
|
Beyond C
|
• Real
• Inverted
• Magnified
|
|
At F
|
Infinity
|
• Real
• Inverted
• Highly Magnified
|
|
Between F and P
|
Behind the mirror
|
• Virtual
• Erect
• Magnified
|
Uses
of Concave Mirrors
- Concave mirrors are used as shaving mirrors to see a larger
image of the face.
·
Dentists use concave mirrors to
view a magnified view of the interior parts of the mouth are concave.
- ENT doctors use them for examining the internal parts of the
ear, nose and throat.
- They are used as reflectors in the headlights of vehicles,
search lights and in torch lights to produce a strong parallel beam of
light.
- Huge concave mirrors are used to focus sunlight to produce
heat in solar furnaces.
Convex
Mirror
If the cut part of the glass sphere is coated from inside with silver or a
similar material, then its outer surface reflects the entire light incident on
it, and thus forms a mirror. Since the outer surface is a convex surface, the
mirror so formed is called a convex mirror.
- The geometric centre of a convex mirror is called its
pole.
- The centre of the sphere from which the mirror was cut is
called the centre of curvature of the mirror.
- The distance from any point on the convex mirror to its
centre of curvature is called the radius of curvature.
- An imaginary line passing through the centre of curvature and
the pole of the mirror is called its principal axis.
- The reflected rays, when projected backwards, appear to meet
at a point on the principal axis. This point is called the principal
focus. The length along the principal axis from the pole to the principal
focus is called the focal length.
- The area of a convex mirror that is exposed to incident light
is called the aperture. If the aperture of a convex mirror is small, then
its focal length is equal to half its radius of curvature.
Convex
mirrors diverge the light incident on them and hence they are called the
diverging mirrors. Due to this they always form diminished, virtual and erect
images irrespective of the position of the object in front of them. Thus, the
magnification produced by these mirrors is always less than one. The field of
view for a convex mirror is greater than that for a plane mirror, the aperture
being the same. Hence, convex mirrors are used as rear-view mirrors in
vehicles. It is also installed behind automated teller machines as a security
measure.
The field of view for a convex mirror is greater than that for a plane mirror,
the aperture being the same. Hence, convex mirrors are used as rear-view
mirrors in vehicles. It is also installed behind automated teller machines as a
security measure. The images formed by convex mirrors are always diminished,
virtual and erect, irrespective of the position of the object.
Reflection
by Convex Mirror
|
Incident Ray
|
Reflected
Ray
|
|
Parallel
to principal axis
|
Appears
to pass through focus
|
|
Directed
towards the focus
|
Appears
to pass parallel to principal axis
|
|
Strikes
the pole at an angle eith principal axis
|
Makes the
same angle with principal axis
|
Image
Formation by Convex Mirror
Irrespective of the position of the object, a virtual, erect and diminished
image is formed between F and P, behind the convex mirror.
Uses
of Convex Mirrors
- Used as rear view mirrors in automobiles as it covers wide
area behind the driver.
- Used as reflectors for street light bulbs as it diverges
light rays over a wide area.
- Used as Rear
view mirrors of vehicles and the ones used in ATM centres.
Sign Convention for Spherical Mirrors
·
Object is always considered at the left of mirror
·
Distances measured along y-axis above the principal axis are taken
as positive and that measured along y-axis below the principal axis are taken
as negative.
·
Distances measured in the direction of the incident ray are taken
as positive and the distances measured in the direction opposite to that of the
incident rays are taken as negative.
·
All distances are measured from the pole of the mirror.
Table
Showing the Sign Convention
|
Types of Mirror
|
u
|
v
|
f
|
R
|
Height of the Object
|
Height of the Image
|
|
Real
|
Virtual
|
Real
|
Virtual
|
|
Concave mirror
|
–
|
–
|
+
|
–
|
–
|
+
|
–
|
+
|
|
Convex mirror
|
–
|
No real image
|
+
|
+
|
+
|
+
|
No real image
|
+
|
Rules
for Construction of Ray Diagrams for Spherical Mirrors
Rule 1: A light ray incident parallel to the principal axis, after reflection,
either actually passes through the principal focus or appears to pass through
the principal focus.
Rule 2: A light ray which first passes through the principal focus or appears
to pass through the principal focus, after reflection, will travell parallel to
the principal axis.
Rule 3: A light ray which first passes through the centre of
curvature or appears to pass through the centre of curvature, after
reflection, retraces its initial path.
Mirror
Formula
The relation between the focal length (f), object distance (u) and the image
distance (v) is given by
1 f = 1 v + 1 u
Magnification
The
ratio of the height of the image in a spherical mirror, to the height of the
object is called magnification (m)
Magnification (M) = Heigth
of the Image (Hi) Height
of the Object (Ho) = Image Distance (v) Object distance(u)
The distance from the principal focus to the pole of the mirror is the focal
length of the mirror and is equal to half the radius of curvature, which is the
distance between the centre of curvature and the pole.
For a real image object distance (u) and the image distance (v) are negative
and the magnification is negative. If the magnification of an image is
negative it does mean that the image is real and inverted.
On the other hand for a virtual image object distance (u) is negative and image
distance (v) is positive and hence the magnification is positive, i.e., the
image is erect. If the magnification of an image is positive it does mean
that the image is virtual and erected.
If the magnification is less than 1 The image formed is diminished in size.
If the magnification is more than 1 The image formed is magnified in size.
If the magnification is equal to 1 The image formed is equal to the
object in size.
Differences
Between Convex Mirror and Concave Mirror
|
Convex
Mirror
|
Concave Mirror
|
|
1. Convex mirror is curved outwards.
2. The focal point of convex mirror is behind the mirror.
3. In convex mirror the image is always virtual, upright and smaller than the
object.
4. Convex mirrors are used in cars (as passenger-side mirror since they
provide upright and wide view), they are also used in camera phones, for
safety measures there are also used in roads and driveways.
Besides these convex mirrors are found in many hospitals, schools etc. as
hallway safety mirror.
5. It has a virtual focus.
|
1. Concave mirror is curved inwards.
2. The focal point of concave mirror is in front of the mirror.
3. In case of concave mirror different types of images are formed on
different location of the object. The image is upside down (inverted) and far
away but if we bring the object close to the mirror then image will be larger
and upright.
4. Concave mirrors are used in telescope. These are also used as make up and
shaving mirrors since these provide larger images.
Besides these concave mirrors are used by dentists and also used in
headlights of cars, solar devices, satellite dishes etc.
5. It has a real focus.
|
·
Refraction Basics
- Light bends while travelling from one medium to another as
its velocity differs from one medium to another. The change in the
directionof the path of light, when it passes from one transparent medium
to the another transparent medium is called refraction of light.The refraction is a surface phenomenon.
The speed of light in optically rarer medium is larger compared to that in
optically denser medium. Hence, while travelling from one medium to
another, light bends. Light ray passing from rarer to denser medium bends
towards the normal. This makes the angle of incidence (angle between the
incident ray and the normal at the point of incidence) larger than that of
the angle of refraction (angle between the normal and the refracted ray).
The incident ray, the normal and the refracted ray, all lie in a plane. If
the light ray retraces its path while travelling from denser to rarer, the
angle of incidence is lesser than that of the refraction. This is the principle of reversibility.
The extent to which a light ray bends depends on the refrangibility of the
ray with respect to the medium. The ratio of velocity of light in vacuum
to that in a medium, which is the absolute refractive index (m) of the
medium, is the measure of the ability of light to get bend in the given
medium. Measuring speed of light is difficult. Hence, Snell’s law helps to
determine the refractive index. According to Snell’s law,
µ = Sin i Sin r
When a light ray, incident at an angle, passes through a glass slab, the
emergent ray is shifted laterally. The lateral shift depends on the
thickness and refractive index of the glass slab.
When a light ray bends from denser to rarer medium, it bends away from the
normal. If the angle of incidence gradually increases, the angle of
refraction too increases. At a particular angle of incidence in the denser
medium, the refracted ray emerges along the surface. That particular angle
is the critical angle. If the angle of incidence is greater than the
critical angle, the ray undergoes total internal reflection. It is due to
this phenomenon we observe mirages in deserts.
The bottom of a water glass appears to rise upwards when viewed normally.
This is due to the vertical shift of the bottom of the glass, which takes
place because of refraction.
Terms
Used for Lens
Centre
of Curvature: The
centre of the imaginary glass sphere of which the lens is a part, is
called centre of curvature.
Principal
Axis: An
imaginary line joining the centres of curvature of the two spheres, of
which lens is a part, is called Principal Axis.
Optical
Centre: A
point within the lens, where a line drawn through the diameter of lens
meets principal axis, is called optical centre.
Principal
Focus for Convex Lens: It
is a point on the principal axis of a convex lens, where parallel
beam of light rays, travelling parallel to principal axis, after passing
through the lens actually meet.
Principal
Focus for Concave Lens: It
is a point on the principal axis of a concave lens, from where parallel
beam of light rays, travelling parallel to principal axis, after passing
through the lens, appears to come.
Focal
Length: The
distance between principal focus and optical centre is called focal
length.
Aperture: The effective diameter of the lens through which refration takes
place is called aperture of lens.
Optic centre is a point on the axis of a lens such that any light ray
passing through this point emerges without refraction.
• Principal focus is a point on the
axis of a lens.
• Principal focus is also known as
the focal point
·
Refraction by Spherical Lenses
Lenses are
the most used things in optical devices like microscopes and telescopes. Bi-convex and bi-concave lenses
are the most popular ones in use among school labs. Lenses use the phenomenon
of refraction of light to
form images.
Concave lens diverge the light incident on it. Hence, called the diverging
lens. Due to this these lenses always form diminished, virtual and erect images
irrespective of the position of the object in front of them. Thus, the
magnification produced by these lenses is always less than one.
Convex lenses converge the light and hence are called the converging lenses.
You can observe the magnified image of your palm when the lens is placed close
to your palm. This is due the position of the object between the focus and the
optic centre. As the object moves away from the lens, the size of its image
reduces along with its distance from the lens. Convex lenses form erect,
virtual, magnified images or inverted, real, diminished/magnified images
depending on the position of the object.
Lens
A lens is a piece of transparent optical material with one or two curved
surfaces to refract light rays.
It may converge or diverge light rays to form an image.
A bi-convex lens is one with a surface that is bulged outwards on both the
sides. It is generally referred to as a convex lens.
Another type of a lens is a bi-concave lens that has two inward bent surfaces.
It is generally referred to as a concave lens.
A Plano-convex lens has a convex
surface on one side and a plane surface on the other.
A Plano-concave lens is the one that has a concave surface on one side and a
plane surface on the other.
A concavo-convex lens has a concave surface on one side and a convex surface on
the other.
Convex and concave lenses are important as they are more commonly used than the
other types of lenses.
Terms
Used for Lens
Centre
of Curvature: The
centre of the imaginary glass sphere of which the lens is a part, is called
centre of curvature.
Principal
Axis: An
imaginary line joining the centres of curvature of the two spheres, of which
lens is a part, is called Principal Axis.
Optical
Centre: A
point within the lens, where a line drawn through the diameter of lens meets
principal axis, is called optical centre.
Principal
Focus for Convex Lens: It is a point on the principal axis
of a concex lens, where parallel beam of light rays, travelling parallel
to principal axis, after passing through the lens actually meet.
Principal
Focus for Concave Lens: It
is a point on the principal axis of a concave lens, from where parallel beam of
light rays, travelling parallel to principal axis, after passing through the
lens, appears to come.
Focal
Length: The
distance between principal focus and optical centre is called focal length.
Aperture: The effective diameter of the lens through which refration takes place is called aperture of
lens.
Optic centre is a point on the axis of
a lens such that any light ray passing through this point emerges without refraction.
• Principal
focus is a point on the axis of a lens.
• Principal
focus is also known as the focal point.
Convex
Lens:
• A
lens in which both the surfaces are convex, is known as convex lens
• Light
rays incident on a convex lens get converged at its focus
• Used
by palmists and fingerprint experts
• If
an incident ray passes through a focus and its emergent ray passes parallel to
the principal axis, then that focus is called the first principal focus.
• If
an incident ray passes parallel to the principal axis, and its emergent ray
converges at a focus, then that focus is called the second principal
focus.
• The
distance between the optic centre and the focal point is called the focal
length.
Behaviour
of Light Rays Propagating Through a Convex Lens
|
Incident Ray
|
Emergent Ray
|
|
Is parallel to principal axis
|
Passes through focus
|
|
Passes through optic centre
|
Passes with out deviation
|
|
passes through focus
|
Passes parallel to principal axis
|
Location
and Characteristics of Images Formed by a Convex Lens
|
Object Location
|
Image Location
|
Nature of Image
|
|
Infinity
|
At F2
|
Real
Inverted
Highly Diminished
|
|
Beyond 2F1
|
Between F2 and 2F2
|
Real
Inverted
Diminished
|
|
At 2F1
|
At 2F2
|
Real
Inverted
Equal in size to that of the object
|
|
Between 2F1 and F1
|
Beyond 2F2
|
Real
Inverted
Magnified
|
|
At F1
|
Infinity
|
Real
Inverted
Highly Magnified
|
|
Between F1 and O
|
On the same side of lens as the
object
|
Virtual
Erect
Magnified
|
Concave
Lens
A lens, in which both the surfaces are concave, is known as a concave
lens.
An image formed by a concave lens is always diminished due to the divergence of
rays. This is why concave lenses are widely used to correct eye defects such as
myopia.
A concave lens is also known as a diverging, reducing, negative and myopic or
minus lens.
Behaviour
of Light Rays Propagating Through a Concave Lens
|
Incident Ray
|
Emergent Ray
|
|
Is parallel to principal axis
|
Appears to pass through focus
|
|
Passes through optic centre
|
Passes without deviation
|
|
Is directed towards focus
|
Passes parallel to principal axis
|
The lens formula defines the relationship between the focal length of
the lens (f), the distance of the object from the optic centre (u) and the
distance of the image from the optic centre (v):
1 f
= 1 v - 1 u
Where,
f = focal length
u = object distance
v = image distance
Location
and Characteristic of the Images Formed by a Concave Lens
|
Object Location
|
Image Location
|
Nature of Image
|
|
Infinity
|
As a point at F1
|
Virtual
Erect
Highly Diminished
|
|
Beyond 2F1
|
Between F1 and O
|
Virtual
Erect
Diminished
|
Sign
convention for spherical lenses:
·
All distances measured above the principal axis are taken as
positive. Thus, height of an object and that of an erect image are positive and
all distances measured below the principal axis are taken as negative.
·
The distances measured in the direction of incident rays are taken
as positive and all the distances measured in the direction opposite to that of
the incident rays are taken as negative.
·
All distances on the principal axis are measured from the optic
center.
Lens
Formula and Sign Conventions
1 f = 1 v - 1 u
Where,
f = focal length
u = object distance
v = image distance
All the distances are to be measured from the optic centre of the lens:
The distances measured in the direction of the incident light are taken as
positive (+).
The distances measured in the direction opposite to that of the incident light
are taken as negative (-).
Magnification
(m)
Magnification is the ratio of the image size to the object size. It is also
measured as the ratio of image distance to object distance.
m = (Size of the image / Size of Object ) Or m = (Image distance / Object
distance)
If m = 1; image size = object size
If m > 1: image size > object size
If m < 1: image size < object size
Power
of Lens (P)
• The converging or diverging capacity of
a lens is ascertained by its power
• Power of a lens is the reciprocal of its
focal length expressed in metre. P = 1 f (
measured in meters).
• SI Unit of power of a lens is dioptre
(D).
• Power of a convex lens is positive and
that of a concave lens is negative.
Differences
Between Convex Lens and Concave Lens
|
Convex Lens
|
Concave Lens
|
|
1. It is thick in the middle
and thin at the edges.
2. It converges the incident rays towards the principal axis.
3. It has a real focus.
|
1. It is thin in the middle
and thick at the edges.
2. It diverges the incident rays away from the principal axis.
3. It has a virtual focus.
|
- HUMAN EYE
AND COLOURFUL WORLD
Human Eye
Human eye is
the most important organ of our body which is an optical device that serves as
our organ of sight. It consists of a tough fibrous membrane called sclera that
protects the internal parts of the eye.
Cornea is the membrane covering the front of the eye that is bulged out and is
responsible for the maximum refraction
of the light that
enters the eye.
Aqueous humour lies behind cornea that enables the eye to cope up with the
atmospheric changes.
Iris forms the coloured part of the eye. It adjusts the size of the pupil,
thereby controls the amount of light entering the eye.
the crystalline lens, lies behind Iris a biconvex structure that helps in
fine adjustment to the refracted light so that it is focused on the screen of
the eye, which is referred to as retina.
Ciliary muscle helps in adjusting the focal length of the lens by contraction
or relaxing. Vitreous humour lies behind the lens which is a dense, clear,
jelly like fluid which helps to maintain the shape of the eye and
focus the image clearly on the retina.
Retina is actually a canopy of the nerve endings of the optical nerve through
which images are converted into electrical impulses and transferred to the
brain for realization of the image.
The eye can focus near objects as well distant objects and this is
accommodation of the eye. The minimum distance of the object at which an eye
can focus clearly is the near point the maximum is called the far point.
If an eye is unable to focus the nearby objects and is able to view clearly the
far off objects, the defect is called hypermetropia or long sightedness and can
be corrected by a suitable convex lens.
On the other hand if a person is able to view the nearby objects clearly and
unable to view the distant objects the defect is myopia or short sightedness
and can be corrected by a suitable concave lens.
The power of the corrective lens is calculated by using lens formula and is
measured in dioptre. The major parts of the human eye and
their functions are as the following:
Functions
of the Parts of Human Eye
Sclera
Protects and contains internal parts
Cornea
Cornea is responsible for maximum refraction of
incident light
Aqueous
Humour
Prevents collapse of the eye due to atmospheric pressure changes
Iris
Iris controls the light entering the eye by adjusting the size of pupil
Crystalline
Lens
Focuses the light reflected by objects on the retina.
Ciliary
Muscles
Alter focal length of the crystalline lens
Retina
Receives optical image and converts it to electrical impulses
Vitreous
Humour
Maintains the shape of the eye
Optic
Nerve
Carries electrical impulses to the brain. Brain interprets these impulses and
produces the sense of vision.
The functioning of a camera is similar to that of the eye.
Accommodation
The ability of the eye to change the focus between objects at different
distances by altering the curvature of the lens is called accommodation.
• To form a clear image of
different objects at different distances from the eye, the focal length of the
eye lens has to be changed.
• The contraction and
relaxation of ciliary muscles helps to alter the curvature of the lens.
• Far point is the maximum
distance from the eye at which the eye can obtain a focused image of an object
without straining.
Far
point
The farthest point upto which a shortt sighted eye can see clearlyis called the
farpoint of the eye. For a normal human eye, the far point is infinity.
Near
Point
Near point is the minimum distance at which the eye can obtain a focused image
of an object without straining. For a normal human eye, of an adultthe near
point is about25 cm from the eye.
Least
Distance of Distinct Vision
The minimum distance required between the object and the eye to view the object
comfortably is called the least distance of distinct vision.
• Long exposure of the eyes to
ultraviolet light, effects of diabetes, hypertension and old age can result in
a condition called cataract.
• Cataract results in a cloudy
translucent eye lens. This cloudiness affects the ability of the eye to
accommodate.
• The horizontal field of view
for a single eye is 150o.
• Stereovision position of the
eyes, help us to see the maximum possible number of objects around us.
Factors
causing irregularities in vision
• Irregularities on the
surface of the cornea
• Development of cataract
• Weakening of ciliary muscles
• Change in the size of the
eyeball
These irregularities lead to the
following three major types of defective vision.
• Myopia
• Hypermetropia
• Presbyopia
Myopia
Myopia, also known as short sightedness or near sightedness, is a defect in
which a human eye can see nearby objects clearly but distant objects appear
blurred and unclear.
Myopia can be corrected by placing a suitable concave lens in the line of sight.
Hypermetropia
Hypermetropia also known as long sightedness is a defect of vision in which a human
eye has problems seeing objects located nearby, clearly.
• A person suffering from
hypermetropia can see distant objects clearly.
• Hypermetropia occurs when
the converging power of the eye lens is less than normal.
• Hypermetropia can be
corrected by placing a suitable convex lens in the line of sight.
Presbyopia
Presbyopia is a condition in which the crystalline lens of an eye loses its
flexibility.
Persons suffering from presbyopia are unable to read or see clearly even at the
least distance of distinct vision, which is 25 centimetre. To correct
presbyopia, a bifocal lens is used.
Correction
of Hypermetropia and Myopia
To correct the short sightedness i.e. Myopia a concave lens whose focal length
is equal to the distance of the far poin tof the myopic eye is to be placed in
front of the the myopic eye.
To correct the Longt sightedness i.e. Myopia a converging i.e. convex lens of
suitable focal length is used. When it is placed before the eye lens, the final
image is focussed on to the retina.
Calculation
of focal length of the corrective lens of Longt sightedness (Myopia)
The Focal length of the creective lens is calculated as the following.
If x is the distance of the near point of the defective eye and D is the least
distance of distict vision, the
u = - D,v = -x, where u = Object distance and x = Distance of the near
point of the defective eye
⇒(1/f) = [(1/v) -(1/u)]
⇒(1/f) = [-(1/x) =(1/D)]
⇒(1/f) = [(x D)/(x - D)]
⇒(1/f) = xD/(x - D)
Since x>D, the focal lenth is posive.
whose focal length is equal to the distance of the far poin tof the myopic eye
is to be placed in front of the the myopic eye.
Dispersion and
Scattering of Light
Rainbow is the natural phenomenon in
which dispersion takes place. The cause of dispersion is that sun light consists of seven constituents
(colours namely violet, indigo, blue, green, yellow, orange and red popularly
referred to as VIBGYOR) that have different refractive index with respect to a medium. The wavelength of
each colour is different that causes the difference in velocity of the
corresponding light when passing from one medium to another.
This phenomenon can be observed in a lab environment using a triangular glass
prism. It is a solid structure having three rectangular and two triangular
surfaces. Any two rectangular faces are the refracting surfaces and the third
one is the base. The angle between two refracting surfaces of a triangular
glass prism is denoted by A, called the angle of the prism or the refracting
angle.
The ray that deviates at the point of incidence due to a change in the medium
is the refracted ray.
The angle formed between the incident ray and the normal at the point of
incidence is known as the angle of incidence.
The angle between the normal and the refracted ray is known as the angle of refraction.
The angle between the directions of the incident ray and that of the emergent
ray is called the angle of deviation and is represented by Greek letter δ or qd.
• The splitting of white light
into its constituent colours is called dispersion of light.
• Light disperses and creates
a rainbow effect, when it propagates and refracts in a prism.
• Light disperses and creates
a rainbow effect, when it propagates and refracts in a prism.
The order of colours in a rainbow is popularly identified using the acronym,
VIBGYOR, each letter standing for a colour in order.
Atmospheric refraction refers to the apparent random wavering or
flickering of objects due to inconsistency in the physical conditions of the
refracting media such as air.
In scientific terms, the twinkling of stars is termed as astronomical
scintillation. When the sun is just below the horizon, its rays enter
earth’s atmosphere and are refracted towards the earth. The refracted rays
reach the earth making it appear as if the sun has already risen above the
horizon. This is apparent sunrise.
Apparent sunset occurs slightly later than the actual sunset, since the light
from the sun is already below the horizon, it refracts through the atmosphere, enabling us to
see the apparent sunset, even after the sun has already set.
Scattering of light is the deviation of light rays from its straight
path. As light propagates through the atmosphere, it travels in a straight
path until it is obstructed by bits of dust or gas molecules.
During sunrise and sunset, the sun is at the horizon and refractive index of the atmosphere of the earth decrease with
height. Due to this, light reaching the earth's atmosphere from different parts
of the vertical diameter of the sun enters at different heights in earth's
atmosphere and so travels in media of different refractive indices at the same instant and hence, bend unequally.
Due to this unequal bending of of light from the vertical diameter, the image
of the sun gets destored and it apppears oval and larger. However, at noon when
the sun is overhead, then due to normal incidence of light there is no bending
of light and hence, the sun appears circular.
The sky appears blue because out of the seven colours of light, blue has the
shortest wavelength, and therefore it experiences more scattering than other
colours.
Scattering of light gives rise to many amazing and spectacular phenomena such
as the Tyndall effect and the reddening of the sun at sunrise and sunset.
The Tyndall effect is the scattering of light by colloidal particles.
Sun
Appears red at Sunrise and Sunset
The sun appears white at noon becuase the light from the sun overhead would
travel relatively shorter distance. As only a little of the blue and
violetcolours are scattered.
the light from the sun, near the horizon, passes through the thicker layers of
air and covers a large distance in the earth's atmosphere before reaching our
eyes.
Near the horizon, most of the blue light and other shorter wavelengths are
scattered away by the particles. Therefore, the light that reaches our eyes is
of longer wavelengths. This gives rise to the reddish appearance of the sun.
Clouds
are White
Clouds are white because their water droplets or ice crystals
are large enough to scatter the light of the seven wavelengths the component
colours of white light(i.e red, orange, yellow, green, blue, indigo, and
violet), which combine to produce white light.
CHAPTER - ELECTRICITY
Current Electricity Basics
Electricity
is one of the oldest branches of science without which we cannot just imagine
ourselves in the current world. The current flow from a high potential
area to a low potential area is termed the conventional current whereas the
flow of electrons constitute the electron current and is in a direction
opposite to that of the conventional current.
Flowing water constitutes water current in rivers. Similarly, if the electric
charge flows through a conductor we say that there is an electric current
in the conductor. A continuous and closed path of an electric current is
called an electric circuit.
In a torch light, the cells provide flow of
charges or an electric current through the torch bulb to glow. The torch gives
light only when its switch is on. If the circuit is broken anywhere (or the
witch of the torch is turned off), the current stops flowing and the bulb does
not glow.
In circuits using metallic wires, electrons constitute the flow of charges. As
the electrons ere not known (not discovered) at the time of the observation of
the electric phenomenon. So, electric current was considered to be the flow of
positive charges and the direction of flow of positive charges was taken to be
the direction of electric current.
Conventionally, in an electric circuit the
direction of electric current is taken as opposite to the direction of the flow
of electrons, which are negative charges. Electric current is the rate of
flow of charges.
If a net charge Q flows across any cross-section of a conductor in time t, then
the current I through the cross-section is I = Q t .
The SI unit of electric charge is coulomb (C), which is equivalent to the
charge contained in nearly 6 × 1018electrons. (We know that an
electron possesses a negative charge of 1.6 × 10–19 C.) The electric current is expressed
by a unit called ampere (A), named after the French scientist, Andre-Marie
Ampere (1775–1836). One ampere is constituted by the flow of one coulomb of
charge per second, i.e., 1 A = 1 C/1 s. The SI unit of electric current is
ampere.
Small quantities of current are expressed in milliampere (1 mA = 10–3 A) or in microampere (1 μA = 10–6 A). An instrument called
ammeter measures electric current in a circuit.
An ammeter is always connected in series in a circuit through which the current
is to be measured. In a typical electric circuit comprising a cell, an electric
bulb, an ammeter and a plug key, the electric current flows from the positive
terminal of the cell to the negative terminal of the cell through the bulb and
ammeter.
Charges do not flow in a copper wire by themselves, just as water in a
perfectly horizontal tube does not flow. Water flows in a tube only if there is
a pressure difference between the two ends of a tube. Similarly electrons move
along the conductor only if there is a difference of electric pressure, known
as the potential difference.
For flow of charges in a conducting metallic wire, the gravity, of course, has
no role to play.
The difference of potential may be produced by a battery, consisting of one or
more electric cells. The chemical action within a cell generates the potential
difference across the terminals of the cell, even when no current is drawn from
it. When the cell is connected to a conducting circuit element, the potential
difference sets the charges in motion in the conductor and produces an electric
current. In order to maintain the current in a given electric circuit, the cell
has to expend its chemical energy stored in it.
The electric potential difference between two points in an electric circuit
carrying some current is the work done to move a unit positive charge from one
point to the other: Potential difference (V) between two points = Work done
(W)/Charge (Q),
i.e., V = W Q
The SI unit of electric potential difference is volt (V), named after the
Italian physicist Alessandro Volta. One volt is the potential difference
between two points in a current carrying conductor when 1 joule of work is done
to move a charge of 1 coulomb from one point to the other. 1 volt = 1 joule/1
coulomb; 1 V = 1 J/ C.
The potential difference is measured using a voltmeter. The voltmeter is
always connected in parallel across the points between which the potential
difference is to be measured.
A schematic diagram in which different components of the circuit are
represented by symbols is called aelectric circuit diagram.
A closed loop through which charge can continuously move is referred to as a
closed circuit. If the loop is not complete then charge stops flowing and
such a circuit is called an open circuit.
In 1827, a German physicist Georg Simon Ohm (1787–1854) found out the
relationship between the current I, flowing in a metallic wire and the
potential difference across its terminals. He stated that the electric current
flowing through a metallic wire is directly proportional to the potential
difference V, across its ends provided its temperature remains the same. This
is called Ohm’s law. In other words, V/I = constant = R, or V = IR, where R is
a constant for the given metallic wire at a given temperature and is called its
resistance.
As per electricity, we have two categories of materials, namely conductors and
insulators. All of the conductors do
not conduct electricity the same way. Some of them offer a restriction to the
flow of charge and are referred to as resistors. The restriction to the flow of
charge is electrical resistance and depends on the physical dimensions and
temperature of the conductor.
The resistance (R) of a conductor varies directly with its length (l) and
inversely with its area of cross-section (A). The mathematical expression is
R = ρl/A, where ‘r’ is the constant called resistivity or
specific resistance of the material which depends on the nature and temperature
of the material. Resistivity is measured in ohm-metre.
At a given temperature, the current through a conductor is directly
proportional to the potential difference across its ends and is known as Ohm’s
law.
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Ohmic Conductors
|
Non-Ohmic Conductors
|
|
1. Conductors that obey Ohm’s Law
are called Ohmic conductors.
2. In Ohmic conductors, current is proportional to voltage.
3. Magnitude of current remains unchanged when current or voltage is reversed
in Ohmic conductors.
4. In Ohmic conductors, temperature affects current and resistance.
|
1. Conductors which do not obey
Ohm’s Law are called Non-Ohmic conductors.
2. In Non-Ohmic conductors, current is not proportional to voltage.
3. Magnitude of current changes when current or voltage is reversed in
Non-Ohmic conductors.
4. In Non-Ohmic conductors, different factors affect current and resistance.
|
Factors
affecting the resistance of a conductor :
(1)
The material of wire : The
resistance of a wire depends on the number of collisions which the electrons
moving through it suffer with the other electrons and with the fixed positive
ions of the wire. In different materials, the concentration of electrons and the
arrangement of atoms are different, therefore, the resistance of wires of same
length, same area of cross section, but of different materials differ depending
on their material. Good conductors having higher concentration of free electrons
(such as metals) offer less resistance.
(2)
The length of wire : The
number of collisions suffered by the moving electrons will be more if they have
to travel a longer distance in wire, therefore, a long wire offers more
resistance than a short wire (i.e, resistance ∝
length of wire)
(3)
The area of cross section of wire : In a thick wire, electrons get a
larger area of cross section to flow as compared to a thin wire, therefore, a
thick wire offers a less resistance ((i.e, resistance ∝ 1/area of cross section)
(4)The
temperature of wire: If
the temperature of wire increases, ions in it vibrate more violently. As a
result, the number of collisions increases and hence the resistance of wire
increases with the increase in its temperature.
Current Electricity
Circuits
An electric circuit is a closed path for flow of
electricity through which electricity can be converted into different forms of energy. An electric circuit basically contains a source of electricity,
a load resistance, a switch or a key for making the circuit on or off at ones
convenience (which makes or breaks the circuit correspondingly).
The diagrammatic representation of an electric circuit is called the circuit diagram. Each electric component in a
circuit has a unique symbol through which it is represented in a circuit
diagram. If a circuit is switched off, it is called an open circuit and if the
circuit is switched on it is called a closed circuit.
The reciprocal of the net resistance of a number of resistors connected in
parallel is the sum of the reciprocals of the individual resistances.
The resistivity of an alloy is generally higher than that of its constituent
metals. Alloys do not oxidise (burn) readily at high temperatures. For this
reason, they are commonly used in electrical heating devices, like electric
iron, toasters etc. Tungsten is used almost exclusively for filaments of
electric bulbs, whereas copper and aluminium are generally used for electrical
transmission lines.
In various electrical gadgets, we often use resistors in various combinations.
There are two methods of joining the resistors together.
Series
Combination of Resistors
If a number of resistors are joined end to end in an electric circuit, the
resistors are said to be connected in series.
In a series combination of resistors the current is the same in every part of
the circuit or the same current flows through each resistor, i.e., there is
only one path for the flow of current.
Let us consider a circuit in which three resistors R1, R2 and R3 are connected in series with a battery
of potential difference V. The potential difference V is equal to the sum of
potential differences V1, V2, and V3. That is
the total potential difference across a combination of resistors in series is
equal to the sum of potential difference across the individual resistors. That
is,
V = V1 + V2 + V3 ------------ (i)
Let I be the current through the circuit. The current through each resistor is
also I. It is possible to replace the three resistors joined in series by an
equivalent single resistor of resistance Rs, such that the potential
difference V across it, and the current I through the circuit remains the same.
Applying the Ohm’s law to
the entire circuit,
V = I Rs. ------------------- (ii)
On applying Ohm’s law to the three resistors separately,
V1 = I R1;
V2 = I R2;
and V3 = I R3.
------------------- (iii)
From the eaquations (i),(ii) and (iii)
I Rs = I R1 + I R2 + I R3 implies that
Rs = R1 +R2 + R3.
When several resistors are joined in series, the resultant resistance of the
combination Rs equals the sum of their individual resistances, R1, R2,
R3.
Note: Rs is greater than any individual
resistance.
Parallel
Combination of resistors
In a parallel circuit each resistor is placed in its own separate branch.
A parallel circuit provides multiple paths for the current to flow.
Consider the arrangement of three resistors joined in parallel with a
battery. It is observed that the total current I, is equal to the sum of
the separate currents through each branch of the combination.
I = I1 + I2 + I3 --------------- (i)
The potential difference across each resistor is the same and is equal to the
voltage of the battery.
Let Rp be the
equivalent resistance of the parallel combination of resistors. By applying Ohm’s law to
the parallel combination of resistors,
I = V R p ---------------
(ii)
On applying Ohm’s law to each resistor,
I1 = V R 1 ; I2 = V R 2
; and I3 = V R 3
--------------- (iii)
From the equations (i), (ii) and (iii)
V R p = V R 1
+ V R 2 + V R 3
or 1 R p
= 1 R 1
+ 1 R 2 +
1 R 3
.
The reciprocal of the equivalent resistance of a group of resistances joined in
parallel is equal to the sum of the reciprocals of the individual resistances.
Note:
The effective resistance in a parallel circuit is always less than the lowest
resistance in the circuit.
In a series circuit the current is constant throughout the electric circuit.
Thus it is obviously impracticable to connect an electric bulb and an electric
heater in series, because they need currents of widely different values to
operate properly. Another major disadvantage of a series circuit is that when
one component fails the circuit is broken and none of the components works. For
example, the electrician has to spend lot of time in trouble-locating and replacing
the ‘dead’ bulb in a series of decorative bulbs– each has to be tested to find
which has fused or gone.
On the other hand, a parallel circuit divides the current through the
electrical gadgets. The total resistance in a parallel circuit is decreased.
This is helpful particularly when each gadget has different resistance and
requires different current to operate properly.
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Ohmic Conductors
|
Non-Ohmic Conductors
|
|
1. Conductors that obey Ohm’s Law are
called Ohmic conductors.
2. In Ohmic conductors, current is proportional to voltage.
3. Magnitude of current remains unchanged when current or voltage is reversed
in Ohmic conductors.
4. In Ohmic conductors, temperature affects current and resistance.
|
1. Conductors which do not obey
Ohm’s Law are called Non-Ohmic conductors.
2. In Non-Ohmic conductors, current is not proportional to voltage.
3. Magnitude of current changes when current or voltage is reversed in
Non-Ohmic conductors.
4. In Non-Ohmic conductors, different factors affect current and resistance.
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Laws
of Electric Resistance
1. The resistance (R) of a conductor of a given material is directly
Proportional to its length (l)
Rα l ----------------- (i)
2. The resistance (R) of a conductor of a given material is inversely
Proportional to its area of cross section (A)
Rα 1 A
----------------- (ii)
From the equations (i) and (ii)
R =
ρl A , where ρ is
called the resistivity of the material of unit length and unit
cross-sectional area.
It is measured in ohm-meter. It is independent of the length or cross-sectional
area of the conductor.
Heating Effect of Electric
Current
Heating effect of electricity is
one of the widely used effects in the world. When electric current is passed
through a conductor, it generates heat due to the resistance it offers to the
current flow. The work done in overcoming the resistance is generated as heat.
This is studied by James Prescott Joule and he enunciated various factors that
affect the heat generated. The heat produced by a heating element is directly
proportional to the square of the electric current (I) passing through the
conductor, directly proportional to the resistance (R) of the conductor, time
(t) for which current passes through the conductor. It is given by the
expression
H = I2Rt and is well known as Joule’s Law.
Applications of the heating effect of electric current include appliances like
electric immersion water heater, electric iron box, etc. All of these have a
heating element in it. Heating elements are generally made of specific alloys
like, nichrome, manganin, constantan etc.
A good heating element has high resistivity and high melting point. An electric
fuse is an example for the application of heating effect of electric current.
The rating of 3 A of an electric fuse implies the maximum current it can
sustain is three ampere.
The chemical reaction within the cell generates the potential difference
between its two terminals that sets the electrons in motion to flow the
current through a resistor or a system of resistors connected to the battery.
To maintain the current, the source has to keep expending its energy.
A part of the source energy in maintaining the current may be consumed
into useful work (like in rotating the blades of an electric fan). Rest of
the source energy may be expended in heat to raise the temperature of gadget.
For example, an electric fan becomes warm if used continuously for longer time,
etc.
If the electric circuit is purely resistive, that is, a configuration of
resistors only connected to a battery, the source energy continually gets
dissipated entirely in the form of heat. This is known as the heating effect of
electric current. When a conductor offers resistance to the flow of
current the work done by the electric current in overcoming this resistance is
converted into heat energy.
The generation of heat in a conductor is
an inevitable consequence of electric current. In many cases, it is undesirable
as it converts useful electrical energy into heat. In electric circuits, the
unavoidable heating can increase the temperature of the components and alter
their properties.
The electric heating is also used to produce light, as in an electric bulb.
Here, the filament must retain as much of the heat generated as is possible, so
that it gets very hot and emits light. It must not melt at such high
temperature. A strong metal with high melting point such as tungsten (melting
point 3380°C) is used for making the filaments of the bulb. The filament should
be thermally isolated as much as possible, using insulating support, etc.
The bulbs are
usually filled with chemically inactive nitrogen and argon gases to prolong the
life of filament. Most of the power consumed by the filament appears as heat,
but a small part of it is in the form of light radiated.
Devices which work on the heating effect of electric current have a heating
element or filament. Good heating elements have high resistivity, high melting
point and negligible variation in resistance due to temperature changes.
The three metal alloys most commonly used as heating elements are: Nichrome
(80% Ni + 20% Cr); Manganin (86% Cu + 12% Mn + 2% Ni); Constantan (60% Cu + 40%
Ni).
Joule's
law
The Joule's law states that the quantity of heat
produced in a resistor is directly proportional to: (i)the square of current
for a given resistance, (ii) the resistance for a given current, and (iii) the
time for which the current flows through the resistor, i.e., H = I2Rt.
Consider a current I flowing through a resistor of resistance R.
Let the potential difference across it be V.
Let t be the time during which a charge Q flows across.
The work done in moving the charge Q through a potential difference, V =VQ.
⇒
The source must supply energy equal to VQ in time t.
⇒
The power input to the circuit by the source is
P = VQ t = VI.
Or the energy supplied to the circuit by the source in time t
⇒H=
P × t,
⇒
H = VIt
This energy gets dissipated in the resistor as heat.
Thus for a steady current I, the amount of heat H produced in time t is H =
VIt.
Applying Ohm’s law, H = I2 Rt.
In practical situations, when an electric appliance is connected to a known
voltage source, current can be calculated using the relation I = V R . Using this value in H = I2Rt,
the heat produced
can be calculated.
One of the common applications of Joule’s heating is the fuse used in electric
circuits. An electric fuse is a safety device used to protect circuits and
appliances by stopping the flow of any unduly high electric current. It works
on the heating effect of electric current.
Electric
Fuse
The fuse is
placed in series with the device. An electric fuse consists
of a piece of wire made of a metal or an alloy of appropriate melting point,
for example aluminum, copper, iron, lead, etc. If a current larger than the
specified value flows through the circuit, the temperature of the fuse wire
increases. This melts the fuse wire and breaks the circuit. The fuse wire is
usually encased in a cartridge of porcelain or similar material with metal
ends.
The fuses used for domestic purposes are rated as 1 A, 2 A, 3 A, 5 A, 10 A,
etc. For an electric iron which consumes 1 kW electric power when operated at
220 V, a current of (1000/220) A, that is, 4.54 A will flow in the circuit. In
this case, a 5 A
fuse must be used.
Electric
energy and power
The rate of doing work is
called power. This is also
the rate of consumption of energy.
The equation H = I2 Rt
gives the rate at which electric energy is dissipated
or consumed in an electric circuit. This is also termed as electric power. The
power P is given by P = VI. Or P = I2R = V 2 R
.
The SI unit of electric power is watt (W).
It is the power consumed by a device that carries 1 A of current when operated
at a potential difference of 1 V.
1 W = 1 volt × 1 ampere = 1 V A.
The unit ‘watt’ is very small. Therefore, in actual practice we use a much
larger unit called ‘kilowatt’. It is equal to 1000 watts.
Since electrical energy is the product of power and time, the unit of electric
energy is, therefore, watt hour (W h). One watt hour is the energy consumed
when
1 watt of power is used for 1 hour.
The commercial unit of electric energy is kilowatt hour (kW h), commonly known
as ‘unit’. 1 kW h = 1000 watt × 3600 second = 3.6 × 106 watt second = 3.6 × 106 joule (J).
We pay the electricity board or electric company to provide energy to move
electrons through the electric gadgets like electric
bulb, fan and engines. We pay for the
energy that we use and not for the electrons. Electrons are not consumed in a
circuit, as many people think.
MAGNETIC EFFECTS
OF ELECTRIC CURRENTS
Magnetic Effects of
Electric Current
Magnetic effect of electric current is
one of the major effects of electric current in use, without the applications
of which we cannot have motors in the existing world. A current carrying
conductor creates a magnetic field around it, which can be comprehended by
using magnetic lines of force or magnetic field lines. The nature of
the magnetic field lines around a straight current carrying conductor is concentric
circles with centre at the axis of the conductor.
The direction of the magnetic field lines of force around a conductor is given
by the Maxwell’s right hand grip rule or the right handed cork
screw rule.
The strength of the magnetic field created depends on
the current through the conductor. If the conductor is in the form of
a circular loop, the loop behaves like a magnet.
Clock-S
rule
Cloak-S rule is rule which helps us to find the formation of magnetic South
Pole due to electromagnetic induction in a current carrying conducting coil.
According to clocks rule if one face of a current carrying conducting coil is
placed such that one face of the coil is faced to us and current is moving in
the clockwise direction with respect to us then the face of the coil which is
faced to us becomes as a magnetic south pole and the other face behaves as the
north magnetic pole.
A current carrying conductor in the form of a rectangular loop behaves like a
magnet and when suspended in an external magnetic field experiences force.
SNOW
Rule
SNOW rule states that if the current is flowing in an electric circuit from South to North
direction and a magnetic compass is placed Over
the conducting wire, the needle of the compass deflects in the direction of
west.
Right
hand thumb rule
Right hand thumb rule states that if we hold the conductor in the right hand
such that the thumb points in the direction of electric current, then the
direction in which the fingers curl gives the direction of the magnetic field
If we point thumb down wards in the direction of the current, the magnetic
field would be represented by the curled fingers as the circles around the
conductor.So, if it is viewed from the above plane this field lines will be
clockwise circles, but the direction of the magnetic field at any point on this
circular magnetic lines is in the direction of the tangent drawn to the
circular magnetic lines at the desired points.
Maxwell’s
cork-screw rule:
Maxwell' cork screw rule is also known as maxwell's right hand thumb ruleIf the
head of a cork-Screw is rotated such that the tip of the screw advances in the
direction of electric current, then the direction of rotation of the head of
the screw represents the direction of the magnetic field aroundthe conductor.
A magnetic field caused by a current-carrying conductor consists of sets of
concentric lines of force. The direction of the magnetic field lines depends on
the direction of the current passed through the conductor.
Electromagnet
An electromagnet is a magnet made up of a coil of insulated wire wrapped around
a soft iron core that is magnetised only when current flows through the wire.
Solenoid
The solenoid is an electro magnet which is a long cylindrical coil of wire
consisting of a large number of turns bound together very tightly.
Note: The length of the coil should be
longer than its diameter. (Or)
Solenoid is a coil of a number of turns of insulated copper wire closely
wrapped in shape of a cylinder. Magnetic field around a current carrying
solenoid is as shown in the figure.
Theses appear to be similar to that of a bar magnet. One end of the solenoid
behaves like North Pole and the other end behaves like the South Pole. Magnetic
field lines inside the solenoid are in the form of parallel straight lines.
This means that the field is same at all the points inside the solenoid.
When soft iron rod is placed inside the solenoid, it behaves like an electro
magnet. The use of soft iron as core in the solenoid produces the strongest
magnetism.
A solenoid consists of an insulated conducting wire wound on a cylindrical tube
made of plastic or cardboard.
Fleming’s
left hand rule
If the forefinger, middle finger and thumb of the left hand are stretched such
that they are at right angles to each other, then:The forefinger gives the
direction of the magnetic field.
• The
middle finger points in the direction of the current.
• The thumb gives the direction of
the force acting on the current-carrying conductor placed in the external
magnetic field.
• An electric motor converts
electrical energy into mechanical energy using the magnetic effect of
electricity.
Electric
motor
The direction of the force is given by Fleming’s left hand rule. This
gives the basis for an electric motor. An electric motor essentially
consists of a coil as an armature, a split ring commutator for changing the
direction of the current in the coil. There are two brushes linked with the
split rings that maintain the contact with the armature for the current flow.
Electric motor converts electrical energy to mechanical energy.
A number of such loops form a coil and the coil is termed solenoid. If
there is a soft iron core in the solenoid, it behaves like a magnet as long as
there is current through the coil. Thus it is an electromagnet.
When an electric current passes through a conductor, a magnetic field is
created around the conductor. This phenomenon is known as the magnetic effect
of electricity.
A magnetic field is the extent of space surrounding a magnet where the magnet’s
effect can be felt.
Magnetic field lines represent the lines of action of the force acting on a
unit North Pole placed in a magnetic field.
Electromagnetic
Induction
Electromagnetism created
a revolution by leading to the devices called motors which convert electrical
energy to mechanical energy. Experiments by scientists like Oersted and Faraday
made a long leap by converting mechanical energy to electrical energy.
When a straight conductor is
moved in a magnetic field an electric current is induced in it and the
phenomenon is electromagnetic induction.
The emf caused is the induced emf and the current is induced current.
Oersted found the same by relative motion of a magnet with respect to a coil.
Faraday's experiment proved that the strength of the induced current depends on
several factors like the strength of the magnet, the speed of motion of the
magnet, its orientation, the number of turns in the coil and the diameter of
the coil. The induced current can be detected by a galvanometer.
Fleming’s right hand rule gives the direction of the induced current in a
conductor when it is moved in amagnetic field. Transformers are based on this
principle, which consist of a primary coil and a secondary coil. The number of
turns in the coils is selected based on the type of the transformer to be made,
namely, step-up or step-down.
Electric generators work on the same principle. They have an armature which is
free to rotate in a magnetic field. Its terminals are connected to two slip
rings, which are further connected to two brushes and they are connected across
a load resistance through which the generated electricity can be trapped. The
rotation of the armature in the magnetic field changes the magnetic flux in the
coil of the armature and an electric current is induced. As the direction of
the induced current changes for every half rotation, it is called alternating
current.
The current at the power plants is distributed through transmission lines at a
high voltage and hence the lines are referred to as high tension power lines.
At the substations these are stepped down to a lower voltage and supplied to
houses at a low voltage.
A domestic electric circuit essentially contains mains, a fuse, live or line,
neutral and earth wires. From the poles supply cables bring the current to the
mains. Within the house, all the equipment is connected in parallel
combination.
Electromagnetic induction (EMI)
is the process of generating an electromotive force by moving a conductor
through a magnetic field.
The electromotive force generated due to electromagnetic induction is called
induced emf. The current due to induced emf is called induced
current.
Fleming’s
right hand rule
Fleming’s right hand rule states that if the index finger points in the
direction of the magnetic field and the thumb indicates the direction of the
motion of the conductor, then the middle finger indicates the direction of the
induced current flow in the conductor.
An electric generator is used to convert mechanical energy into electrical
energy, using electromagnetic induction.
Alternating current (AC) is the current induced by an AC generator. AC current
changes direction periodically. Direct current (DC) always flows in one direction,
but its voltage may increase or decrease.
Electrical components and wires fitted in a household to supply electricity to
various appliances form a domestic electric circuit. The main supply cable has
two wires: Live wire and neutral wire. Domestic electric circuits have earth
wires to save users from severe electric shocks. An electric fuse is a safety
device used to protect an electric circuit against excessive current.
Electricity and magnetism are inter-related and are also inter-convertible. In
this setup an electric current passing through a conductor produces a magnetic
field which can be observed through the deflection of a magnetic compass
needle placed near the conductor. This proves that moving electric charges
produce magnetic fields. Electric motors work on this principle.
Electromagnetic Induction.
However, in this setup we see that an electric current is induced in a closed
coil when subjected to a changing magnetic field. The phenomenon in which an
electric current is generated by varying magnetic fields is called
electromagnetic induction.
Electric generators work on this principle. We will now discuss and learn about
three experiments
by Faraday and Henry, relating to electromagnetism. In the first experimental
setup, a coil is connected to a Galvanometer.
When a bar magnet with its north pole facing the coil, is moved towards or away
from the coil, the
Galvanometer needle deflects to the right and left side of zero reading
respectively, showing
the presence of a current in the coil.
Let us see what happens if the south pole of the magnet faces the coil. The
Galvanometer needle deflects to the left side of zero reading as the magnet
approaches the coil and deflects to the right when the magnet moves away from
the coil, showing the presence of a current in the coil.
The Galvanometer needle deflects only as long as the bar magnet is in motion.
Once the bar magnet comes to rest the galvanometer needle settles down at “0”
reading indicating that there is no current in the coil.
From all these observations we can conclude that whenever there is relative
motion between a bar
magnet and a coil, an electric current is induced in the coil. In the second
experimental setup, there are two coils:
Coil 1 connected to a Galvanometer, Coil 2 connected to a battery Due to the
steady current in coil 2, a steady magnetic field is set up around the coil 2
and this magnetic field is also linked to the coil 1.
When coil 2 is kept stationary and coil 1 is moved towards coil 2, a current is
induced in coil 1 and
the galvanometer needle deflects to the left of “0”. When coil 2 is kept
stationary and coil 1 is moved away from coil 2, a current is induced in coil 1
and the galvanometer needle deflects to the
right of “0”. If we keep coil 1 stationary and move coil 2 towards coil 1, a
current is induced in coil 1 and a deflection is observed in the galvanometer
needle to the left of “0”.
Now if we keep coil 1 stationary and move coil 2 away from coil 1, a current is
induced in coil 1 and a deflection is observed in the galvanometer needle to
the right of “0”. From all these observations we can conclude that whenever
there is relative motion between a current carrying coil and a closed coil in
which a galvanometer is connected a current is induced in the closed coil.
In the third experiment a tap key is provided in the coil 2 circuit. Here we
can observe the
deflection of the galvanometer needle even when the two coils are stationary.
This deflection is observed only at those instants when the tap key is either
switched on or off. This happens because of the change in magnetic field during
switching on and off.
When a ferromagnetic material like an iron rod is placed co axially along the
two coils, the effect
of the magnetic field linked to the coil 2 increases due to the nature of the
ferromagnetic material as it allows more number of magnetic lines of force to
link within the area of the coil. Hence the deflection of the galvanometer
needle increases indicating an increase in the induced current.
Electricity and magnetism are inter-related and the energies linked with them
are also inter-convertible. Whenever there is relative motion between the
magnet and a coil, an electric current is induced in the coil.
SOURCES OF ENERGY
Sources of Energy
We cannot imagine
the world without energy. The
source of energy is important as well. There are various sources of energy
available today to the mankind. On a broad sense, sources of energy can be
categorized into non-renewable and renewable. Wood, coal, oil, natural
gas are some of the non-renewable sources as they cannot be renewable.
These are also called the conventional sources of energy. Nuclear fuels like
uranium produce energy by fission process. Nuclear energy from sun is
obtained by nuclear fusion process.
Conventional fuels and sources of energy cause a lot of pollution to mankind
and hence there is a need for looking towards alternate sources of energy,
which are most likely to be renewable. Solar energy, energy
from wind, hydro energy, geothermal energy and energy
from biomass are some of the alternate sources of energy. Wind energy
can be harnessed by using wind mills that can be erected at suitable locations.
Hydroelectric plants make use of hydro energy. In most of the rural areas biomass is utilized.
Characteristics
of a Good Source of Energy
• Enables us to do a large amount of work per
unit volume or mass.
• Is easily accessible.
• Is easy to store and transport.
• Is economical.
Burning coal or petroleum products causes acidic oxides to be
released. Thermoelectric production of electricity involves
turbines. In thermal power stations, fossil fuels are burned to produce
steam, basically a form of heat energy. This steam runs a turbine, which rotates
a generator to produce electricity.
In hydroelectric power stations, the kinetic energy of flowing water, which is
actually the potential energy of water stored at a height, is converted into
electricity. Plant and animal products, wood and cow-dung cakes, are used
as fuels. The source of these fuels is called bio-mass.
Burning a given mass of charcoal generates more heat than burning an equal mass
of wood. Cow-dung, crop residue, garbage and sewage are decomposed in the
absence of oxygen to produce bio-gas.
Advantages
of Bio-Gas:
• It is an excellent fuel with 75%
methane.
• It burns without smoke.
• It has a high heating capacity.
• It is also used for lighting.
Wind is another freely available resource that is used for generating energy.
Alternative
or Non-Nonventional Sources of Energy:
• Energy from the sun
• Energy from the sea
• Geothermal energy
• Nuclear energy
Black surfaces absorb more heat when compared to white under identical conditions.
Three
Types Energy From the Sea:
• Tidal energy
• Wave energy
• Ocean thermal energy
Molten rock in the earth’s crust is pushed upward and trapped in certain
regions called hot spots.
Nuclear energy is produced either by nuclear fission or nuclear fusion.
Exploiting various sources of energy causes dist
OUR ENVIRONMENT
Our Environment
Balance
in nature is maintained by the interaction between biotic components with that
of abiotic components.
The ecosystem is a community of organisms and their physical environment
interacting with each other as an ecological unit, involving the flow of
energy.
• An ecosystem consists of biotic
components including living organisms and abiotic components, the physical
factors like temperature, rainfall, wind, soil and minerals.
• An ecosystem can be natural or
artificial. Organisms in the ecosystem can be categorised into producers,
consumers and decomposers.
Producers are the organisms that produce their own food without the help of any
other organism.
• They are also known as autotrophs.
• They make their food from
inorganic substances through a process called photosynthesis.
• Autotrophs are green plants,
phytoplankton and blue green algae.
Consumers are the organisms which cannot produce food but depend on producers
for the same.
• These are also called as called
heterotrophs.
• Heterotrophs are the animals can
be classified into herbivores, omnivores, carnivores and parasites based on
their food pattern.
Decomposers are the organisms which feed on dead and decaying matter.
• Decomposers break down the complex
organic compounds present in dead animals and plants, which are then used by
other members of the ecosystem.
• Decomposers like bacteria and
fungi are known as saprobes.
Food chains describe the feeding relationship between the organisms of an
ecosystem.
• The flow of energy from one
species to another at various biotic levels forms a food chain.
• The successive levels in the food
chains of a community are called as trophic levels.
• Various trophic levels in a food
chain include producers, primary consumers, secondary consumers and tertiary
consumers.
• A web of cross-linked food chains
is called a food web.
Biological magnification is a phenomenon by which toxic substances accumulate
from one trophic level to another. As human beings occupy the top level in any
food chain, the maximum concentration of these toxic chemicals gets accumulated
in your body which becomes toxic to us.
Ozone is molecule formed by the combination of three oxygen atoms. There is a
layer of ozone in the stratosphere. It acts as a natural sun-block and shields
us from the UV radiations of the sun which are dangerous to living
organisms.Ozone depletion is the sharp reduction of ozone in the stratosphere
due to chlorofluorocarbons (CFC’s) used as refrigerants and in fire
extinguishers.
Increased use of non-biodegradable items have left the environment polluted
with them.
MANAGEMENT OF NATURAL
RESOURCES
Management of Forest
Resources
Natural resources
are the materials provided by nature. They include forests, water, coal and
petroleum reserves. Day-by-day we are exploiting our natural resources.
River Ganga features an example for the exploitation of natural resources.
• The river Ganga runs its course of
over 2500 kilometres from Gangotri in the Himalayas to the Bay of Bengal,
through Uttar Pradesh, Bihar and West Bengal.
• Pollution of the river Ganga is
due to activities like bathing, washing clothes, immersion of the ashes of the
dead, industrial effluents and release of untreated sewage.
• The coliform bacteria are usually
found in the human intestine whose presence in the Ganga water indicates
contamination by faeces and disease-causing micro-organisms.
• The Ganga Action Plan project was
launched in 1985 to clean the Ganga and make its water free from pollution.
Forests are 'biodiversity hotspots' due to the sheer number as well as the
variety of species of flora and fauna that live in them.
• Stake holders are people who live
in and around forest, the forest department of the government, industrialists,
forest and wildlife activists etc.
• We have to conserve forests which
are of greater use to the environment.
• The Chipko Andolan ('Hug the Trees
Movement') originated in the 1970's, in a village called Reni in Garhwal high
up in the Himalayas. It was to save trees from being cut down.
• The conservation of forests by the
Bishnoi community in Rajasthan became well known because of Amrita Devi
Bishnoi, who sacrificed her life in 1731 for the protection of the Khejri trees
in village Khejrali.
• The role of the government in
forest conservation includes owning of forest land, controlling industries,
framing rules to ensure that local people benefit and to control illegal
activities.
• Biodiversity should be conserved.
This happens by protecting flora and fauna of the place.
• The ways to conserve our resources
are judicious use, long-term perspective, and equitable distribution.
• Pollution should be controlled.
The 3R's in conserving resources are Reduce, Recycle and Reuse.
Sustainable development is not only about the resources we use but also ensures
that they are equally distributed. Stake holders together help in sustainable
management.
Government should control the industries in using raw materials. It should
ensure that local people should not be marginalised. Government should also
control illegal activities. Industries should play an important role in the
management of natural resources.
Management of Water
and Coal Resources
Water
Water is an essential form of life. Water is useful in agriculture, industries,
cooking and various domestic activities.Most of us depend on rainfall for
water.
The rainfall pattern in India differs in different geographical regions.
Tropical regions receive more rainfall as compared to desert regions.
The passage of water from water bodies to the atmosphere and back to the earth
is called water cycle.
During water cycle, water from aquatic bodies evaporates into the atmosphere
due to sunlight and condenses into clouds. Due to air currents, the clouds turn
into rains and reach water bodies and the ground.
Forms
of water
• Around 97.5 percent of water in
the oceans is salty. About 1.75 percent of fresh water remains frozen in
glaciers and polar ice caps while the remaining 0.75 percent exists as
groundwater.
• The advantages of groundwater are
that it does not evaporate, it recharges wells and it is protected from
contamination by human and animal waste.
Dams
Dams are the structures constructed to divide and retain river water in a
particular area.
• Some famous dams in India are the
Bhakra Nangal Dam, the Sardar Sarovar Dam and the Tehri Dam.
• Dams provide water which is used
to generate hydroelectric power.
• Dams are also used to supply water
for agriculture, for domestic purposes and as drinking water in cities. Water
from dams is distributed through canal systems that transport stored water to
great distances.
• The Indira Gandhi Canal is one of
the biggest canal projects in India which provides water for Rajasthan.
• The disadvantages of dams are
deforestation, sedimentation, erosion of river beds, and disruption of animal
and plant life.
Watershed
management
Watershed management is an integrated multi resource management of land and
water.
• Watershed management aims at water
conservation to increase biomass production.
• Water harvesting is an age old
concept in India.
• Water harvesting techniques are
named differently at different places, but the use remains the same. For
example, Khadins and Nadis in Rajasthan, Bandharas and Tals in Maharashtra,
Bundhis in Madhya Pradesh and Uttar Pradesh, Ahars and Pynes in Bihar, and Eris
in Tamil Nadu.
• Kulhs in Himachal Pradesh, Kattas
in Kerala, Trenches in Karnataka help in recharging water resources.
Fossil
fuels
Coal, petroleum and natural gas are the fossil fuels which provide us energy in
many activities of our life. These are non-renewable sources of energy.
• Coal was formed hundreds of
million years ago as a result of the action of heat and pressure on decaying,
buried plants in the swampy areas of the earth. It is a continuous process
taking place under the earth.
• Coal helps in the production of
thermal electricity. About 37 percent of the world’s electricity is produced
using coal.
• Coal is a non-renewable but
cheaper resource than other fuels like petroleum and gas.
• The disadvantages of fossil fuels
are that they release carbon dioxide, oxides of nitrogen and oxides of sulphur
on combustion. Carbon dioxide causes global warming.
Some alternative sources of energy are wind, solar, thermal and
hydroelectric energy. These are all viable options since they are more
environment-friendly.
Energy conservation can be done by recycling and reusing plastic bags,
switching off lights, and also by using CFL bulbs.